Restoration of cadmium-contaminated paddy soils by washing with ferric chloride: Cd extraction mechanism and bench-scale verification

The ability of FeCl3 to extract Cd from three paddy soils was compared with that of various irons, manganese, and zinc salts to elucidate the extraction mechanism. Manganese, zinc and iron salts (including FeCl3) extracted 4-41%, 8-44% and 24-66% of total Cd, respectively. This difference reflected the pH of the extraction solution, indicating that the primary mechanism of Cd extraction by FeCl3 is proton release coupled with hydroxide generation, as iron hydroxides are insoluble. Washing with FeCl3 led to the formation of Cd-chloride complexes, enhancing Cd extraction from the soils. FeCl3 effectively extracted Cd from all of the three soils compared to HCl that is a conventional washing chemical, when the concentrations of the two washing chemicals were between 15 and 60mM(c) (at above extraction pH 2.4), while the corresponding extraction pH of FeCl3 was slightly higher than HCl. As HCl is the strong acid of complete dissociation, if excess amount of HCl was added to soil, it is possible to give the dissolution of clay minerals in soils. In contrast, proton release from FeCl3 is controlled by the chemical equilibrium of hydroxide formation. While soil fertility properties were affected by a bench-scale soil washing with 45mM(c) FeCl3, adverse effects were not crucial and could be corrected. The bench-scale test confirmed the effectiveness of FeCl3 for removal of soil Cd. The washing had no negative effect on rice yield and lowered the Cd concentration of rice grain and rice straw in a pot experiment.     

Impact of the December 2004 tsunami on soil, groundwater and vegetation in the Nagapattinam district, India

The tsunami of 26 December 2004 struck the Nagapattinam District, Tamil Nadu, India. Sea water inundation from the tsunami caused salinization problems for soil and groundwater in coastal areas of the district, and also induced salt injuries in crops. To document the recovery of the agricultural environment from the tsunami, we conducted observations of the soil, groundwater, and vegetation. Soil electrical conductivity increased sharply after the tsunami, but returned to pre-tsunami levels the following year. Groundwater salinity returned to pre-tsunami levels by 2006. These rapid rates of recovery were due to the monsoon rainfall leaching salt from the highly permeable soils in the area. MODIS NDVI values measured before and after the tsunami showed that vegetation damaged by the tsunami recovered to its pre-tsunami state by the next rice cropping season, called samba, which starts from August to February. From these results, we conclude that the agricultural environment of the district has now fully recovered from the tsunami. Based on the results, we have also identified important management implications for soil, groundwater, and vegetation as follows: 1) due to the heavy monsoon rainfall and the high permeability of soils in this region, anthropogenic inputs like fertilizers should be applied carefully to minimize pollution, and the use of green manure is recommended; 2) areas that were contaminated by sea water extended up to 1000 m from the sea shore and over pumping of groundwater should be carefully avoided to prevent inducing sea water intrusion; and 3) data from a moderate resolution sensor of 250 m, such as MODIS, can be applied to impact assessment in widespread paddy field areas like the Nagapattinam District.     

Viable chemical recycling of poly(carbonate) as a phosgene equivalent illustrated by the coproduction of bisphenol A and carbohydrate carbonates

Chemical recycling of waste poly(carbonate) (PC) to coproduce bisphenol A (BPA) and carbohydrate carbonates was studied by selecting glycerol (Gly) and glucose (Glu) as model carbohydrates (CHs). In advance of the reaction of PC with CHs, reactions with diphenyl carbonate were examined as a model PC. In dioxane at 100°C using NaOH as catalyst, Gly was converted to cyclic carbonate hydroxymethyldioxolane (HMDO) at 98% and Glu was converted to the dicarbonate (Glu-DC) at 46%, in pyridine, in addition to the production of phenol. Similar treatment of PC with Gly using KOH as a catalyst produced HMDO and BPA at very high yields and treatment with Glu produced Glu-DC and BPA in 38%–42% yields. Chemical Feedstock Recycling & Other Innovative Recycling Techniques 6     

Subcellular distribution of trace elements in kidney of a mother-fetus pair of Dall's porpoises (Phocoenoides dalli)

Total and subcellular renal Zn, Cu, Se, Mn, V, Hg, Cd and Ag were determined by a mother-fetus pair of Dall's porpoises (Phocoenoides dalli). All element concentrations in the maternal individual were higher than those in the fetal individual. Most of total renal elements studied were present in the cytosol of both animals. In maternal cytosol, Mn, Hg and Ag were present in high molecular weight substances (HMW); Se was in low molecular weight substances (LMW); Zn, Cu, and Cd were in metallothionein (MT), mostly; and the distribution of V in percentage among the three renal cytosolic fractions was similar. In fetal cytosol, Zn, Mn, Hg, V, Cd, and Ag were present in HMW, Cu was present in MT, mostly. In contrast, Se was observed mostly in both LMW and HMW. MT isoforms were characterized. Three obvious peaks in retention time were found in either the maternal or fetal MT. The highest elemental ion intensities were in the 7.8min peak for the mother, and in the 4.3min peak for the fetus, respectively, implying that different MT isoforms may be closely associated with elemental accumulation between maternal and fetal renal cytosols.     

Sustainability education and a new master’s degree, the master of sustainability science: the Graduate Program in Sustainability Science (GPSS) at the University of Tokyo

The University of Tokyo started its Graduate Program in Sustainability Science (GPSS), offering a master of sustainability science degree, in 2007. The GPSS curriculum consists of: (1) knowledge and concept oriented courses, which cover sustainability-related subjects from a holistic viewpoint; (2) experiential learning and skills oriented practical courses, which offer practical exercises to acquire the skills and sensibility required of future leaders; and (3) the Master’s thesis, for which students are encouraged to address complex sustainability problems through a transdisciplinary approach. Sustainability science is not a discipline that can be defined simply by the subjects it deals with, but is an academic field characterized by core principles that include holistic thinking, transdisciplinarity, and respect for diversity. The GPSS has been designed so that students may gain the capacity to understand and practice these principles. The present paper describes how the GPSS has defined sustainability education and designed its curriculum accordingly.     

Concentrations of polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, and dioxin-like polychlorinated biphenyls in blood collected from 195 pregnant women in Sapporo City, Japan

We measured the concentrations of polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), non-ortho coplanar polychlorinated biphenyls (non-ortho PCBs), and mono-ortho coplanar polychlorinated biphenyls (mono-ortho PCBs) in blood collected between 2002 and 2004 from 195 pregnant women living in Sapporo City of Hokkaido Prefecture, Japan. The present study is one of the few studies in which PCDDs, PCDFs, and dioxin-like PCBs have been measured in the blood of pregnant women. Of the 195 pregnant women, 101 were primipara (mean: 28.8 years) and 94 were multipara (mean: 32.4 years). The arithmetic mean total TEQ concentrations of PCDDs, PCDFs, non-ortho PCBs, and mono-ortho PCBs of primiparous and multiparous mothers in Sapporo City were 17.4 (median: 15.7) and 14.0 (median: 13.9)pgTEQ/glipid, respectively, and the concentrations were in the range of 6.6-43.4 and 3.4-28.2pgTEQ/glipid, respectively. In regard to the relationship between the total TEQ concentrations of PCDDs, PCDFs, non-ortho PCBs, and mono-ortho PCBs in maternal blood and the number of deliveries or age of primiparous and multiparius mothers, the levels of these dioxin-like compounds tended to decrease with increases in the number of deliveries and significantly increased with increasing maternal age in both groups. Furthermore, significant correlations were observed between the total TEQ concentrations of these dioxin-like compounds and the age of primiparae and multiparae. The total TEQ concentration of PCDDs, PCDFs, non-ortho PCBs, and mono-ortho PCBs measured in 195 pregnant women has decreased compared to past levels in Japan for the last several decades. The results of the present study have indicated that dioxin contamination in the blood of young women in Japan is continuing to decrease.     

Immunologic effects of perinatal exposure to dioxins, PCBs and organochlorine pesticides in Japanese infants

Effects of perinatal exposure to dioxins, PCBs and organochlorine pesticides on lymphocyte subsets were investigated in the peripheral blood from 101 Japanese infants with approximately 10 months of age. Perinatal exposure to these organochlorine compounds were estimated by their contamination levels in the breast milk of the mothers. Lymphocyte subsets such as CD16+, HLA-DR+, CD4+, CD4+8+, CD8+, CD3+ and CD20+ cells in peripheral venous blood were assessed in a subgroup of 92 infants. Greater exposures to HCE, chlordane and dioxins were significantly associated with the increase in the percentages of CD8+ and CD3+ T lymphocytes and CD4+/CD8+ T cell ratios, respectively. In addition, higher HCH exposure was also associated with a decrease in the percentage of HLA-DR+ T lymphocytes. Furthermore effects of dioxins, DDT and PCBs on the percentage of CD16+ T lymphocyte were more pronounced by the combined exposure of dioxins and PCBs or by the combined exposure of DDT and PCBs. Effects of HCE on the percentages of CD8+ T lymphocyte were also more pronounced by the combined exposure of HCE and chlordane. In conclusion, our study suggests that greater exposures to dioxins, PCBs and organochlorine pesticides determined in this study (except dieldrin) influence the immune system of Japanese infant, although the clinical significance of these changes is uncertain.     

The input-output balance of cadmium in a paddy field of Tokyo

Field monitoring was practiced from 2001 to 2003 to evaluate the input (irrigation, atmospheric deposition, and fertilizer application) and the output (uptake and accumulation into the above-ground biomass of rice plants and leaching) of cadmium (Cd) in a contaminated paddy field in Tokyo. The cadmium concentrations of irrigated water, open-bulk precipitation, soil solution (leaching water), rice plants collected at the harvesting stage and the chemical fertilizer and the cow manure compost applied were determined. The Cd flux of each factor was calculated by multiplying the Cd concentration by the volume or mass of the media. The annual input-output balance of Cd in the paddy field in 2001 and 2002 was estimated to be -5.44 [corrected] g ha(-1) and -2.01 [corrected] g ha(-1), respectively, indicating the loss of Cd from the paddy field, although the losses accounted for only 0.24% [corrected] and 0.089% [corrected] of the total amount of Cd in the ploughed layer soil in 2001 and 2002, respectively. Among the factors involved, the input from fertilizers (including manure compost) and the output due to the uptake by rice plants played a major role in the balance. The former largely depended on the types and amounts of fertilizers applied, and the latter on the water management practices in the paddy field, such as flooding and drainage of the surface water.     

Factors affecting the degradation of amoxicillin in composting toilet

The biological and non-biological factors that affect the degradation of amoxicillin in the composting process of feces have been investigated. The effect of living bacteria and the enzyme (beta-lactamase) on amoxicillin decay was examined, and our results indicated that the biological effects are likely to be negligible. Consequently, the effect of phosphate, ammonia and pH level as non-biological factors was investigated by monitoring the reduction rate of amoxicillin in phosphate and ammonia buffer solutions with several pH levels. Each reduction rate constant was integrated by a simulation model, and the each calculated amoxicillin reduction profile was compared to the reduction profiles of amoxicillin in the composting process of feces. The calculated results corresponded almost exactly to the experimental profiles. We therefore concluded that the degradation of amoxicillin in a toilet matrix was dependent on the concentration of ammonia, phosphate and hydroxyl ion.     

Conflicting views on opposition to LULUs: distributive justice in three Japanese cases of waste disposal facility siting

Local residents often oppose some types of facilities because of their negative side effects, even though they are claimed to be necessary for the public good. These facilities are known as locally unwanted-land-uses, and local opposition to them is often referred to as not-in-my-backyard, usually with a pejorative connotation. However, some studies have challenged this conventional view of local opposition. Given these conflicting views, the present article explores how local mobilisation should be evaluated, focusing particularly on distributive justice. First, the study illuminates how different interpretations of distributive justice lead to difference in views on local opposition. Then, by comparing three waste disposal facility cases in Japan, a distinction between cost sharing and cost overlapping cases is illuminated. The study further develops discussions by pointing out the limits of using this distinction to evaluate local opposition movements and provides insights that can contribute to a fuller understanding of siting conflicts.