The status and distribution of PCBs along the coast of Vietnam

Environmental Geochemistry and Health - Polychlorinated biphenyls (PCBs), well-known as an important scientific achievement, are now considered as one of the most persistent organic pollutants...     

Sediment measurement and transport modeling: impact of riparian and filter strip buffers

Well-calibrated models are cost-effective tools to quantify environmental benefits of conservation practices, but lack of data for parameterization and evaluation remains a weakness to modeling. Research was conducted in southwestern Oklahoma within the Cobb Creek subwatershed (CCSW) to develop cost-effective methods to collect stream channel parameterization and evaluation data for modeling in watersheds with sparse data. Specifically, (i) simple stream channel observations obtained by rapid geomorphic assessment (RGA) were used to parameterize the Soil and Water Assessment Tool (SWAT) model stream channel variables before calibrating SWAT for streamflow and sediment, and (ii) average annual reservoir sedimentation rate, measured at the Crowder Lake using the acoustic profiling system (APS), was used to cross-check Crowder Lake sediment accumulation rate simulated by SWAT. Additionally, the calibrated and cross-checked SWAT model was used to simulate impacts of riparian forest buffer (RF) and bermudagrass [ (L.) Pers.] filter strip buffer (BFS) on sediment yield and concentration in the CCSW. The measured average annual sedimentation rate was between 1.7 and 3.5 t ha yr compared with simulated sediment rate of 2.4 t ha yr Application of BFS across cropped fields resulted in a 72% reduction of sediment delivery to the stream, while the RF and the combined RF and BFS reduced the suspended sediment concentration at the CCSW outlet by 68 and 73%, respectively. Effective riparian practices have potential to increase reservoir life. These results indicate promise for using the RGA and APS methods to obtain data to improve water quality simulations in ungauged watersheds.     

A GIS Approach to Prioritizing Habitat for Restoration Using Neotropical Migrant Songbird Criteria

Restoration efforts to increase wildlife habitat quality in agricultural landscapes have limited funding and are typically done on a first come, first serve basis. In order to increase the efficiency of these restoration efforts, a prioritized ranking system is needed to obtain the greatest increase in habitat quality possible for the fewest amount of hectares restored. This project examines the use of a GIS based multi-criteria approach to prioritize lands for reforestation along the Kaskaskia River in Illinois. Loss of forested area and corresponding increase in forest fragmentation has decreased songbird habitat quality across the Midwestern United States. We prioritized areas for reforestation based on nine landscape metrics: available agricultural land, forest cover gaps, edge density, proximity to river, 200 m corridor area, total forest core area, fringe core area, distance to primary core value, and primary core area. The multi-criteria analysis revealed that high priority areas for reforestation were most likely to be close to the riparian corridor and existing large blocks of forest. Analysis of simulated reforestation (0, 0.5, 1.0, 5.0 10.0, 25.0, and 50.0% of highest priority parcels reforested) revealed different responses for multiple landscape metrics used to quantify forest fragmentation following reforestation, but indicated that the study area would get the greatest rate of return on reforestation efforts by reforesting 10.0% of the highest priority areas. This project demonstrates how GIS and a multi-criteria analysis approach can be used to increase the efficiency of restoration projects. This approach should be considered by land managers when attempting to identify the location and quantity of area for restoration within a landscape.     

Impacts of Land‐Cover Change on Suspended Sediment Transport in Two Agricultural Watersheds1

Schilling, Keith E., Thomas M. Isenhart, Jason A. Palmer, Calvin F. Wolter, and Jean Spooner, 2011. Impacts of Land‐Cover Change on Suspended Sediment Transport in Two Agricultural Watersheds. Journal of the American Water Resources Association (JAWRA) 47(4):672‐686. DOI: 10.1111/j.1752‐1688.2011.00533.x Abstract: Suspended sediment is a major water quality problem, yet few monitoring studies have been of sufficient scale and duration to assess the effectiveness of land‐use change or conservation practice implementation at a watershed scale. Daily discharge and suspended sediment export from two 5,000‐ha watersheds in central Iowa were monitored over a 10‐year period (water years 1996‐2005). In Walnut Creek watershed, a large portion of land was converted from row crop to native prairie, whereas in Squaw Creek land use remained predominantly row crop agriculture. Suspended sediment loads were similar in both watersheds, exhibiting flashy behavior typical of incised channels. Modeling suggested that expected total soil erosion in Walnut Creek should have been reduced 46% relative to Squaw Creek due to changes in land use, yet measured suspended sediment loads showed no significant differences. Stream mapping indicated that Walnut Creek had three times more eroding streambank lengths than did Squaw Creek suggesting that streambank erosion dominated sediment sources in Walnut Creek and sheet and rill sources dominated sediment sources in Squaw Creek. Our results demonstrate that an accounting of all sources of sediment erosion and delivery is needed to characterize sediment reductions in watershed projects combined with long‐term, intensive monitoring and modeling to account for possible lag times in the manifestation of the benefits of conservation practices on water quality.     

Effect of citric acid and EDTA on chromium and nickel uptake and translocation by Datura innoxia

EDTA and citric acid were tested to solubilize metals and enhance their uptake by Datura innoxia, chosen because of its ability to accumulate and tolerate metals. Two application modes were used on an industrial soil contaminated mainly by Cr and Ni. The results showed that citric acid was the most effective at increasing the uptake of Cr and EDTA for Ni. These results are consistent with the effectiveness of both chelants in solubilizing metals from the soil. The translocation factor (TF) of Ni was 1.6- and 6.7-fold higher than the control, respectively, for one and two applications of 1mmolkg(-1) EDTA. After two applications of 5 and 10mmolkg(-1) citric acid, the TF of Cr increased 2- and 3.5-fold relative to the control. Whatever the concentration, the application of EDTA modified the plant physiology significantly. For citric acid this was only observed with the highest dose (10mmolkg(-1)).     

The CPCAT as a novel tool to overcome the shortcomings of NOEC/LOEC statistics in ecotoxicology: a simulation study to evaluate the statistical power

Species reproduction is an important determinant of population dynamics. As such, this is an important parameter in environmental risk assessment. The closure principle computational approach test (CPCAT) was recently proposed as a method to derive a NOEC/LOEC for reproduction count data such as the number of juvenile Daphnia. The Poisson distribution used by CPCAT can be too restrictive as a model of the data-generating process. In practice, the generalized Poisson distribution could be more appropriate, as it allows for inequality of the population mean \(\mu\) and the population variance \(\sigma ^2\). It is of fundamental interest to explore the statistical power of CPCAT and the probability of determining a regulatory relevant effect correctly. Using a simulation, we varied between Poisson distribution (\(\mu =\sigma ^2\)) and generalized Poisson distribution allowing for over-dispersion (\(\mu <\sigma ^2\)) and under-dispersion (\(\mu >\sigma ^2\)). The results indicated that the probability of detecting the LOEC/NOEC correctly was \(\ge 0.8\) provided the effect was at least 20% above or below the mean level of the control group and mean reproduction of the control was at least 50 individuals while over-dispersion was missing. Specifically, under-dispersion increased, whereas over-dispersion reduced the statistical power of the CPCAT. Using the well-known Hampel identifier, we propose a simple and straight forward method to assess whether the data-generating process of real data could be over- or under-dispersed.     

基于环境逸度模型的化学物质暴露与风险评估研究进展

工业化学品通过各种迁移转化过程后在环境区间中广泛分布,同时新化学品正被大量的生产并进入环境,使得对于化学品管控的需求和压力不断增加。基于这一背景,多国政府颁布了相应的政策法规对化学品进行管控。除了用相应的政策法规进行预先管控之外,使用基于逸度概念的多介质环境模型来表征化学品的行为与归趋是一个相对简单而有效的方法,不仅适用于环境中存在的现有化学品的暴露评估,也成为各国化学品管理中对新化学品的环境暴露进行预测的有力工具。本文综述逸度概念与方法、相关环境模型、建模过程、应用验证等方面的国内外研究进展,希望能够对我国化学品环境暴露评估与风险评估的模型构建、优化与方法应用提供信息和借鉴。     

Landscape-level influences of terrestrial snake occupancy within the southeastern United States

Habitat loss and degradation are thought to be the primary drivers of species extirpations, but for many species we have little information regarding specific habitats that influence occupancy. Snakes are of conservation concern throughout North America, but effective management and conservation are hindered by a lack of basic natural history information and the small number of large-scale studies designed to assess general population trends. To address this information gap, we compiled detection/nondetection data for 13 large terrestrial species from 449 traps located across the southeastern United States, and we characterized the land cover surrounding each trap at multiple spatial scales (250-, 500-, and 1000-m buffers). We used occupancy modeling, while accounting for heterogeneity in detection probability, to identify habitat variables that were influential in determining the presence of a particular species. We evaluated 12 competing models for each species, representing various hypotheses pertaining to important habitat features for terrestrial snakes. Overall, considerable interspecific variation existed in important habitat variables and relevant spatial scales. For example, kingsnakes (Lampropeltis getula) were negatively associated with evergreen forests, whereas Louisiana pinesnake (Pituophis ruthveni) occupancy increased with increasing coverage of this forest type. Some species were positively associated with grassland and scrub/shrub (e.g., Slowinski's cornsnake, Elaphe slowinskii) whereas others, (e.g., copperhead, Agkistrodon contortrix, and eastern diamond-backed rattlesnake, Crotalus adamanteus) were positively associated with forested habitats. Although the species that we studied may persist in varied landscapes other than those we identified as important, our data were collected in relatively undeveloped areas. Thus, our findings may be relevant when generating conservation plans or restoration goals. Maintaining or restoring landscapes that are most consistent with the ancestral habitat preferences of terrestrial snake assemblages will require a diverse habitat matrix over large spatial scales.     

Contaminants in Wintering Canvasbacks and Scaups from San Francisco Bay, California

Organochlorines, metals, and trace elements were measured in liver, kidney, or whole-body tissues of canvasbacks (Aythya valisineria), lesser scaups (A. affinis), and greater scaups (A. marila) collected from San Francisco Bay and three coastal areas of California during the winter of 1986–1987. Potentially toxic concentrations of mercury (mean 10.4 µg/g, dry weight) and selenium (mean 32.7 µg/g, dry weight) were found in livers of scaups and canvasbacks from several San Francisco Bay sites. These elements varied spatially, temporally, and between species, with the highest concentrations found in late winter. Mean concentrations of mercury, selenium, and cadmium were generally higher in scaups than in canvasbacks. Of all the organochlorines included in the analyses, only p,p'-DDE and total PCBs were detected in all samples in this study. Mean whole-body concentrations of DDE and PCBs from San Francisco Bay ducks collected in late winter varied spatially and between species, but the concentrations were not considered toxic. Causes for inter-specific differences are unclear, but may be attributable to differences in diet, movement, or physiology.