全文获取类型
收费全文 | 16335篇 |
免费 | 172篇 |
国内免费 | 137篇 |
专业分类
安全科学 | 448篇 |
废物处理 | 627篇 |
环保管理 | 2285篇 |
综合类 | 2567篇 |
基础理论 | 4459篇 |
环境理论 | 4篇 |
污染及防治 | 4295篇 |
评价与监测 | 1005篇 |
社会与环境 | 851篇 |
灾害及防治 | 103篇 |
出版年
2022年 | 111篇 |
2021年 | 129篇 |
2020年 | 105篇 |
2019年 | 148篇 |
2018年 | 224篇 |
2017年 | 220篇 |
2016年 | 354篇 |
2015年 | 239篇 |
2014年 | 357篇 |
2013年 | 1265篇 |
2012年 | 441篇 |
2011年 | 632篇 |
2010年 | 536篇 |
2009年 | 519篇 |
2008年 | 689篇 |
2007年 | 691篇 |
2006年 | 659篇 |
2005年 | 506篇 |
2004年 | 587篇 |
2003年 | 521篇 |
2002年 | 482篇 |
2001年 | 702篇 |
2000年 | 471篇 |
1999年 | 282篇 |
1998年 | 241篇 |
1997年 | 217篇 |
1996年 | 227篇 |
1995年 | 247篇 |
1994年 | 271篇 |
1993年 | 219篇 |
1992年 | 247篇 |
1991年 | 222篇 |
1990年 | 254篇 |
1989年 | 238篇 |
1988年 | 193篇 |
1987年 | 173篇 |
1986年 | 158篇 |
1985年 | 167篇 |
1984年 | 192篇 |
1983年 | 180篇 |
1982年 | 185篇 |
1981年 | 179篇 |
1980年 | 137篇 |
1979年 | 153篇 |
1978年 | 131篇 |
1977年 | 117篇 |
1975年 | 118篇 |
1974年 | 115篇 |
1973年 | 110篇 |
1972年 | 133篇 |
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
601.
Polychlorinated biphenyl contamination trends in Lake Hartwell, South Carolina (USA): sediment recovery profiles spanning two decades 总被引:1,自引:0,他引:1
To assess the ca. 20-year polychlorinated biphenyl (PCB) contamination trends in Lake Hartwell, SC, sediment cores from the Twelve Mile Creek arm were collected in July 2004 at two sites (G30 and G33) first sampled in the mid-1980s. Congener-specific PCB data as a function of depth from the sediment-water interface for the 2004 sediment samples were compared to data obtained from 1987 and 1998 samples taken from the same locations. Despite modest decreases in total PCB levels near the G30 sediment-water interface, historical increases in average degrees of chlorination may elevate the overall toxic risk at this site. Unlike G30, the more rapid recovery in the near-surface sediment of G33 suggests that the effectiveness of the U.S. EPA natural attenuation record of decision is site-specific and is unlikely to result in uniform surface sediment recovery throughout the most contaminated regions of Lake Hartwell. 相似文献
602.
Ethier AL Braune BM Scheuhammer AM Bond DE 《Environmental pollution (Barking, Essex : 1987)》2007,145(3):915-919
To determine if significant differences exist in lead (Pb) accumulation in different bones, especially those most often used for bone-Pb studies in wildlife, we compared Pb concentrations in radius, ulna, humerus, femur, and tibia of Common Eider (Somateria mollissima); and radius/ulna (combined), femur, and tibia of American Woodcock (Scolopax minor). There were no significant differences in bone-Pb concentrations among woodcock bones over a wide range of Pb concentrations (3-311 microg/g). In eider, where bone-Pb concentrations were low (<10 microg/g), leg bones had significantly higher Pb concentrations (approximately 30-40%) than wing bones from the same individuals. The variation among individual birds was greater than the variation among different bones within a bird. Based on our findings, we conclude that one type of bone may be substituted for another in bone-Pb studies although the same bone type should be analyzed for all birds within a study, whenever possible. 相似文献
603.
Dynamic responses of photosystem II in the Namib Desert shrub, Zygophyllum prismatocarpum, during and after foliar deposition of limestone dust 总被引:1,自引:0,他引:1
van Heerden PD Krüger GH Kilbourn Louw M 《Environmental pollution (Barking, Essex : 1987)》2007,146(1):34-45
The effects of limestone dust deposition on vegetation in desert ecosystems have not yet been reported. We investigated these effects in a succulent shrub from the Namib Desert at a limestone quarry near Skorpion Zinc mine (Namibia). Effects of limestone dust were determined in Zygophyllum prismatocarpum (dollar bush) plants with heavy, moderate and no visible foliar dust cover by means of chlorophyll a fluorescence measurements. Limestone dust deposition decreased overall plant performance through loss of chlorophyll content, inhibition of CO(2) assimilation, uncoupling of the oxygen-evolving complex and decreased electron transport. Importantly, dynamic recovery occurred after termination of limestone extraction at the quarry. Recovery was accelerated by rainfall, mainly because of dust removal from leaves and stimulation of new growth. These results indicate that limestone dust has severe effects on photosynthesis in desert shrubs, but that recovery is possible and that, in arid environments, this process is modulated by rainfall. 相似文献
604.
Comparative toxicity of chlorpyrifos, diazinon, malathion and their oxon derivatives to larval Rana boylii 总被引:1,自引:0,他引:1
Organophosphorus pesticides (OPs) are ubiquitous in the environment and are highly toxic to amphibians. They deactivate cholinesterase, resulting in neurological dysfunction. Most chemicals in this group require oxidative desulfuration to achieve their greatest cholinesterase-inhibiting potencies. Oxon derivatives are formed within liver cells but also by bacterial decay of parental pesticides. This study examines the toxicity of chlorpyrifos, malathion and diazinon and their oxons on the foothill yellow-legged frog (Rana boylii). R. boylii is exposed to agricultural pesticides in the California Central Valley. Median lethal concentrations of the parental forms during a 96 h exposure were 3.00 mg/L (24h) for chlorpyrifos, 2.14 mg/L for malathion and 7.49 mg/L for diazinon. Corresponding oxons were 10 to 100 times more toxic than their parental forms. We conclude that environmental concentrations of these pesticides can be harmful to R. boylii populations. 相似文献
605.
Water is key element in human life. All forms of life upon the earth depend upon water for their mere existence. Life & water
may be aptly said to be two facets of the same coin. Most of the water bodies are getting polluted due to domestic waste,
sewage, industrial waste and agricultural effluent. The present study is designed to ascertain the effectiveness of artificial
aeration cum Ozonizer unit installed at Lower Lake, Bhopal for assessment of water quality. Various physico- chemical parameters
like pH, Dissolved oxygen, Biochemical Oxygen demand, Chemical oxygen demand, nitrate, phosphate and bacteriological status
were studied to assess the extent of deterioration in water quality of Lower lake and at the same time to assess the performance
of the dual aeration system in improvement of water quality. 相似文献
606.
Factors affecting river health and its assessment over broad geographic ranges: the Western Australian experience 总被引:1,自引:0,他引:1
Halse SA Scanlon MD Cocking JS Smith MJ Kay WR 《Environmental monitoring and assessment》2007,134(1-3):161-175
AusRivAS is an Australia-wide program that measures river condition using predictive models to compare the macroinvertebrate
families occurring at a river site with those expected if the site were in natural condition. Results of assessment of 685
sites across all major rivers in Western Australia are presented. Most rivers were in relatively natural condition in the
northern half of the state where the human population is low and pastoralism is the major land use. In the south, where the
human population is higher and agriculture is more intensive, rivers were mostly more disturbed. AusRivAS assessment produced
some erroneous results in rivers of the south-west cropping zone because of the lack of appropriate reference site groups
and biased distribution of sampling sites. Collecting low numbers of animals from many forested streams, because of low stream
productivity and samples that were difficult to sort, also affected assessments. Overall, however, AusRivAs assessment identified
catchment processes that were inimical to river health. These processes included salinisation, high nutrient and organic loads,
erosion and loss of riparian vegetation. River regulation, channel modification and fire were also associated with river degradation.
As is the case with other assessment methods, one-off sampling at individual sites using AusRivAS may be misleading. Seasonal
drought, in particular, may make it difficult to relate conditions at the time of sampling to longer-term river health. AusRivAS
has shown river condition in Western Australia is not markedly different from other parts of Australia which, as a whole,
lacks the substantial segments of severely degraded river systems reported in England. 相似文献
607.
The inorganic nitrogen transformations occurring at a municipal waste leachate treatment facility were investigated. The treatment
facility consisted of a collection well and an artificial wetland between two aeration ponds. The first aeration pond showed
a decrease in ammonium (from 3480 (± 120) to 630(± 90) mg ⋅ L−1), a reduction in inorganic nitrogen load (3480 to 1680 mg N ⋅ L−1), and an accumulation of nitrite (< 1.3 mg-N ⋅ L−1 in the collection well, to 1030 mg-N ⋅ L−1). Incomplete ammonium oxidation was presumably the result of the low concentration of carbonate alkalinity (∼2 mg ⋅ L−1), which may cause a limitation in the ammonium oxidation rate of nitrifiers. Low carbonate alkalinity levels may have been
the result of stripping of CO2 from the first aeration pond at the high aeration rates and low pH. Various chemodenitrification mechanisms are discussed
as the reason for the reduction in the inorganic nitrogen load, including; the reduction of nitrite by iron (II) (producing
various forms of gaseous nitrogen); and reactions involving nitrous acid. It is suggested that the accumulation of nitrite
may be the result of inhibition of nitrite oxidizers by nitrous acid and low temperatures. Relative to the first aeration
pond, the speciation and concentration of inorganic nitrogen was stable in the wetlands and 2nd aeration pond. The limited
denitrification in the wetlands most probably occurred due to low concentrations of organic carbon, and short retention times. 相似文献
608.
Organic pollutants in compost and digestate. Part 1. Polychlorinated biphenyls, polycyclic aromatic hydrocarbons and molecular markers 总被引:1,自引:0,他引:1
Brändli RC Bucheli TD Kupper T Furrer R Stahel WA Stadelmann FX Tarradellas J 《Journal of environmental monitoring : JEM》2007,9(5):456-464
In Europe, 9.3 x 10(6) t(dry weight (dw)) of compost and digestate are produced per year. Most of this is applied to agricultural land, which can lead to considerable inputs of organic pollutants, such as polychlorinated biphenyls (PCB) and polycyclic aromatic hydrocarbons (PAH) to soil. This paper presents an inventory of the pollutant situation in source-separated composts, digestates and presswater in Switzerland by a detailed analysis of over 70 samples. PCB concentrations ( summation PCB 28, 52, 101, 118, 138, 153, 180) were significantly higher in urban (median: 30 microg kg(-1)dw, n = 52) than in rural samples (median: 14 microg kg(-1)dw, n = 16). Together with low concentrations in general, this points to aerial deposition on compost input material as the major contamination pathway. Enantiomeric fractions of atropisometric PCB were close to racemic. Median PAH concentration was 3010 microg kg(-1)dw( summation 15PAH, n = 69), and one quarter of the samples exhibited concentrations above the relevant Swiss guide value for compost (4000 microg kg(-1)dw). The levels were influenced by the treatment process (digestate > compost), the season of input material collection (spring-summer > winter > autumn), the particle size (coarse-grained > fine-grained), and maturity (mature > less mature). The main source of PAH in compost was pyrogenic, probably influenced mainly by liquid fossil fuel combustion and some asphalt abrasion, as suggested by multiple linear regression. This study, together with a companion paper reporting on other organic contaminates including emerging compound classes, provides a starting point for a better risk-benefit estimation of the application of compost and digestate to agricultural soil in Switzerland. 相似文献
609.
Harrad S Robson M Hazrati S Baxter-Plant VS Deplanche K Redwood MD Macaskie LE 《Journal of environmental monitoring : JEM》2007,9(4):314-318
The environmentally prevalent polybrominated diphenyl ether (PBDE) #47 and polychlorinated biphenyls (PCBs) #28 and #118 were challenged for 24 hours with a novel biomass-supported Pd catalyst (Bio-Pd(0)). Analysis of the products via GC-MS revealed the Bio-Pd(0) to cause the challenged compounds to undergo stepwise dehalogenation with preferential loss of the least sterically hindered halogen atom. A mass balance for PCB #28 showed that it is degraded to three dichlorobiphenyls (33.9%), two monochlorobiphenyls (12%), and biphenyl (30.7%). The remaining mass was starting material. In contrast, while PCB #118 underwent degradation to yield five tetra- and five trichlorinated biphenyls, no less chlorinated products or biphenyl were detected, and the total mass of degraded products was 0.3%. Although the Bio-Pd(0) material was developed for treatment of PCBs, a mass balance for PBDE #47 showed that the biocatalyst could prove a potentially useful method for treatment of PBDEs. Specifically, 10% of PBDE #47 was converted to identifiable lower brominated congeners, predominantly the tribrominated PBDE #17 and the dibrominated PBDE #4, 75% remained intact, while 15% of the starting mass was unaccounted for. 相似文献
610.
Trott D Dawson JJ Killham KS Miah MR Wilson MJ Paton GI 《Journal of environmental monitoring : JEM》2007,9(1):44-50
Despite the widespread and successful use of luminescence-based bioassays in water testing, their applications to soils and sediments is less proven. In part this is because such bioassays have mainly been carried out in an aqueous-based medium and, as such, favour contaminants that are readily water-soluble. In this study, aqueous solutions and soils contaminated with heavy metals (HM), polar organic contaminants and hydrophobic organic contaminants (HOCs) were tested using a range of luminescence-based bioassays (Vibrio fischeri, Escherichia coli HB101 pUCD607 and Pseudomonas fluorescens 10586r pUCD607). For the first two chemical groups, the assays were highly reproducible when optimised extraction procedures were employed but for HOCs the bioassay response was poor. Quantitative structure-activity relationships (QSARs) obtained from aqueous solutions had a linear response although correlation for the chemicals tested using bacterial bioassays was significantly less sensitive than that of sublethal tests for Tetrahymena pyriformis. Bacterial and Dendrobaena veneta bioassay responses to extracts from HM amended soils showed that a clear relationship between trophic levels could be obtained. There is no doubt that the wide range of bioluminescent-based bioassays offers complementary applications to traditional testing techniques but there is a significant need to justify and optimise the extraction protocol prior to application. 相似文献