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71.
Some kinds of amine groups can be introduced to the glassy carbon surface by the electrode oxidation of the carbon electrode surface in ammonium carbamate solution, and this amine groups modified electrode is named as an aminated glassy carbon electrode. The existences of not only primary amine but also secondary and tertially amines were confirmed by X ray photoelectron spectroscopy. The applications of the aminated carbon material for the electrocatalytic reductions of oxygen, hydrogen peroxide, and organic compounds such as quinones were carried out, and the effects of amination on the formation of electrocatalytic sites for many species were revealed. The electrocatalyzed cyclic voltammograms of metal ions and metal chelate compounds obtained by aminated glassy carbon electrodes are also discussed. Moreover, we intend to describe that the aminated carbon electrode can exhibit the large reduction waves of inorganic oxoacids such as N02? or bromide ion. The introduced functional groups containing nitrogen atom can change the distribution of the electron densities of the graphite carbon surface, and this specific electron distribution environment may generate the various electrocatalytic activities. 相似文献
72.
73.
Bruno Takahashi Kanni Huang Frederick Fico David Poulson 《Environmental Communication: A Journal of Nature and Culture》2017,11(1):106-121
This study focuses on the use of science sources as experts in news stories about climate change coverage in the Great Lakes region of the US and Canada. We examine, using the hierarchy of influences model, whether the use of scientific sources in climate change coverage may be related to factors such as geographic location, reporting frequency, and authorship, in the prestige press as well as regional and local media. The study found that as many or more non-scientists than scientists are selected as sources regardless of geographic location, reporting frequency, or authorship. However, the study also found that the more stories reporters produce on this topic, the more likely their stories are to use and give prominence to science sources. In addition, the articles included few denier sources, but denier views are more likely to appear in a more prominent location in the articles than supporters when stories are framed as conflict over global warming. These results highlight the need for additional research examining the expertise of climate scientists in news stories to better understand news decision-making in the context of complex scientific reporting. 相似文献
74.
Kambe Y Yoshii Y Takahashi K Tonokura K 《Journal of environmental monitoring : JEM》2012,14(3):944-950
Measurements of the local distribution of atmospheric nitrogen dioxide (NO(2)) by long-path pulsed differential optical absorption spectroscopy (LP-PDOAS) in Tokyo during August 2008 are presented. Two LP-PDOAS systems simultaneously measured average NO(2) temporal mixing ratios along two different paths from a single observation point. Two flashing aviation obstruction lights, located 7.0 km north and 6.3 km east from the observation point, were used as light sources, allowing spatiotemporal variations of NO(2) in Tokyo to be inferred. The LP-PDOAS data were compared with ground-based data measured using chemiluminescence. Surface wind data indicated that large inhomogeneities were present in the spatial NO(2) distributions under southerly wind conditions, while northerly wind conditions displayed greater homogeneity between the two systems. The higher correlation in the NO(2) mixing ratio between the two LP-PDOAS systems was observed under northerly wind conditions with a correlation factor R(2) = 0.88. We demonstrated that the combined deployment of two LP-PDOAS systems oriented in different directions provides detailed information on the spatial distribution of NO(2). 相似文献
75.
Of the two resting life-forms of the planktonic diatom Chaetoceros pseudocurvisetus Mangin formed during periods of nitrate depletion, resting spores survived at least 1 month after spore formation at 24 °C,
while resting cells survived only for about 10 d at the same temperature. Under nitrogen limitation, resting cells exhibited
higher specific death rates than resting spores at temperatures ranging from 5 to 30 °C. After nitrogen replenishment, resting
spores required a certain lag period of about 1 d to initiate vegetative growth at levels of nitrate supply from 0.5 to 20 M, while resting cells initiated vegetative growth almost immediately. Resting spores exhibited an intracellular accumulation
of the supplied nitrate during germination and initial vegetative growth. The resting cells, however, exhibited more active
vegetative growth, closely coupled with the uptake of the supplied nitrate. The resting spores and resting cells appear to
play different roles in the maintenance of populations under nutrient fluctuations depending on the interval length between
nutrient fluxes in natural waters.
Received: 27 April 1998 / Accepted: 1 March 1999 相似文献
76.
Tani T Arai R Nozoe S Tako Y Takahashi T Nakamura Y 《Journal of environmental radioactivity》2011,102(4):340-347
A dynamic compartment model was investigated to describe 14C accumulation in rice plants exposed to atmospheric 14C with temporally changing concentrations. In the model, rice plants were regarded to consist of three compartments: the ear and the mobile and immobile carbon pools of the shoot. Photosynthetically fixed carbon moves into the ear and the mobile carbon pool, and these two compartments release a part of this carbon into the atmosphere by respiration. Carbon accumulated in the mobile carbon pool is redistributed to the ear, while carbon transferred into the immobile carbon pool from the mobile one is accumulated there until harvest. The model was examined by cultivation experiments using the stable isotope, 13C, in which the ratios of carbon photosynthetically fixed at nine times during plant growth to the total carbon at the time of harvest were determined. The model estimates of the ratios were in relatively good agreement with the experimental observations, which implies that the newly developed compartment model is applicable to estimate properly the radiation dose to the neighboring population due to an accidental release of 14C from nuclear facilities. 相似文献
77.
Devanathan G Subramanian A Someya M Sudaryanto A Isobe T Takahashi S Chakraborty P Tanabe S 《Environmental pollution (Barking, Essex : 1987)》2009,157(1):148-154
The present study was carried out to understand the current contamination status of organochlorine compounds (OCs) in human breast milk from three metropolitan cities in India (New Delhi, Mumbai and Kolkata). Among the OCs analyzed, DDTs were predominant followed by HCHs and PCBs. CHLs and HCB levels were much lower. Contamination patterns were different in human milk found in our previous study in Chennai, a metropolitan city in southern India, indicating region specific exposure routes and variable sources. In comparison with previous data, levels of DDTs and HCHs generally declined with time, implying the effect of various bans and restrictions on their usage. No association between concentrations of OCs and demographic characteristics such as parity and age of mothers was observed which might be due to narrow range of mother's age. Estimated daily intake shows that some infants are exposed to OCs to a greater extent, particularly HCHs than the guideline standard. 相似文献
78.
Kazuhide Matsuda Yoshifumi Fujimura Kentaro Hayashi Akira Takahashi Ko Nakaya 《Atmospheric environment (Oxford, England : 1994)》2010,44(36):4582-4587
In order to increase knowledge of aerosol dry deposition for the regional assessment of acid deposition and transboundary air pollution in East Asia, an experimental study on PM2.5 sulfate deposition was implemented in the early summer of 2009. The experimental field was located in a deciduous forest at the foot of Mt. Asama, central Japan. Aerosol fluxes were obtained using the aerodynamic gradient method. Three aerosol samplers were placed on an experimental tower at 21, 24 and 27 m above the ground surface, and collected PM2.5 on filters for chemical analysis. Vertical concentration differences between 21 m and 27 m of PM2.5 sulfate were detected significantly when the concentration exceeded 1 μg m?3. Mean deposition velocity was estimated to be 0.9 ± 1.0 cm s?1 in the daytime and 0.3 ± 0.3 cm s?1 in the nighttime. In the case that a height-dependent correction in the roughness sub-layer was taken into account, the deposition velocities increased more, especially in daytime. Higher deposition velocities in the daytime were associated with larger friction velocities and unstable conditions. The deposition velocities observed in this study were in agreement with other experimental results found in the literature. On the other hand, they were higher than those calculated by theoretical models. Two empirical parameterizations (Wesely, M.L., Cook, D.R., Hart, R.L., 1985. Measurement and parameterization of particulate sulfur dry deposition over grass. Journal of Geophysical Research 90, 2131–2143; Ruijgrok, W., Tieben, H., Eisinga, P., 1997. The dry deposition of particles to a forest canopy: a comparison of model and experimental results. Atmospheric Environment 31, 399–415) were validated by the observations. The general trend of higher daytime and lower nighttime deposition velocities was similar among the observation and the two parameterizations. The large variability found in the measurement was not reproduced by the parameterizations, because it is attributable to random error from the differences between the samplers. The observations were in accordance with the parameterization of Ruijgrok et al. (1997) for a forest, although much larger than that of Wesely et al. (1985) for grasslands. This indicates the large difference in aerosol deposition velocities between forests and grasslands. 相似文献
79.
A three-dimensional/high-resolution transport model for persistent organic pollutants (POPs) has been developed for the East China Sea (ECS). The POPs model has four compartments (gaseous, dissolved, phytoplankton-bound, and detritus-bound phases) and includes processes for diffusive air-water exchange, phytoplankton uptake/depuration to POPs, decomposition of dissolved phase, vertical sinking of phytoplankton, detritus production by phytoplankton mortality, and vertical sinking and decomposition of detritus. The POPs model is coupled with an ocean circulation model that can reproduce the seasonal variation in physical variables to represent the advection and diffusion of POPs. We applied the POPs model to the polychlorinated biphenyl congener 153 (PCB 153) from the atmosphere and examined the behavior of PCB 153 in the ocean. The model showed a remarkable seasonal variability of PCB 153. Concentrations in the dissolved and particulate phases are high in winter (January-March) and low in summer (July-September). In coastal regions, where chlorophyll a concentration is high, horizontal and vertical distributions in the dissolved and particulate PCB 153 concentrations are strongly affected by phytoplankton uptake. The sensitivity experiments on the dynamics of PCB 153 suggested that a change of Henry’s law constant associated with water temperature is the major factor controlling the seasonal variability of PCB 153. The model-based yearly mass balance of PCB 153 in the ECS indicated that most of the atmospheric input (35.5 kg year−1) is removed by the horizontal advection outside the ECS (19.0 kg year−1) and accumulates to the sea bottom by vertical sinking (15.7 kg year−1). For comparison with PCB 153, we also conducted simulations for PCB 52, 101, and 180. The seasonal variations are similar to that of PCB 153. The mass balance of PCB 52 that has short half-life time and less hydrophobic property shows the different results compared with PCB 101, 153, and 180. 相似文献
80.
Umehara A Tsutsumi H Takahashi T 《Environmental science and pollution research international》2012,19(8):3257-3267