Deposition and Storage of Spheroidal Carbonaceous Fly-Ash Particles in European Mountain Lake Sediments and Catchment Soils

Spheroidal carbonaceous particles(SCPs) are produced only from high temperaturecombustion of fossil-fuels. In mountain lakesystems, they provide an unambiguous indicator ofatmospheric deposition. In order to comparedepositional fluxes of SCPs between mountainareas experiencing various pollutant regimes,intensive bulk deposition sampling was undertakenat five sites across Europe. Catchment soil coresand lake sediment cores were also taken at eachsite to compare SCP storage over the post-industrial period. Atmospheric, sediment and soilSCP data showed similar patterns. Highestcontamination was found in Scotland, Slovakia andSpain with the Austrian site intermediate and themid-Norwegian site least contaminated. A highproportion of accumulated SCPs were found to bestored in catchment soils at each site.Therefore, a significant increase in soilerosion, possibly as a result of future climatechange, could lead to the input of largequantities of catchment stored SCPs and, byimplication, other atmospherically depositedcontaminants to the lake ecosystem.     

Rhizosphere acidification and cadmium uptake by strawberry clover

Strawberry clover (Trifolium fragiferum L.) is a hardy legume found in indigenous or introduced populations throughout the world. Tolerance to saline and alkaline soils, flooding, and heavy metals make it a good prospect for reclamation projects. The research, described here, was conducted to: (i) characterize the morphological variation in plants from available seed sources, (ii) evaluate cadmium uptake and tolerances over a wide range of morphological variants, and (iii) elucidate the variability in the effects of roots on rhizosphere pH and the relationship to cadmium uptake. Seeds from selected accessions were planted in the greenhouse for comparison of morphological variation. The accessions examined had a mean height of 10.7+/-7 cm. Accessions 254916 and 237925 are tall with high rhizosphere pH values and might be useful in phytoremediation. Strawberry clover accessions were also grown hydroponically to examine differences in cadmium uptake. The ability of strawberry clover roots to change rhizosphere pH and take up cadmium was examined using culture tubes containing nutrient agar, a moderate level of cadmium, and a pH indicator dye. The results provided evidence for a negative correlation between rhizosphere pH and cadmium uptake.     

Towards an assessment of the influence of climate on wet acidic deposition in Europe

The EMEP precipitation composition network is used to examine relationships between non-marine SO4(2-), NO3-, NH4+, H+ concentrations and precipitation amount and a local zonal pressure index (an index of the atmospheric circulation). The pattern of the relationships changes across Europe with the zonal pressure gradient explaining more of the variance in ion concentrations in the west, and precipitation amount explaining relatively more of the variance in the east. There is some predictive capability for precipitation composition in the zonal pressure gradient for restricted regions in Europe; R2 values are up to 40% on a daily basis but in some seasons/months attain >60%. The zonal pressure gradient is an index which appears to include pertinent information on transport and wet removal. Preliminary analysis indicates that this approach can be useful in assessing the contributions of changing atmospheric circulation to time-trends of wet acidic deposition in an area stretching from the UK over the North Sea to Denmark. The zonal pressure gradient is known to have varied on time-scales of decades, and the simple index may be one appropriate approach to assessing future deposition patterns from future climate projections.     

Odour control at biowaste composting facilities

There are several options to effectively reduce odorous emissions at composting facilities depending on the type of composting system used. Some of the more relevant measures for open and enclosed composting facilities are presented in this article. Results from different investigations on odour reduction efficiencies of biological waste gas treatment systems at various scales are presented. Biofilter/bioscrubber combinations were used and different biofilter materials were tested. The more relevant odorous substances in the waste gas were identified, and their reduction in the different systems was measured. The biofilter proved to be mainly responsible for efficient odour degradation. The investigations presented in this article revealed that screened compost was very effective, and proved to be a low cost biofilter material for odour degradation purposes. Screened compost showed higher degradation rates than a coke-compost mixture newly developed by the University of Leipzig. Furthermore, it seems that enclosed systems have advantages when compared to conventional open single bed biofilters.     

Desorption kinetics for selected PCB congeners from river sediments

Desorption of PCBs from sediment can significantly affect the ultimate fate and effects of PCBs in aquatic systems. Using a gas purging technique to strip soluble and sorbed polychlorinated biphenyls (PCBs) from solutions and sediment suspensions, Henry's law constants, approach to equilibrium, and desorption rate constants for four PCB congeners were measured. Henry's law constants were on the order of 10⁻⁴ m³ atm mole⁻¹. Desorption rate constants measured for a predominantly kaolinitic, low-organic carbon sediment were on the order of 0.03–0.1 days⁻¹. In contrast, desorption rate constants measured for a sediment composed of montmorillonite with a 3% organic carbon content were on the order of 0.009–0.04 days⁻¹. Desorption data suggest that equilibration times for PCBs with low chlorine content are on the order of six weeks, and months to years for PCBs with a significantly higher chlorine content.     

Levels of organochlorine compounds in spotted dolphins from the Coiba archipelago, Panama

Blubber and skin samples from 63 spotted dolphins (Stenella attenuata) (18 males, 40 females and 5 of unknown sex) were collected by biopsy techniques in the waters of the Coiba archipelago. Blubber was analyzed for organochlorine compounds and skin for gender determination. Mean levels of HCB (hexachlorobenzene), tPCB (polychlorinated biphenyls) and tDDT (dichlorodiphenyltrichloroethane) were 0.064, 2.30 and 6.4 mgkg(-1), respectively. These levels are low and are not considered to represent a threat to the S. attenuata population. No significant differences either in concentrations of HCB, tPCB and tDDT or in PCB profiles were observed between males and females. The ratio tDDT/tPCB was 2.69, indicating predominantly agrarian versus industrial activities in the area. The ratio ppDDE/tDDT was 0.83, a high figure that suggests both a local reduction of DDT inputs and a high rate of DDT degradation. Significant quantitative and qualitative differences were observed between two schools, suggesting intra-population heterogeneity in organochlorine exposure possibly due to demographic segregation.     

Measuring agricultural sustainability in terms of efficiency: the case of Dutch sugar beet growers

Sustainability embraces socio-economic and bio-ecological dimensions or attributes. This paper presents a conceptual framework for quantifying sustainability on the basis of efficiency theory commonly used in economics. The conceptual model is implemented using Data Envelopment Analysis (DEA). Sustainability is measured for a sample of Dutch sugar beet growers. The average technical efficiency was only 50%. A positive correlation was found between technical efficiency and sustainable efficiency. Differences in efficiency among farmers were persistent within and between years. We conclude that there is considerable scope for improving the sustainability of arable farming by better management.