Exposure assessment of lead to workers and children in the battery recycling craft village,Dong Mai,Vietnam

Human exposure to lead (Pb) due to uncontrolled Pb-acid battery recycling has been an environmental health issue in newly developed industrial regions. We conducted a human monitoring survey in Dong Mai, a battery recycling village in Vietnam, to assess exposure status to Pb. Lead level was measured in hair, blood and urine samples of residents in Dong Mai and two reference sites during 4 years spanning 2007–2011. In Dong Mai, Pb levels in three matrixes were significantly higher than those in reference sites. Blood Pb levels of all adults and children exceeded 10 μg/dL, the Centers for Disease Control and Prevention definition of an elevated blood Pb level. Clear increase of urinary δ-aminolevulinic acid (ALA) level with increasing blood Pb level indicated disruption of heme synthesis. One adult exceeded 100 μg/dL of blood Pb, where encephalopathy is of concern. The blood Pb levels achieved various toxic effect threshold values, and elevated blood Pb was not limited to recycling workers, but was also in children and women of reproductive age. Serious pollution status of Dong Mai village suggests an importance of further monitoring surveys in various developing Asian countries.     

Photochemical Smog Modeling for Assessment of Potential Impacts of Different Management Strategies on Air Quality of the Bangkok Metropolitan Region,Thailand

Abstract

A photochemical smog model system, the Variable-Grid Urban Airshed Model/Systems Applications International Mesoscale Model (UAM-V/SAIMM), was used to investigate photochemical pollution in the Bangkok Metropolitan Region (BMR). The model system was first applied to simulate a historical photochemical smog episode of two days (January 13-14, 1997) using the 1997 anthropogenic emission database available at the Pollution Control Department and an estimated biogenic emission. The output 1-hr ozone (O₃) for BMR, however, did not meet the U.S. Environmental Protection Agency suggested performance criteria. The simulated minimum and maximum O₃ values in the domain were much higher than the observations. Multiple model runs with different precursor emission reduction scenarios showed that the best model performance with the simulated 1-hr O₃ meeting all the criteria was obtained when the volatile organic compound (VOC) and oxides of nitrogen (NO_x) emission from mobile source reduced by 50% and carbon monoxide by 20% from the original database. Various combinations of anthropogenic and biogenic emissions in Bangkok and surrounding provinces were simulated to assess the contribution of different sources to O₃ pollution in the city. O₃ formation in Bangkok was found to be more VOC-sensitive than NO_x-sensitive. To attain the Thailand ambient air quality standard for 1-hr O₃ of 100 ppb, VOC emission in BMR should be reduced by 50-60%. Management strategies considered in the scenario study consist of Stage I, Stage II vapor control, replacement of two-stroke by four-stroke motorcycles, 100% compressed natural gas bus, 100% natural gas-fired power plants, and replacement of methyltertiarybutylether by ethanol as an additive for gasoline.     

Residual congener pattern of dioxins in human breast milk in southern Vietnam

This study evaluated residual congener patterns of dioxin/furan (=PCDD/DF) related to tactical herbicides aerially sprayed over the regions of southern Vietnam through Operation Ranch Hand. The study focused on Cam Chinh (CC) commune, Quang Tri province (an area sprayed with tactical herbicides), and the Cam Phuc (CP) commune, Ha Tinh province (a non-sprayed area). Breast milk samples for analysis were collected in September 2002 and July 2003 from lactating primiparous and multiparous mothers born after the war (<31 years old). We found the levels of each congener in the CC commune were higher than in the CP commune, and determined specificity in the PCDD/DF congener pattern in CC commune samples by cluster analysis. The congener pattern is characterized by higher (the hexa-, the hepta-, and the octa-) chlorinated PCDD/DFs; this appears to be the same profile as that presented by pentachlorophenol (PCP), rather than 2,4,5-trichlorophenoxy acid (2,4,5-T) contaminated with 2,3,7,8-TCDD. A GC/MS study in the 1970s detected the chlorophenols 2,4-di and 2,4,6-trichlorophenol in some Agent Orange samples, which contained, like PCP, a wide variety of PCDD/DF congeners. In this context, it may be expected that certain tactical herbicides contaminated with various chlorophenol impurities, have a unique congener pattern when compared with pure 2,4,5-T formulations.     

Activated carbon/Fe(3)O(4) nanoparticle composite: fabrication, methyl orange removal and regeneration by hydrogen peroxide

In the water treatment field, activated carbons (ACs) have wide applications in adsorptions. However, the applications are limited by difficulties encountered in separation and regeneration processes. Here, activated carbon/Fe₃O₄ nanoparticle composites, which combine the adsorption features of powdered activated carbon (PAC) with the magnetic and excellent catalytic properties of Fe₃O₄ nanoparticles, were fabricated by a modified impregnation method using HNO₃ as the carbon modifying agent. The obtained composites were characterized by X-ray diffraction, scanning and transmission electron microscopy, nitrogen adsorption isotherms and vibrating sample magnetometer. Their performance for methyl orange (MO) removal by adsorption was evaluated. The regeneration of the composite and PAC-HNO₃ (powdered activated carbon modified by HNO₃) adsorbed MO by hydrogen peroxide was investigated. The composites had a high specific surface area and porosity and a superparamagnetic property that shows they can be manipulated by an external magnetic field. Adsorption experiments showed that the MO sorption process on the composites followed pseudo-second order kinetic model and the adsorption isotherm date could be simulated with both the Freundlich and Langmuir models. The regeneration indicated that the presence of the Fe₃O₄ nanoparticles is important for a achieving high regeneration efficiency by hydrogen peroxide.     

Pesticide pollution in agricultural areas of Northern Vietnam: case study in Hoang Liet and Minh Dai communes

Soils and agricultural products from the Red River basin in Northern Vietnam were reported to be contaminated by agrichemicals. To assess potential exposure of local farmers and consumers to these contaminants, pesticide use and management practices of local farmers were surveyed and residue concentrations were determined for recently used as well as for banned pesticides in water, soil, vegetables, and fish samples in two communes of Northern Vietnam. DDTs, HCHs, and Drin compounds still persist at relatively high concentrations in soil and occur in vegetable and fish samples. Recently used pesticides, such as fenobucarb, trichlorfon, cyfluthrin, and cypermethrin were detected in vegetable and fish samples. Thresholds for acceptable daily intake levels (ADI) were frequently reached in the analyzed food products pointing to the fact that current pesticide management practices do not only result in a pollution of the environment but also pose threats to human health.     

Occurrence of antimicrobials in animal manure-amended soils around the breeding farms: The case of the Saigon River (southern Vietnam)

The excessive use of antimicrobials in animal rearing and the associated environmental hazards have become a pressing issue. Animal agriculture is often viewed as a significant contributor to environmental degradation due to the residues of antimicrobials. It is a common practice to use livestock waste as a soil enhancer in farming. Despite some research into antimicrobials, there is room for more comprehensive data regarding these pollutants in animal farming environments. A handful of earlier studies have identified antimicrobials in animal waste. This research undertook the task of examining and evaluating soils amended with animal waste (from chickens, cows, and pigs) for the presence of seven specific antimicrobials. The antimicrobials under scrutiny included trimethoprim (TRI), ormethoprim (ORM), ofloxacin (OFL), norfloxacin (NOR), tetracycline (TET), chlortetracycline (CTE), and tylosin (TLS). Soil samples were collected from areas surrounding breeding farms located upstream of the Sai Gon River. These samples were then subjected to laboratory analysis, which involved solid-phase extraction using ultrasonic waves and the application of high-performance liquid chromatography-tandem mass spectrometry (LCMS/MS) to identify the antimicrobials. TRI, which had the highest average concentration (2.603–91.304 μg/kg), and OFL, with the second highest average concentration (1.815–15.832 μg/kg), were detected in all soil samples amended with manure. CTE, with the third highest average concentration, was found in soils amended with cow and pig waste (1.625–15.486 μg/kg). ORM and TE, with lower average concentrations (0.595–1.318 μ and 11.537–13.569 μg/kg, respectively), were only detected in soils amended with chicken waste, while NOR was only found in soils amended with cow waste. These findings indicate that the use of antimicrobials in animal farming can negatively impact the soil ecosystem. Consequently, these results can contribute to the creation of guidelines for monitoring antimicrobial residues in agricultural ecosystems.     

Exchange pattern of gaseous elemental mercury in an active urban landfill facility

The environmental behavior of gaseous elemental mercury (Hg) in the ambient air was investigated from the center of a municipal landfill site (area approximately 0.6km(2)) located in Dae Gu, Korea in the winter of 2004. In order to provide insight on the Hg exchange processes in strong source areas, we continuously analyzed Hg concentration gradients developed across two heights between 1m and 5m over soil surfaces at hourly intervals. The results displayed Hg concentrations in the lower and upper levels in the range of 1.46-13.1ngm(-3) (3.33+/-1.29ngm(-3): N=139) and 1.20-13.7ngm(-3) (3.27+/-1.23ngm(-3): N=139), respectively. The results of our analysis, when divided separately into emission and dry deposition, showed that emission of Hg was fairly dominant in frequency (up to 58%) over dry deposition. By multiplying our Hg gradient data with the K-values predicted indirectly from the results of previous studies, the emission and deposition fluxes of Hg were estimated as 39.0+/-43.3ngm(-2)h(-1) (N=80) and -60.0+/-80.2ngm(-2)h(-1) (N=59), respectively. Although the magnitudes of exchange were moderately lower than previously investigated anthropogenic sources, the overall results of this study suggest that an active landfill site can act as an important source of Hg in an urban environment along with other man-made activities.     

A conductive polypyrrole based ammonium ion selective electrode

In view of the development of miniaturized sensor arrays, a solid-contact ammonium ion selective electrode has been investigated. A conductive polypyrrole film was electrochemicallydeposited on a glassy carbon surface and used as an internal solid contact layer between the sensing membrane and solid electrode surface. A systematic evaluation of the importantparameters affecting the electromotive force (emf) response ispresented. The performances of this solid-contact sensor were verified using a batch-mode measurement setup and a wall-jet flow cell system. The designed sensor exhibited excellent selectivity for the primary ion and a linear response over the pNH₄ ⁺ range 1–5 with a slope of 56.3 mV decade^-1. The sensor has a fast response and is relativelyrobustness, and was also used to determine ammonium concentrations in natural waters, with promising results.     

长江口潮滩芦苇根表铁膜磁性特征及其环境意义

湿地植物根表铁膜对包括重金属在内的物质迁移转化具有重要作用,其氧化铁组成研究备受重视,但利用环境磁学方法进行表征的研究还未见报道.本文对长江口潮滩植物芦苇根系及周边沉积物进行了磁学分析,并结合沉积物粒度、漫反射光谱等测试,对芦苇根表铁膜的磁性矿物组成进行了系统研究.结果表明,芦苇根表铁膜磁性矿物主要包括磁铁矿和赤铁矿.由于沉积物不同深度氧化还原环境的不同,铁膜磁性矿物组成存在垂向差异.研究柱样24 cm深度以上,由于相对氧化的环境,铁膜磁性矿物除磁铁矿外,还有较多的赤铁矿贡献;24 cm深度以下,因根系处于相对还原的环境,磁性矿物以磁铁矿为主.与沉积物相比,24 cm以上深度铁膜中亚铁磁性矿物含量较低,24 cm深度以下则相反,反映铁膜和沉积物磁性矿物来源不同.本项研究表明,磁性测量方法有助于认识湿地植物根表铁膜的矿物组成,对湿地生物地球化学过程研究具有重要价值.     

Meso-scale hydrodynamic and reproductive asynchrony affects the source–sink metapopulation structure of the coastal polychaete Pectinaria koreni

The polychaete Pectinaria koreni exhibits a complex life cycle characterized by non-overlapping generations and widespread larval dispersal. To explore how “local” metapopulation genetic structure varies spatially and temporally during population turnover, we combined observations on demography, larval dispersal through hydrodynamic modelling and population genetics of successive age cohorts in the Baie de Seine (eastern English Channel, France). Mature adults (March), newly settled (July) and later-stage juveniles (September) were sampled in 2003 on the edge and in the main demes of the metapopulation. Demes displayed an asynchronous dynamics due to variations in habitat quality affecting reproductive timing (e.g. three distinct spawning events observed) and in local larval supply linked to temporal fluctuations of hydrodynamism. Two-source populations were identified among dense areas with the greatest larval retention and self-recruitment rates: one with a single recruitment event, stable temporal genetic variation and a strong spatial genetic re-homogenization during turnover, and the other with two recruitment events and significant allele frequency changes over time. Sink habitats displayed single recruitment event and experienced strong inter-generational (juveniles vs adults) genetic changes due to genetic drift associated with strong winter mortalities. Altogether, results suggested that adult spawning asynchrony and sweepstakes reproductive success, together with genetic drift, played a greater role than hydrodynamics itself in determining effective recruitment rates at some sites and generating genetic patchiness.