微波辐射在二氧化锰诱导下对六氯苯污染土壤的修复研究

以二氧化锰为微波吸附剂,在密封体系中研究了微波辐射技术对六氯苯污染土壤的修复效果。分别以不同浓度的酸碱水溶液添加到土壤中,在模拟含水率为20%情况下,硫酸(50%)介质下六氯苯处理效果最好,10min的微波辐射即可使50mg/kg的六氯苯达到完全去除;但是在纯水和10mol/L氢氧化钠介质下,六氯苯基本上没有去除;随着硫酸浓度的降低,六氯苯的去除率显著降低。气相色谱/质谱联用(GC/MS)分析没有检测到新物质。六氯苯去除机理推测为,直接矿化或者HCB及其分解的中间产物同土壤发生化学结合而被固定起来,以致难以萃取出来。     

染料结晶紫降解菌分离及其特性研究

从印染废水中筛选分离得到结晶紫(CV)降解菌株H,并对其脱色条件和机理进行了研究.结果表明,在外加生长基质条件下,菌株H不仅对CV降解脱色而且能降解中间产物.在pH 7.0、35℃、摇床转速180 r/min条件下,菌株H有最佳的脱色效果.对于20 mg/L CV溶液,生长细胞降解0.5 h,脱色率可达95%.休眠细胞对CV的降解规律也进行了对比探讨.菌株H对CV脱色过程遵循一级动力学方程,脱色速率常数k随CV浓度升高而降低,生长细胞的k值约为休眠细胞的6～7倍.     

Effect of long-term application of biosolids for land reclamation on surface water chemistry

Biosolids are known to have a potential to restore degraded land, but the long-term impacts of this practice on the environment, including water quality, still need to be evaluated. The surface water chemistry (NO3-, NH4+, and total P, Cd, Cu, and Hg) was monitored for 31 yr from 1972 to 2002 in a 6000-ha watershed at Fulton County, Illinois, where the Metropolitan Water Reclamation District of Greater Chicago was restoring the productivity of strip-mined land using biosolids. The mean cumulative loading rates during the past 31 yr were 875 dry Mg ha(-1) for 1120-ha fields in the biosolids-amended watershed and 4.3 dry Mg ha(-1) for the 670-ha fields in the control watershed. Biosolids were injected into mine spoil fields as liquid fertilizer from 1972 to 1985, and incorporated as dewatered cake from 1980 to 1996 and air-dried solids from 1987 to 2002. The mean annual loadings of nutrients and trace elements from biosolids in 1 ha were 735 kg N, 530 kg P, 4.5 kg Cd, 30.7 kg Cu, and 0.11 kg Hg in the fields of the biosolids-amended watershed, and negligible in the fields of the control watershed. Sampling of surface water was conducted monthly in the 1970s, and three times per year in the 1980s and 1990s. The water samples were collected from 12 reservoirs and 2 creeks receiving drainage from the fields in the control watershed, and 8 reservoirs and 4 creeks associated with the fields in the biosolids-amended watershed for the analysis of NO3- -N (including NO2- N), NH4+-N, and total P, Cd, Cu, and Hg. Compared to the control (0.18 mg L(-1)), surface water NO3- -N in the biosolids-amended watershed (2.23 mg L(-1)) was consistently higher; however, it was still below the Illinois limit of 10 mg L(-1) for public and food-processing water supplies. Biosolids applications had a significant effect on mean concentrations of ammonium N (0.11 mg L(-1) for control and 0.24 mg L(-1) for biosolids) and total P (0.10 mg L(-1) for control and 0.16 mg L(-1) for biosolids) in surface water. Application of biosolids did not increase the concentrations of Cd and Hg in surface water. The elevation of Cu in surface water with biosolids application only occurred in some years of the first decade, when land-applied sludges contained high concentrations of trace metals, including Cu. In fact, following the promulgation of 40 CFR Part 503, the concentrations of all three metals fell below the method detection level (MDL) in surface water for nearly all samplings. Nitrate in the surface water tends to be higher in spring, and ammonium, total P, and total Hg in summer and fall. Mean nitrate, ammonium, and total phosphorus concentrations were found to be greater in creeks than reservoirs. The results indicate that application of biosolids for land reclamation at high loading rates from 1972 to 2002, with adequate runoff and soil erosion control, had only a minor impact on surface water quality.     

环境分权、环境规制对农业面源污染的影响

环境规制是实现农业面源污染减排的重要手段,而科学合理地划分环境管理权力是夯实环境规制减排绩效的制度基础。厘清环境分权、环境规制与农业面源污染三者之间的关系对优化环境管理体制和促进农业绿色发展具有重要的理论与现实意义。鉴于此,文章将环境规制、环境分权和农业面源污染纳入同一分析框架,基于2005—2017年省际面板数据,构建动态面板模型和面板门槛模型,实证考察了环境分权、环境规制与农业面源污染的内在联系。研究结果显示:①环境规制是抑制农业面源污染的重要手段;环境分权、环境监察分权和环境监测分权对农业面源污染具有显著的正向作用,环境行政分权对农业面源污染则表现为负向作用。②环境事务管理权力的下放将恶化环境规制的农业面源污染减排效应,引发“绿色悖论”效应,其中环境监察分权和环境监测分权的影响尤为突出。③从区域层面来看,中西部地区环境事务管理权力下放引发的“绿色悖论”效应显著,而东部地区则不显著。④环境规制对农业面源污染的影响随环境分权程度的变化呈现出门槛特征。伴随环境分权程度的提高,环境规制对农业面源污染的影响由“援助之手”转为“攫取之手”。因此,为解决日益严重的农业面源污染,应制定差异化的环境分权策略。一方面,环境行政权力应适当下放,而环境监察和环境监测权力要逐步上移;另一方面,进一步压缩中西部地区环境政策自由裁量空间,加大农业环境考核与监督力度。同时,建立长期动态农业面源污染监测体系,形成联防联控治理格局。     

菲律宾最大油污灾害

油污遍布的滩涂、渐渐枯萎的椰树、人们惊恐地瞪着充满血丝的眼睛……菲律宾吉马拉斯岛,就这样被定格在空前的悲剧画面中。2006年8月11日,菲石化公司租用的本国油轮在附近海域遭风浪击沉,总共200多万升工业燃油随之落入约900米深的海底。次日,汩汩泄漏     

固定化甲烷八叠球菌研究—─甲烷八叠球菌富集分离和固定化

用亨盖特（Hungate）厌氧技术,以甲醇为唯一碳源获得了甲烷八叠球菌的富集培养物,以甲醇或乙酸钠（或两者各50％）为碳源滚管培养,获得了以甲烷八叠球菌的分离培养物。用聚乙烯醇（PVA）为包埋剂对甲烷八叠球菌sp固定化,并对其特性进行了研究。结果表明：固定化甲烷八叠球菌与非固定化甲烷八叠球菌的总产气量相似,但两者的产气特性有明显不同。固定化甲烷八叠球菌产气迟于非固定化甲烷八叠球菌,固定化甲烷八叠球菌的产气集中,在产气的6天中,平均日产气量30.88mL甲烷,最高产气量可达2.80mL甲烷/h,在产气高峰两天中的产气量占总产气量的66.0％。非固定化甲烷八叠球菌产气平稳,平均日产气量为8.91mL甲烷。固定化甲烷八叠球菌的电子显微镜观察结果表明,细胞在固定介质中多呈较大包囊存在,包囊直径30～50μm。     

新型的无公害海洋防污涂料

本文概述了海洋防污涂料的发展现状及影响污损生物附着的主要因素,着重论述了低表面自由能材料,吸水性材料的和生化材料等无公害新型防污涂料的防污机制及其试用效果。并指出,开发和应用无锡自抛光涂料和新型低毒防污涂料,这是解决海洋中有机锡污染的近期目标。而刚刚兴起的无公害防污染料尚处在初期研制阶段,其推广应用还需要一个较长时间的发展过程。并且强调应当加强对静,动船舶在苛刻的海洋环境中抗海洋污染生物附着的防污     

铜铬催化剂清洁生产工艺研究

采用清洁生产概念与思维模式,对铜铬催化剂生产全过程进行审核,找出造成其产率低、活性差、污染重的原因及影响因素。以新催化剂研制理论和方法为指导,探讨铜铬催化剂用于糠醇生产过程中提高其产率、活性、原材料利用率以及减轻污染的清洁生产工艺。试验结果表明,在pH为6．2～6．5、Cu／Cr质量比为1：1、反应温度为65℃,活化温度为400℃的条件下,催化剂能获得较高产率和活性。按此新工艺生产的催化剂,产率可提高22％,Cr^6 的排放量可减少95％,活性可提高一倍,废品率可由原来的10％降至零。     

城市河流水域功能合理分类的研究——以第二松花江支流伊通河为例

为提高地方环境标准的科学性与可操作性,本文对我国重点保护水域－第二松花江的支流,流经长春市的伊通河现行过严的功能分类标准提出质疑;并根据第二松花江干流的功能要求和实施流域水污染总量控制的原则,通过预测与计算,提出了伊通河应分河段,跨类别控制的较为科学合理又切实可行的功能分类建议。     

BP及RBF人工神经元网络对臭氧生物活性炭水处理系统建模的比较

运用BP和RBF人工神经元网络建立臭氧生物活性炭系统模型,考察了两个网络对水处理系统建模的适应性。研究表明,BP和RBF人工神经元网络的臭氧生物活性炭系统模型准确地描述了系统影响因素的关系,可以求出系统中臭氧的经济投量;用BP人工神经元网络建立水处理系统模型,泛化能力好,但逼近速度较慢;运用RBF人工神经元网络建模,泛化能力较差,但逼近速度快。该项研究克服了运用传统方法建模的不足,为实现水处理系统的优化设计提供了可行的途径。