Tight sorption of arsenic,cadmium, mercury,and lead by edible activated carbon and acid-processed montmorillonite clay

Environmental Science and Pollution Research - Heavy metal exposure in humans and animals commonly occurs through the consumption of metal-contaminated drinking water and food. Although many...     

A miniature gas chromatograph for atmospheric monitoring

The techniques of integrated circuit processing have been utilized to miniaturize the main components of a gas chromatography system. A 1.5-m long separating column, sample injection valve, and output thermal conductivity detector are all fabricated on a single 5-cm diameter silicon wafer. These components are combined with a sophisticated microcomputer system, to form an advanced, portable gas analysis and data logging system. The present prototype instrument package is about 20×22×10 cm and weighs about 3 kg. The instrument is capable of automatically sampling the air at one minute intervals during an 8 h shift, measuring the concentrations of up to 10 different gases, calculating and storing the average and peak concentrations of those gases, and sounding an alarm if potentially dangerous environmental conditions are detected. It can also be used as a survey instrument to take and analyze samples and provide concentration information within 30 sec of sampling. The small size, advanced capabilities, and ease of operation of the system should have a significant impact on the fields of industrial hygiene and occupational safety and health. The instrument will greatly expand the ability to monitor workers' exposures to toxic gases and therefore aid in the reduction of such exposures, and provide better epidemiological data in future health studies.     

Consistency of implications of three role stressors across four countries

Relationships between role stressors (ambiguity, overload, and conflict), anxiety, commitment (affective and continuance), and turnover intention were examined. These variables were measured via a survey of 1396 nurses in a total of 15 hospitals in Hungary, Italy, the United Kingdom, and the United States. Three role stressors were expected to predict anxiety and indirectly predict intention to leave. Anxiety was expected to predict affective and continuance commitment, and anxiety, affective commitment, and continuance commitment were expected to predict intention to leave the hospital. Although mean score differences were expected across countries, direction of the relationships between variables were expected to be the same, which would indicate consistency regarding the implications of three role stressors across countries. AMOS's structural equations modeling program was used to test a multi‐group manifest variable path analysis. Results yielded support for the proposed relationships (NFI = 0.93; TLI = 0.89). It was tentatively concluded that stress is a culture‐general process. Copyright © 2005 John Wiley & Sons, Ltd.     

A SYSTEMS RESOURCES APPROACH TO CITIZEN PARTICIPATION: THE CASE OF THE CORPS OF ENGINEERS1

ABSTRACT: The thesis of this paper is that the citizen participation process provides necessary, but not sufficient conditions to affect substantive change in federal water resource management agencies' planning and decisionmaking. That is, in its present form, the citizen participation process has been observed to occur outside of the normal decision arenas of federal resource management agencies. The paper reviews concepts of citizen participation and defines some theoretical problems inherent with them. Then, a strategy for the structuring of a citizen participation process is proposed. This strategy is based upon the notion that citizen support for federally sponsored programs are essential if such projects are to be implemented. Therefore, an approach which integrates citizen valves with those held by other institutions and the agency is suggested. In conclusion, the relevancy of actively developing and including citizen input to the water resource planning process is illustrated by a discussion of three cases of the Corps of Engineers and Urban Studies planning process, in different metropolitan regions.     

In situ reduction of chromium(VI) in heavily contaminated soils through organic carbon amendment

Chromium has become an important soil contaminant at many sites, and facilitating in situ reduction of toxic Cr(VI) to nontoxic Cr(III) is becoming an attractive remediation strategy. Acceleration of Cr(VI) reduction in soils by addition of organic carbon was tested in columns pretreated with solutions containing 1000 and 10 000 mg L(-1) Cr(VI) to evaluate potential in situ remediation of highly contaminated soils. Solutions containing 0,800, or 4000 mg L(-1) organic carbon in the form of tryptic soy broth or lactate were diffused into the Cr(VI)-contaminated soils. Changes in Cr oxidation state were monitored through periodic micro-XANES analyses of soil columns. Effective first-order reduction rate constants ranged from 1.4 x 10(-8) to 1.5 x 10(-7) s(-1), with higher values obtained for lower levels of initial Cr(VI) and higher levels of organic carbon. Comparisons with sterile soils showed that microbially dependent processes were largely responsible for Cr(VI) reduction, except in the soils initially exposed to 10 000 mg L(-1) Cr(VI) solutions that receive little (800 mg L(-1)) or no organic carbon. However, the microbial populations (< or = 2.1 x 10(5) g(-1)) in the viable soils are probably too low for direct enzymatic Cr(VI) reduction to be important. Thus, synergistic effects sustained in whole soil systems may have accounted for most of the observed reduction. These results show that acceleration of in situ Cr(VI) reduction with addition of organic carbon is possible in even heavily contaminated soils and suggest that microbially dependent reduction pathways can be dominant.     

Selenium removal and mass balance in a constructed flow-through wetland system

A field study on the removal of Se from agricultural subsurface drainage was conducted from May 1997 to February 2001 in the Tulare Lake Drainage District (TLDD) of San Joaquin Valley, California. A flow-through wetland system was constructed consisting of ten 15- x 76-m unlined cells that were continuously flooded and planted with either a monotype or combination of plants, including sturdy bulrush [Schoenoplectus robustus (Pursh) M.T. Strong], baltic rush (Juncus balticus Willd.), smooth cordgrass (Spartina alterniflora Loisel.), rabbitsfoot grass [Polypogon monspeliensis (L.) Desf.], salt-grass lDistichlis spicata (L.) Greene], cattail (Typha latifolia L.), tule [Schoenoplectus acutus (Muhl. ex Bigelow) A. L?ve & D. L?ve], and widgeon grass (Ruppia maritima L.). One cell had no vegetation planted. The objectives of this research were to evaluate Se removal efficiency of each wetland cell and to carry out a mass balance on Se. The inflow drainage water to the cells had average annual Se concentrations of 19 to 22 microg L(-1) dominated by selenate [Se(VI), 95%]. Average weekly water residence time varied from about 3 to 15 d for Cells 1 through 7 (target 7 d), 19 to 33 d for Cells 8 and 9 (target 21 d), and 13 to 18 d for Cell 10 (target 14 d). Average weekly Se concentration ratios of outflow to inflow ranged from 0.45 to 0.79 and mass ratio (concentration x water volume) from 0.24 to 0.52 for year 2000, that is, 21 to 55% reduction in Se concentration and 48 to 76% Se removal in mass by the wetland, respectively. The nonvegetated cell showed the least Se removal both in concentration and in mass. The global mass balance showed that on the average about 59% of the total inflow Se was retained within the cells and Se outputs were outflow (35%), seepage (4%), and volatilization (2%). Independent measurements of the Se retained in the cells totaled 53% of the total Se inflow: 33% in the surface (0-20 cm) sediment, 18% in the organic detrital layer above the sediment, 2% in the fallen litter, < 1% in the standing plants, and < 1% in the surface water. Thus, about 6% of the total Se inflow was unaccounted for in the internal compartments.     

Distribution of chromium contamination and microbial activity in soil aggregates

Biogeochemical transformations of redox-sensitive chemicals in soils can be strongly transport-controlled and localized. This was tested through experiments on chromium diffusion and reduction in soil aggregates that were exposed to chromate solutions. Reduction of soluble Cr(VI) to insoluble Cr(II) occurred only within the surface layer of aggregates with higher available organic carbon and higher microbial respiration. Sharply terminated Cr diffusion fronts develop when the reduction rate increases rapidly with depth. The final state of such aggregates consists of a Cr-contaminated exterior, and an uncontaminated core, each having different microbial community compositions and activity. Microbial activity was significantly higher in the more reducing soils, while total microbial biomass was similar in all of the soils. The small fraction of Cr(VI) remaining unreduced resides along external surfaces of aggregates, leaving it potentially available to future transport down the soil profile. Using the Thiele modulus, Cr(VI) reduction in soil aggregates is shown to be diffusion rate- and reaction rate-limited in anaerobic and aerobic aggregates, respectively. Thus, spatially resolved chemical and microbiological measurements are necessary within anaerobic soil aggregates to characterize and predict the fate of Cr contamination. Typical methods of soil sampling and analyses that average over redox gradients within aggregates can erase important biogeochemical spatial relations necessary for understanding these environments.     

Analysis of transgenic Indian mustard plants for phytoremediation of metal-contaminated mine tailings

Transgenic Indian mustard [Brassica juncea (L.) Czern.] plants overproducing the enzymes gamma-glutamylcysteine synthetase (ECS) or glutathione synthetase (GS) were shown previously to have increased levels of the metal-binding thiol peptides phytochelatins and glutathione, and enhanced Cd tolerance and accumulation. Furthermore, transgenic Indian mustard plants overexpressing adenosine triphosphate sulfurylase (APS) were shown to have higher levels of glutathione and total thiols. These results were obtained with a solution culture. To better examine the phytoremediation potential of these transgenics, a greenhouse experiment was performed in which the transgenics were grown on metal-contaminated soil collected from a USEPA Superfund site near Leadville, Colorado. A grass mixture used for revegetation of the site was included for comparison. The ECS and GS transgenics accumulated significantly (P < 0.05) more metal in their shoot than wild-type (WT) Indian mustard, while the APS plants did not. Of the six metals tested, the ECS and GS transgenics accumulated 1.5-fold more Cd, and 1.5- to 2-fold more Zn, compared with wild-type Indian mustard. Furthermore, the ECS transgenics accumulated 2.4- to 3-fold more Cr, Cu, and Pb, relative to WT. The grass mixture accumulated significantly less metal than Indian mustard: approximately 2-fold less Cd, Cu, Mn, and Zn, and 5.7-fold less Pb than WT Indian mustard. All transgenics removed significantly more metal from the soil compared with WT Indian mustard or an unplanted control. While WT did not remove more metal than the unplanted control for any of the metals tested, all three types of transgenics significantly reduced the soil metal concentration, and removed between 6% (Zn) and 25% (Cd) of the soil metal. This study is the first to demonstrate enhanced phytoextraction potential of transgenic plants using polluted environmental soil. The results confirm the importance of metal-binding peptides for plant metal accumulation and show that results from hydroponic systems have value as an indicator for phytoremediation potential.     

A REEVALUATION OF THE GROUND WATER BUDGET FOR LAS VEGAS VALLEY,NEVADA, WITH EMPHASIS ON GROUND WATER DISCHARGE1

ABSTRACT: An essential component to the ground water budget for the Las Vegas Valley (LVV) in southern Nevada is discharge from the ground water system. Discharge for the LW has been based on estimates made more than 50 years ago of 35,524,224 m3 per year as evapotranspiration (ET) and 0 m³ per year as subsurface outflow. Newly published values for recharge based on a more robust data set (70,308,360 m³) indicate a large imbalance associated with the earlier discharge estimates, providing the basis for the reevaluation conducted in this study. ET estimates in this study, as opposed to previous studies, were assigned a range in values that included an approach that assigned higher weight to the unique soil, plant, water, and climatic conditions that existed in predevelopment (1905) LW. The earlier discharge estimates also assumed that the basin was hydrologically closed; however, based on our evaluation, a range in yearly discharge by subsurface outflow from 1,480,176 m³ to 19,735,680 m³ could be assigned. Likewise, a range in yearly ET from 20,475,768 m³ to 78,819,372 m³ could be assigned. Based on newly published recharge values, closure can only occur if higher values are assigned to both the subsurface outflow and/or ET components of ground water discharge. We cannot provide a complete water balance closure with our ground water discharge estimate of 64,140,960 m³. However our reevaluation gives support to the higher recharge estimates and provides the rationale for future studies to be conducted based on a more rigorous scientific assessment.     

Evaluating environmental plan quality: the case of planning for sustainable development in New Zealand

This study examines the quality of local and regional environmental plans produced under New Zealand's Resource Management Act (RMA) of 1991, which sets forth a national sustainable development strategy. Plan quality characteristics are defined and used as criteria for plan evaluation. A key finding is that planning programmes have significantly advanced since passage of the RMA, but that high quality plans are not necessarily produced by simply passing mandate legislation. Implications of study findings for sustainable development initiatives in other countries and for future research are presented.