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91.
Solvent microextraction (SME) was applied to the extraction of polycyclic aromatic hydrocarbons (PAHs) from spiked and real environmental soil samples with different matrices. Soil sample was mixed with 7 mL of acetone and 14 mL of water to allow partitioning of the PAHs from the soil to the liquid phase. A 2 microL octane drop suspended from a microsyringe needle tip was then immersed into the stirred solution-soil mixture for extraction. After an 11 min extraction, the octane drop was withdrawn into the syringe and injected directly into the GC for identification and quantification. The whole analysis procedure took 27 min, with an extraction time of 11 min, and a GC separation time of 16 min. A second extraction could be undertaken whilst the GC is running, hence the GC run time currently limits the sample throughput. In this method, a small amount of organic solvent was used for the extraction process, which produced little waste. The limits of detection for lower molecular weight (< 230) PAHs range from 0.13 to 0.36 mg kg-1, and for higher molecular weight (> 250) PAHs are estimated to be between 0.5 and 1.0 mg kg-1, with RSD values generally under 20%. Due to the small volumes of organic solvent used, the consumable cost per extraction is only US$ 0.12. This is the first report of the application of SME to solid samples, and the first report of the use of SME for the analysis of PAHs. 相似文献
92.
A number of methods has been proposed for dealing with single-factor or factorial experiments when the requirements for performing the normal theory analysis of variance procedure are not satisfied. This paper suggests the use of the likelihood ratio statistic for testing the main effects and the interaction between the factors in two-way layout of count data following negative binomial distributions with a common dispersion parameter. The likelihood ratio statistic for testing the equality of the dispersion parameters of several groups of count data is also derived. The methods is illustrated by an example concerning the study of spatial and temporal variation of bacterial counts. 相似文献
93.
94.
M. Anne R. McLane Donald L. Hughes Gary H. Heinz 《Environmental monitoring and assessment》1984,4(2):105-111
Wings from woodcock (Philohela minor) were first monitored for organochlorine pesticides and polychlorinated biphenyls (PCBs) in the eastern U.S. in 1971. Regional differences in these compounds were clearly demonstrated and baseline residue levels were obtained for later comparisons. An expanded sampling of wings in 1972 revealed that residues in wings of adult woodcock may differ significantly from those in immatures, and that residues of several important agricultural insecticides and PCBs had declined significantly. More extensive sampling was undertaken in 1975 to determine if changes in residue levels had taken place in the intervening years. PCBs, mirex, and heptachlor epoxide increased significantly between 1972 and 1975 in adult woodcock wings. In immature woodcock wings mirex, dieldrin, and PCBs increased significantly between 1972 and 1975, but DDT residues decreased significantly. 相似文献
95.
H. Eijsackers 《Environmental monitoring and assessment》1983,3(3-4):307-316
Research on biological indicators of soil pollution is hampered by soil variability and temporal and spatial fluctuations of numbers of soil animals. These characters on the other hand promote a high biological diversity in the soil. A high diversity combined with persistent soil pollutants increases the chance to select good indicators. However research on these topics is still limited. Examples of specific indicators are the changed arthropod species patterns due to pesticide influence and the changed soil enzyme activity under the influence of specific heavy metals. Another approach is to look for organisms that give a general indication of soil pollution. In this respect the earthworm species Allolobophora caliginosa proved to be sensitive for different types of manure especially pig manure with copper, for sewage sludge, for municipal waste compost and for fly ash. A third way of indication is by organisms accumulating pollutants. For some heavy metals (Cd, Zn), earthworms are very efficient accumulators. More research is needed especially on the specific relation between biological responses and abiotic soil characteristics. 相似文献
96.
Excrement cast from Great Blue Heron nests was collected during the nesting period of 1978 from four colonies in Washington and Idaho. Cheesecloth strips placed on the ground beneath the nests served as excrement collecting devices. Chemical analysis for lead, mercury and cadmium were performed on dried samples. Lead was the most abundant trace metal found in heron debris. The Idaho colony at Lake Chatcolet had an average concentration of 46 ppm in the beneath-nest samples and 6 ppm in control samples. A heron colony near Tacoma, Washington had beneath-nest samples averaging 28 ppm and control samples averaging 20 ppm. Two colonies located in the interior region of Washington had substantially lower concentrations of lead. The difference observed between colonies was attributed to their associations with a polluted watershed (Chatcolet colony) an interstate highway (Tacoma colony) and an unpopulated largely agricultural area (inland Washington). 相似文献
97.
Strontium-90 (90SR) released to the ground near the N Reactor at the U.S. Department of Energy's Hanford Site enters the Columbia River through shoreline seeps. The 90Sr is then potentially available for uptake by plants and animals. The life history and foraging behavior of nesting Canada geese is such that female geese could ingest 90Sr while foraging on shoreline plants. Radichemical analyses showed that goose eggshells taken from an island, downstream from the N Reactor, contained more 90Sr than did eggshells collected from other downstream islands. Reed canary grass samples taken from shoreline areas immediately downstream from the N Reactor contained higher concentrations of 90Sr than samples from other downstream areas. All goose eggshells did not contain enhanced levels of 90Sr, and all reed canary grass samples did not contain enhanced levels of 90Sr, but a relationship exists between the releases of 90Sr to the Columbia River and the enhanced levels of 90Sr in some of the environmental samples analyzed.Pacific Northwest Laboratory is operated by Battelle Memorial Institute for the U.S. Department of Energy under contract DE-ACO6-76RLO 1830. 相似文献
98.
Nitrogen leaching is a world-wide concern for the quality of ground- and surfacewater. Measures to abate this is still limited by a lack of understanding mechanisms behind all factors describing the leaching process, time lags between countermeasures and improvement in waterquality and spatial distribution of nitrogen leaching. The purpose of this study was to do an initial test of the SOILNDB model system which is built on the existing mechanistic SOIL and SOILN models and an automatic parameterization procedure for use of simplified input data. The test was done by simulating nitrogen leaching from each of the 150 fields in a small catchment during a three-year study period. The simulated mean root-zone nitrogen leaching rate from all the fields in the catchment was compared to measurements of nitrogen flow in the stream draining the catchment and showed good agreement in between-year dynamics. 相似文献
99.
Sun HF Takata A Hata N Kasahara I Taguchi S 《Journal of environmental monitoring : JEM》2003,5(6):891-895
The degradation, sorption, transportation and material balance of cationic surfactants discharged from domestic waste into river water was studied. Ion-pair solid-phase extraction behavior showed that the sorption of cationic surfactants as an ion-pair with anionic surfactant onto river sediment was so strong that little cationic surfactant was found in the bulk water. Cationic surfactant was found in river sediment at more than 500 times higher concentration than that in the bulk water. The degradation of the cationic surfactant was very slow in river water and much slower in the sediment. A material balance of cationic surfactant was estimated for a river running through Toyama City by measuring the flow rate and the concentration of cationic surfactant in the water at several points. It was found that more than 30% of cationic surfactant introduced to the river was lost during the river running through ca. 3 km in 3 h. This reduction probably comes from a quick transfer of the cationic surfactant from river water to sediment and water weed by means of adsorption or precipitation with suspending solids. 相似文献
100.
A method is described whereby dielectrophoresis of algal cells is used to perform rapid water quality analysis, specifically detecting the presence of CuSO4. The dielectric collection spectrum of the fresh water alga Selenastrum capricornutum was determined for a range of concentrations of CuSO4 from 25 mg L(-1) to 0.25 mg L(-1) for exposure times of 15 min and 18 h. In all cases increasing the concentration of CuSO4 reduced cell collection, but a step reduction was observed in collection between 2 mg L(-1) and 5 mg L(-1). This method has potential for forming a rapid, low-cost test for water quality with broad specificity and significantly reduced analysis time compared to current methods. 相似文献