Comparative study on effect of blending,thermal barrier coating (LHR) and injector nozzle geometry on biodiesel-fuelled engines

Increased petroleum prices, increased threat to the environment from exhaust emissions and global warming have generated intense international interest in developing renewable and alternative non-petroleum fuels for internal combustion engines. Evolving suitable technology for addressing energy crisis creates a continued investigation into the search for sustainable and clean-burning renewable fuels. This work investigates suitability of different non-edible-derived biodiesels such as cotton seed oil methyl ester (COME), Honne oil methyl ester (HnOME) and Rubber seed oil methyl ester (RuOME) to four stroke, single cylinder compression ignition (CI) engine. Engine tests were conducted to study the effect of fuel blending, thermal barrier coating (TBC) or Low Heat Rejection (LHR) and injector nozzle geometry on the performance, combustion and emission characteristics of COME, HnOME and RuOME in the modified CI engine. Blends of biodiesels with diesel were varied from 20 to 80% in steps of 20%. Two thermal barrier coatings of partially stabilized zirconium (PSZ) and aluminium oxide (Al₂O₃) were provided on the engine to make it fully adiabatic. Nozzle injectors of 3, 4 and 5 holes, with size of orifice varied from 0.2 to 0.3 mm size were selected for the study. It was concluded that B20 biodiesel blend, PSZ-coated engine and four hole nozzle injector of 0.2 mm size resulted in overall better engine performance with increased brake thermal efficiency (BTE) and reduced HC, CO, smoke emissions for the fuel combinations tested. Combustion analysis to study the effect of biodiesel blends, LHR coatings, injector nozzle geometry on the performance of the biodiesel-fuelled engine has been presented to give more insight into the behaviour of operation.     

A review of vulnerability indicators for deltaic social–ecological systems

The sustainability of deltas worldwide is under threat due to the consequences of global environmental change (including climate change) and human interventions in deltaic landscapes. Understanding these systems is becoming increasingly important to assess threats to and opportunities for long-term sustainable development. Here, we propose a simplified, yet inclusive social–ecological system (SES)-centered risk and vulnerability framework and a list of indicators proven to be useful in past delta assessments. In total, 236 indicators were identified through a structured review of peer-reviewed literature performed for three globally relevant deltas—the Mekong, the Ganges–Brahmaputra–Meghna and the Amazon. These are meant to serve as a preliminary “library” of potential indicators to be used for future vulnerability assessments. Based on the reviewed studies, we identified disparities in the availability of indicators to populate some of the vulnerability domains of the proposed framework, as comprehensive social–ecological assessments were seldom implemented in the past. Even in assessments explicitly aiming to capture both the social and the ecological system, there were many more indicators for social susceptibility and coping/adaptive capacities as compared to those relevant for characterizing ecosystem susceptibility or robustness. Moreover, there is a lack of multi-hazard approaches accounting for the specific vulnerability profile of sub-delta areas. We advocate for more comprehensive, truly social–ecological assessments which respond to multi-hazard settings and recognize within-delta differences in vulnerability and risk. Such assessments could make use of the proposed framework and list of indicators as a starting point and amend it with new indicators that would allow capturing the complexity as well as the multi-hazard exposure in a typical delta SES.     

Traps in and of our minds: relationships between human logic,dialectical traps and social-ecological traps

Social-ecological traps are theorized to be present when human actions affect feedbacks and drivers in social-ecological systems, which, in turn, lead to regime shifts that may alter ecosystem capacity to generate services on which human wellbeing depends, and this, in turn, triggers societal responses, where actors and institutions interact with ecological dynamics and unwittingly lock development into a vulnerable pathway. The key dynamic in this theorization seems to be that human action often predicates or initiates the series of cascading affects that determine the presence of, and, perhaps, the effectiveness of, social-ecological traps. However, what drives human action in this context? What logic, assumptions, decisions, world views, and other processes are implicated in this configuration? This paper first briefly reviews ecological identity and the problems of anthropocentricism, human exceptionalism, and human exemptionalism and introduces the term ecological disenfranchisement. Building upon this, the author invokes Horn’s logic and dialectical traps as a lens for understanding human roles and the prevalence of issues with ecological identities, within social ecological traps. Drilling further down, the paper illustrates these traps with short vignettes, in each case, attempting to link the human logical traps with larger system dynamics. Finally, the author proposes a chain of reasoning to serve as an example of how the presence of human logic traps (or entrapment) in a number of different spheres has an impact upon the larger system, and, perhaps, even predicts entrapment of the larger system. Future efforts to either understand social-ecological traps or navigate away or out of them must first take stock of the human logical traps that actors within the systems are influenced by, and that influence the large system(s).This paper argues that failing to account for human traps within will render most efforts to avoid or escape social-ecological traps futile.     

Colonized beads as inoculum for marine biodegradability assessment: Application to Linear Alkylbenzene Sulfonate

An innovative biodegradation test system was developed in order to fill the current gap for cost effective and environmentally relevant tools to assess marine biodegradability. Glass beads were colonized by a biofilm in an open flow-through system of seawater with continuous pre-exposure to Linear Alkylbenzene Sulfonate (LAS) (20 μg/L). Thereafter, such colonized beads were added as inoculum in different test systems. [¹⁴C]-LAS (5–100 μg/L) was added and primary and ultimate biodegradation were assessed. The bacterial density collected on the beads (10⁹ bact./mL beads) was ca. 3 orders of magnitude higher than the typical seawater content. The LAS mineralization lag phase duration decreased from 55 to < 1 days and the mineralization extent increased from 53 to 90% as the colonized beads volume increased from 10 to 275 mL. This is the first demonstration of marine bacteria's ability to mineralize LAS. On the opposite, less than 13% LAS was mineralized in seawater only. The colonized beads possibly enhanced the probability to encounter the full degraders' consortium in a low volume of seawater (100 mL).     

Extending the environmental risk assessment for oseltamivir (Tamiflu®) under pandemic use conditions to the coastal marine compartment

In case of an avian-influenza-derived human flu pandemic, an inordinately high use of medicines over several weeks is predicted, in particular for the recommended influenza antiviral oseltamivir (Tamiflu). While the risk of oseltamivir to sewage works and freshwater bodies has already been assessed, the fact that a large percentage of the human population worldwide lives relatively close to the sea raises concern for its environmental compatibility in coastal marine waters. The potential risk of high oseltamivir use to the marine compartment is assessed in this publication, based on the 2003 European Community Technical Guidance Document (TGD) for risk assessment. Subchronic embryo–larval ecotoxicity tests with three marine invertebrates (Pomatoceros triqueter, Annelida; Mytilus edulis, Mollusca; Paracentrotus lividus, Echinodermata) and chronic growth inhibition tests with two different groups of marine microalgae (Isochrysis galbana, Haptophyta; Skeletonema costatum, Heterokontophyta) were performed with the active substance oseltamivir carboxylic acid to derive a dependable marine predicted no-effect concentration (PNEC). This was compared to a predicted environmental concentration (PEC) for oseltamivir in coastal waters, based on the worst-case freshwater PEC. The PEC/PNEC risk characterisation ratio for the marine compartment is well below 1, which in the terminology of the TGD signifies no immediate concern. Further, while oseltamivir may be persistent (P), it is not bioaccumulative (B) nor highly ecotoxic (T) and therefore not a PBT substance. In conclusion, even a high pandemic use of oseltamivir would not lead to a significant risk for the marine compartment, in confirmation of the risk assessment for sewage works and freshwaters.     

Brominated flame retardants and organochlorines in the European environment using great tit eggs as a biomonitoring tool

Large-scale studies are essential to assess the emission patterns and spatial distribution of organohalogenated pollutants (OHPs) in the environment. Bird eggs have several advantages compared to other environmental media which have previously been used to map the distribution of OHPs. In this study, large-scale geographical variation in the occurrence of OHPs, such as polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs) and organochlorine pesticides (OCPs), was investigated throughout Europe using eggs of a terrestrial residential passerine species, the great tit (Parus major). Great tit eggs from 22 sampling sites, involving urban, rural and remote areas, in 14 European countries were collected and analysed (5-8 eggs per sampling site). The environmentally most important congeners/compounds of the analysed pollutants were detectable in all sampling locations. For PCBs, PBDEs and OCPs, no clear geographical contamination pattern was found. Sum PCB levels ranged from 143 ng/g lipid weight (lw) to 3660 ng/g lw. As expected, PCB concentrations were significantly higher in the sampled urban compared to the remote locations. However, the urban locations did not show significantly higher concentrations compared to the rural locations. Sum PBDEs ranged from 4.0 ng/g lw to 136 ng/g lw. PBDEs were significantly higher in the urbanized sampling locations compared to the other locations. The significant, positive correlation between PCB and PBDE concentrations suggests similar spatial exposure and/or mechanisms of accumulation. Significantly higher levels of OCPs (sum OCPs ranging from 191 ng/g lw to 7830 ng/g lw) were detected in rural sampling locations. Contamination profiles of PCBs, PBDEs and OCPs differed also among the sampling locations, which may be due to local usage and contamination sources. The higher variance among sampling locations for the PCBs and OCPs, suggests that local contamination sources are more important for the PCBs and OCPs compared to the PBDEs. To our knowledge, this is the first study in which bird eggs were used as a monitoring tool for OHPs on such a large geographical scale.     

Occurrence and fate of pharmaceutical products and by-products,from resource to drinking water

Among all emerging substances in water, pharmaceutical products (PPs) and residues are a lot of concern. These last two years, the number of studies has increased drastically, however much less for water resources and drinking water than for wastewater. This literature review based on recent works, deals with water resources (surface or groundwater), focusing on characteristics, occurrence and fate of numerous PPs studied, and drinking water including water quality. Through this review, it appears that the pharmaceutical risk must be considered even in drinking water where concentrations are very low. Moreover, there is a lack of research for by-products (metabolites and transformation products) characterization, occurrence and fate in all water types and especially in drinking water.     

Species-specific and context-dependant disruption of temporal population fluctuations resulting from hypereutrophication events

This study quantifies the disruption of zooplankton population fluctuations in relation to two magnitudes of fire retardant contamination events using artificial ponds as model systems. Population time series were analysed using redundancy analysis where time was modelled with a principal coordinate of neighborhood matrices approach that identified relevant scales of fluctuation frequencies. Analyses of temporal coherence provided insight whether population fluctuations correlated with system intrinsic or extrinsic forces. Responses to stress were species-specific and context-dependant. Contamination changed temporal structure in some species. These alterations were associated with an increased intrinsic control of dynamics. In some cases the magnitude of impact was unrelated to contamination severity. Some populations were less tolerant of pollution in the low relative to the high concentration treatment. Results suggest that population-level monitoring of degraded sites may be suboptimal because disparate population responses complicate the selection of specific sentinel organisms to monitor stress.