Investigation of the concentration and isotopic composition of inputs and outputs of Pb in waters at an upland catchment in NE Scotland

As a consequence of the accumulation of anthropogenic Pb in upland catchments, there has been much recent concern about the potential mobilisation and transport of Pb from the soils to receiving waters and also the possible harmful effects that this might have on aquatic biota. This paper presents the findings of a two-year study of Pb behaviour in an organic-rich upland catchment at Glensaugh in NE Scotland. Pb inputs to the catchment were characterised by direct measurements of Pb concentration and (206)Pb/(207)Pb ratios in rain water and interception. Pb outputs from the catchment were calculated from measurements on stream water samples taken from the two main streams, the Cairn Burn and Birnie Burn. The relative contribution of Pb from groundwater and throughflow, under different flow conditions (base flow and high flow), to stream waters was investigated via analysis of springs sourced from groundwater and of waters flowing through the various soil horizons (S (surface), A, B, C, and D), respectively. The outcome of intensive sampling and analysis over the two-year time period was that, even with marked reduction in Pb inputs over the past two decades, the catchment was still acting as a net sink for the current atmospheric deposition. Although the Pb isotopic signature for stream water is very similar to that for the contemporaneous rain water ((206)Pb/(207)Pb approximately 1.15-1.16), only a small portion of the rain water is transferred directly to stream water. Instead, the Pb input is transferred to the stream waters mainly via groundwater and it was also confirmed that the latter had a similar Pb isotopic signature. From the Pb isotopic measurements on throughflow waters, however, Pb being removed via the streams contained some previously deposited Pb, i.e. mobilisation of a small portion of soil-derived anthropogenic Pb was occurring. These findings are important not only with respect to the source/sink status of the catchment but also for calculation of the extent of retention of the current atmospheric Pb inputs, which must take account of the release of previously deposited Pb from the catchment soils, a process occurring mainly under high flow conditions.     

Stage‐Discharge Relationships for U‐, A‐, and W‐Weirs in Un‐submerged Flow Conditions1

Thornton, Christopher I., Anthony M. Meneghetti, Kent Collins, Steven R. Abt, and S. Michael Scurlock, 2011. Stage‐Discharge Relationships for U‐, A‐, and W‐Weirs in Un‐submerged Flow Conditions. Journal of the American Water Resources Association (JAWRA) 47(1):169‐178. DOI: 10.1111/j.1752‐1688.2010.00501.x Abstract: Instream rock weirs are routinely placed into stream systems to provide grade control, reduce streambank erosion, provide energy dissipation, and allow fish passage. However, design and performance criteria for site specific applications are often anecdotal or qualitative in nature, and based upon the experience of the design team. A study was conducted to develop generic state‐discharge relationships for U‐, A‐, and W‐weirs. A laboratory testing program was performed in which scaled, near‐prototype U‐, A‐, and W‐rock weir structures were constructed in 11 configurations. Each configuration encompassed a unique weir shape, bed material, and/or bed slope. Thirty‐one tests were conducted in which each structure was subjected to a sequence of predetermined discharges that minimally included the equivalent of 1/3 bankfull, 2/3 bankfull, and bankfull conditions. All tests were performed in subcritical, un‐submerged flow conditions. Stage‐discharge relationships were developed using multivariant, power regression techniques for each of the U‐, A‐, and W‐rock weirs as a function of the effective weir length, flow depth, mean weir height, rock size, and discharge coefficient. Unique coefficient expressions were developed for each weir shape, and a single discharge coefficient was proposed applicable to the weirs for determining the channel stage‐discharge rating.     

The relative influence of habitat loss and fragmentation: do tropical mammals meet the temperate paradigm?

The relative influence of habitat loss vs. habitat fragmentation per se (the breaking apart of habitat) on species distribution and abundance is a topic of debate. Although some theoretical studies predict a strong negative effect of fragmentation, consensus from empirical studies is that habitat fragmentation has weak effects compared with habitat loss and that these effects are as likely to be positive as negative. However, few empirical investigations of this issue have been conducted on tropical or wide-ranging species that may be strongly influenced by changes in patch size and edge that occur with increasing fragmentation. We tested the relative influence of habitat loss and fragmentation by examining occupancy of forest patches by 20 mid- and large-sized Neotropical mammal species in a fragmented landscape of northern Guatemala. We related patch occupancy of mammals to measures of habitat loss and fragmentation and compared the influence of these two factors while controlling for patch-level variables. Species responded strongly to both fragmentation and loss, and response to fragmentation generally was negative. Our findings support previous assumptions that conservation of large mammals in the tropics will require conservation strategies that go beyond prevention of habitat loss to also consider forest cohesion or other aspects of landscape configuration.