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11.
Aikawa M Hiraki T Tamaki M Kasahara M Kondo A Uno I Mukai H Shimizu A Murano K 《Environmental monitoring and assessment》2006,122(1-3):61-79
An intensive field survey, with 6-h measurement intervals, of concentrations of chemical species in particulate matter and gaseous compounds was carried out at coastal sites on the Sea of Japan during winter. The concentration variation of SO2(g) and HNO3(g) were well correlated, whereas the NH3(g) concentration variation had no correlation with those of SO2(g) and HNO3(g). The NH4
+ (p)/non-sea-salt- (nss-)SO4
2 −(p) ratio in particulate matter was mainly affected by the location of the sampling site. One or more concentration peaks of nss-Ca2 + for survey period were observed. Backward trajectories analyses for the highest nss-Ca2 + concentration peaks showed some inconsistency in pathways. We consider that insufficient mixing of the atmosphere and/or insufficient time for the transported air pollutants to react with those discharged locally are the most likely explanations for the discrepancies between the measured products [HNO3][NH3] and the calculated values. 相似文献
12.
Masahide Aikawa Toshimasa Ohara Takatoshi Hiraki Okihiro Oishi Akihiro Tsuji Makiko Yamagami Kentaro Murano Hitoshi Mukai 《Atmospheric environment (Oxford, England : 1994)》2010,44(3):381-391
We found a significant geographic gradient (longitudinal and latitudinal) in the sulfate (SO42?) concentrations measured at multiple sites over the East Asian Pacific Rim region. Furthermore, the observed gradient was well reproduced by a regional chemical transport model. The observed and modeled SO42? concentrations were higher at the sites closer to the Asian continent. The concentrations of SO42? from China as calculated by the model also showed the fundamental features of the longitudinal/latitudinal gradient. The proportional contribution of Chinese SO42? to the total in Japan throughout the year was above 50–70% in the control case, using data for Chinese sulfur dioxide (SO2) emission from the Regional Emission Inventory in Asia (40–60% in the low Chinese emissions case, using Chinese SO2 emissions data from the State Environmental Protection Administration of China), with a winter maximum of approximately 65–80%, although the actual concentrations of SO42? from China were highest in summer. The multiple-site measurements and the model analysis strongly suggest that the SO42? concentrations in Japan were influenced by the outflow from the Asian continent, and this influence was greatest in the areas closer to the Asian continent. In contrast, we found no longitudinal/latitudinal gradient in SO2 concentrations; instead SO2 concentrations were significantly correlated with local SO2 emissions. Our results show that large amounts of particulate sulfate are transported over long distances from the East Asian Pacific Rim region, and consequently the SO42? concentrations in Japan are controlled by the transboundary outflow from the Asian continent. 相似文献
13.
The amount of dry deposition of SO2(g) and HNO3(g) in an urban area in Japan has been estimated by the inferential method. The mean annual dry deposition of SO2(g) (2.91 kgS/ha/year) was close to or less than that in the Clean Air Status and Trends Network (CASTNet) of the U.S. (3.59 kgS/ha/year).
The mean annual dry deposition of HNO3(g) (10.8 kgN/ha/year) was approximately six times larger than that in CASTNet (1.85 kgN/ha/year). The proportions of dry/(dry+wet)
deposition for sulfur and nitrogen were 0.301 and 0.785, respectively. 相似文献