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971.
Mihail Ionescu Zoran S. Petrović Xianmei Wan 《Journal of Polymers and the Environment》2007,15(4):237-243
Soybean polyols prepared by ring opening reactions of epoxidized soybean oil with hydrogen active compounds (water, alcohols,
organic or inorganic acids, thiols, hydrogen etc.) have a low reactivity in the reaction with isocyanates because the hydroxyl
groups are secondary. This paper presents a simple and convenient method to increase the reactivity of soybean polyols with
secondary hydroxyl groups by ethoxylation reactions with the preservation of triglyceride ester bonds. The method uses mild
reaction conditions: low alkoxylation temperature of 35–45 °C, low pressure of 0.1–0.2 MPa (15–30 p.s.i.) and a superacid
as catalyst (HBF4). The new soybean polyols have a higher reactivity toward isocyanates in polyurethane formation due to the high percentage
of primary hydroxyl groups. The primary hydroxyl content was determined by the second order kinetics of polyol reaction with
phenyl isocyanate. 相似文献
972.
Chemical Treatments of Natural Fiber for Use in Natural Fiber-Reinforced Composites: A Review 总被引:2,自引:0,他引:2
Xue Li Lope G. Tabil Satyanarayan Panigrahi 《Journal of Polymers and the Environment》2007,15(1):25-33
Studies on the use of natural fibers as replacement to man-made fiber in fiber-reinforced composites have increased and opened
up further industrial possibilities. Natural fibers have the advantages of low density, low cost, and biodegradability. However,
the main disadvantages of natural fibers in composites are the poor compatibility between fiber and matrix and the relative
high moisture sorption. Therefore, chemical treatments are considered in modifying the fiber surface properties.
In this paper, the different chemical modifications on natural fibers for use in natural fiber-reinforced composites are reviewed.
Chemical treatments including alkali, silane, acetylation, benzoylation, acrylation, maleated coupling agents, isocyanates,
permanganate and others are discussed. The chemical treatment of fiber aimed at improving the adhesion between the fiber surface
and the polymer matrix may not only modify the fiber surface but also increase fiber strength. Water absorption of composites
is reduced and their mechanical properties are improved. 相似文献
973.
Johan Tidblad Vladimir Kucera Farid Samie Surendra N. Das Chalothorn Bhamornsut Leong Chow Peng King Lung So Zhao Dawei Le Thi Hong Lien Hans Schollenberger Chozi V. Lungu David Simbi 《Water, Air, & Soil Pollution: Focus》2007,7(1-3):241-247
Many national exposure programmes have been performed in tropical and subtropical climates during the last 50 years. However,
ambitious programmes involving more than a few countries are scarce. In this paper a recently formed network of test sites
is described involving 12 test sites in Asia (India, Vietnam, Thailand, Malaysia and China including Hong Kong) and four test
sites in Africa (South Africa, Zambia and Zimbabwe). This effort is part of the 2001–2004 Swedish International Development
Agency (SIDA) funded Programme on Regional Air Pollution in Developing Countries (RAPIDC). Corrosion attack after one (2002–2003)
year of exposure (carbon steel, zinc, copper, limestone and paint coated steel) are presented together with environmental
data (SO2, NO2, HNO3, O3, particles, amount and pH of precipitation, temperature and relative humidity) for all the test sites. The obtained corrosion
values are substantially higher than expected for limestone, higher than expected for carbon steel and lower than expected
for zinc compared to values calculated using the best available dose–response functions. 相似文献
974.
An investigation on the effect of epoxidation and maleated natural rubber (MNR) on fatigue and rubber-filler interaction properties
of paper sludge filled natural rubber composites was elucidated. Paper sludge loading was varied from 0 to 40 phr and conventional
vulcanisation system was used while compounding was carried out on a laboratory sized two roll mill. Two different types of
natural rubber, SMR L and ENR 50 having 0 and 50 mole% of epoxidation were used in order to investigate the effect of epoxidation
on the composites. Results indicate that, at a fixed filler loading, ENR 50 vulcanizates exhibit higher fatigue life than
SMR L vulcanizates especially at filler loading below 20 phr which might be associated with better rubber-filler interaction.
In the case of composites with the addition of maleated natural rubber (MNR), a higher fatigue life was observed due to presence
of physical and/or chemical linkages, which increases the interfacial adhesion. Scanning electron microscopy (SEM) micrographs
of fatigue fracture surfaces and rubber-filler interaction study supported the observed result on fatigue life. 相似文献
975.
Mary Beth Adams James N. Kochenderfer Pamela J. Edwards 《Water, Air, & Soil Pollution: Focus》2007,7(1-3):267-273
In 1989, a watershed acidification experiment was begun on the Fernow Experimental Forest in West Virginia, USA. Ammonium
sulfate fertilizer (35.5 kg N ha−1 yr−1and 40.5 kg S ha−1 yr−1) was applied to a forested watershed (WS3) that supported a 20-year-old stand of eastern deciduous hardwoods. Additions of
N and S are approximately twice the ambient deposition of nitrogen and sulfur in the adjacent mature forested watershed (WS4),
that serves as the reference watershed for this study. Acidification of stream water and soil solution was documented, although
the response was delayed, and acidification processes appeared to be driven by nitrate rather than sulfate. As a result of
the acidification treatment, nitrate solution concentrations increased below all soil layers, whereas sulfate was retained
by all soil layers after only a few years of the fertilization treatments, perhaps due to adsorption induced from decreasing
sulfate deposition. Based on soil solution monitoring, depletion of calcium and magnesium was observed, first from the upper
soil horizons and later from the lower soil horizons. Increased base cation concentrations in stream water also were documented
and linked closely with high solution levels of nitrate. Significant changes in soil chemical properties were not detected
after 12 years of treatment, however. 相似文献
976.
H. Cornier-Ríos P. A. Sundaram J. T. Celorie 《Journal of Polymers and the Environment》2007,15(1):51-56
Recycled plastics are considered low performance materials because their properties are expected to decrease drastically with
recycling. The objective of this study was to characterize a 15 wt.% glass filled polyethylene terephthalate (rPET-15GF) using
six recycle generations and four recycle ratios. Mechanical properties such as tensile strength, elastic modulus, and percent
elongation to failure of the PET composite were determined for various recycle generations and recycle ratios. Results show
that the mechanical properties of rPET-15GF decrease slightly per recycle generation. In contrast, thermal properties of rPET-15GF
were not at all affected by the recycling process. This data demonstrates that recycled glass filled PET can be used effectively
to fabricate components without significantly affecting their mechanical performance. 相似文献
977.
Marcos R. Monteiro Daniela G. G. Moreira Marcelo A. Chinelatto Pedro A. P. Nascente Nelson G. Alcântara 《Journal of Polymers and the Environment》2007,15(3):195-199
The cell phone market is developing at a rapid speed. Today there are more than 1.6 billion consumers in the world, and the
lifetime of a cell phone is less than 2 years. As a consequence, there is an increase in the waste associated to this product,
and many alternatives to the disposal of the cell phones are being studied, such as recycling which shows to be the most important.
It is crucial to know what materials constitute the cell phone in order to carry out recycling and determine environmental
and economical issues. This work presents an evaluation of the cell phone components, characterizing the raw materials and
some properties of the recycled materials. 相似文献
978.
The environmental fate and transport of chlorinated volatile organic compounds (VOCs) is controlled by the physical and chemical properties of the compound and the nature of the subsurface media through which the compound is migrating. Several processes (advection, dispersion, diffusion, biodegradation, and abiotic degradation, to name a few) result in a reduction in concentration and/or mass of contaminants in groundwater. Of these processes, biodegradation is often considered the dominant destructive attenuation mechanism for chlorinated VOCs. However, chlorinated VOCs can also degrade through abiotic processes and, in some cases, may be the primary or only destructive process occurring. © 2007 Wiley Periodicals, Inc. 相似文献
979.
980.
Joseph C. Rode Christine H. Mooney Marne L. Arthaud‐Day Janet P. Near Timothy T. Baldwin Robert S. Rubin William H. Bommer 《组织行为杂志》2007,28(4):399-421
We examined the direct and moderated effects of an ability‐based measure of emotional intelligence (MSCEIT© V2.0) on individual performance in a sample of business undergraduates. Controlling for general mental ability and personality, emotional intelligence explained unique incremental variance in performance ratings on only one of two measures of interpersonal effectiveness (public speaking effectiveness). However, the interaction of emotional intelligence with conscientiousness explained unique incremental variance both in public speaking and group behavior effectiveness, as well as academic performance (cumulative GPA). We conclude that the effects of emotional intelligence on performance are more indirect than direct in nature. Individuals must not only have emotional intelligence, but also must be motivated to use it. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献