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1.
A fragment constant QSAR model for evaluating the EC50 values of organic chemicals to Daphnia magna.
Shu Tao Xiaohuan Xi Fuliu Xu Bengang Li Jun Cao R Dawson 《Environmental pollution (Barking, Essex : 1987)》2002,116(1):57-64
The quantitative relationship between the median effective concentration (EC50) of organic chemicals to Daphnia magna and the number of molecular fragments was investigated based on experimental EC50 values for 217 chemicals derived from the literature. A fragment constant model was developed based on a multivariate linear regression between the number of fragments and the logarithmically transformed reciprocal values of EC50. Functional correction factors were introduced into the model. The model was verified using an independent set of randomly selected data. The mean residual of the final model was 0.4 log-units. The robustness of the model was discussed based on the results of three jackknife tests. 相似文献
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Hiroshi Yamamoto Yudai Nakamura Yuki Nakamura Chise Kitani Tetsuya Imari Jun Sekizawa Yuji Takao Naoyuki Yamashita Narisato Hirai Shigeto Oda Norihisa Tatarazako 《Environmental sciences》2007,14(4):177-193
Eight pharmaceuticals were selected on the basis of their domestic consumption in Japan, the excretion ratio of the parent compound and the frequency of detection in the aquatic environment or wastewater treatment plant effluent. Toxicity tests on these pharmaceuticals were conducted using Japanese medaka (Oryzias latipes), daphnia (Daphnia magna), and green algae (Psuedokirchneriella subcapitata). Predicted no effect concentration (PNEC) was calculated using lethal or effect concentration 50 (LC50 or EC50) values and no effect concentration (NOEC) obtained in the toxicity tests for these compounds. Predicted environmental concentration (PEC) was also calculated from annual consumption, the excretion rate of the parent compound, and removal rate in the preliminary batch activated sludge treatment performed in this study. Maximum concentrations found in the aquatic environment or sewage effluent in Japan or foreign countries were also used for another calculation of PEC. Initial risk assessment on the selected pharmaceuticals was performed using the PEC/PNEC ratio. The results of initial risk assessment on the eight selected pharmaceuticals suggest neither urgent nor severe concern for the ecological risk of these compounds, but further study needs to be conducted using chronic toxicity tests, including reproduction inhibition and endocrine disruption assessments. 相似文献
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正确评价干洗剂对人体的毒副作用,合理地设定干洗过程挥发性有害物质的残留限量,是开发干洗业环境无害技术和绿色服务的先决条件。只有在充分保证环境安全的前提下,通过逐步推行化学清洁产品的总体选择战略,从环境管理和经济发展的结合上来规范企业的环境行为,才能最终实现干洗业的可持续发展。 相似文献
5.
炼油厂污水处理负荷的削减措施 总被引:1,自引:0,他引:1
总结和分析了某厂削减污水处理负荷的主要措施及效益,预测该厂在达到16000kt/a以上加工规模时的污水处理负荷。 相似文献
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喷射溶气回流浮选工艺处理含油废水 总被引:8,自引:0,他引:8
采用喷射溶气回流浮选工艺处理含油废水,替代原来的全加压溶气浮选工艺,提高了浮选过程的处理效果,增强了系统的抗负荷冲击能力,浮选出水油含量由原来的〈40mg/L降至〈20mg/L,COD由原来的〈150mg/L降至〈110mg/L。 相似文献
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M. R. Theobald U. Dragosits C. J. Place J. U. Smith M. Sozanska L. Brown D. Scholefield A. Del Prado J. Webb P. G. Whitehead A. Angus I. D. Hodge D. Fowler M. A. Sutton 《Water, Air, & Soil Pollution: Focus》2004,4(6):135-142
The distribution and impacts of different nitrogen pollutants are inextricably linked. To understand the problem fully, the interactions between the different pollutants need to be taken into account. This is particularly important when it comes to abatement techniques, since measures to reduce emissions of one nitrogen pollutant can often lead to an increase in another. This project represents a step towards greater understanding of these issues by linking together new and existing nitrogen flux models into a larger framework. The modelling framework has been constructed and some of the nitrogen flows between fields, farms and the atmosphere have been modelled for a UK study area for typical farm management scenarios. 相似文献
10.
Davey L. Jones John F. Farrar Kevin K. Newsham 《Water, Air, & Soil Pollution: Focus》2004,4(6):169-175
Amino acids constitute one of the largest inputs of organic nitrogen (N) to most polar soils and have been hypothesized to be important in regulating vegetational succession and productivity in Arctic ecosystems. Our understanding of amino acid cycling in these soils, however, is poor. The aim of this study was to investigate the size and rate of turnover of the amino acid pool in a range of Arctic and Antarctic soils. Our results indicate that in polar soils with either high or low ornithogenic inputs the amino acid pool is small in comparison to the inorganic N pool (NO–3 and NH+4). The free amino acid pool constituted only a small proportion of the total dissolved organic nitrogen (DON) pool in these soils. Here we show that these low concentrations may be due to rapid use by the soil microbial community in both Arctic and Antarctic soils. The turnover of the amino acid pool in soil was extremely rapid, with a half-life ranging from 2 to 24 h, indicating that this N pool can be turned over many hundred times each summer when polar soils are frequently unfrozen. The implications of amino acids in N cycling and plant and microbial nutrition are discussed. 相似文献