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671.
In 1974, Junge postulated a relationship between variability of concentrations of gases in air at remote locations and their atmospheric residence time, and this Junge relationship has subsequently been observed empirically for a range of trace gases. Here, we analyze two previously-published datasets of concentrations of cyclic volatile methyl siloxanes (cVMS) in air and find Junge relationships in both. The first dataset is a time series of concentrations of decamethylcyclopentasiloxane (D5) measured between January and June, 2009 at a rural site in southern Sweden that shows a Junge relationship in the temporal variability of the measurements. The second dataset consists of measurements of hexamethylcyclotrisiloxane (D3), octamethylcyclotetrasiloxane (D4) and D5 made simultaneously at 12 sites in the Global Atmospheric Passive Sampling (GAPS) network that shows a Junge relationship in the spatial variability of the three cVMS congeners. We use the Junge relationship for the GAPS dataset to estimate atmospheric lifetimes of dodecamethylcyclohexasiloxane (D6), 8:2–fluorotelomer alcohol and trichlorinated biphenyls that are within a factor of 3 of estimates based on degradation rate constants for reaction with hydroxyl radical determined in laboratory studies. 相似文献
672.
In this research, low-heat alkaline pretreatment was evaluated to determine the extent to which urban landscape waste (yard waste), corn stover, and switchgrass could be codigested under conditions typical of US farm-based anaerobic digestion (AD). Waste heat from combined heat and power (CHP) units associated with AD could make such pretreatment economical. Short-term batch digestion studies and 8-week continuous-feed studies were used to screen and evaluate various pretreatment conditions. Results indicate that maple and oak leaves did not digest well, even with pretreatment. Pretreatment did improve digestion of corn leaves and stalks as well as switchgrass. However, these materials also digested reasonably well even without pretreatment. No digester operational problems were observed during continuous-feed studies of intermittently stirred bench top digesters, but optimal levels of alkali, temperature, and pretreatment time may be specific to the feedstock, particle size, and digester loading rate. Results suggest that some common lignocellulosic biomass materials, such as corn stover and switchgrass, could be successfully codigested in many existing farm-based digesters. Interestingly, without pretreatment, switchgrass digestion improved over 20-fold when digested with seed culture from a dairy digester compared to seed culture from a municipal digester, suggesting that culture acclimation could be as important as pretreatment in improving digestion of specific lignocellulosic feedstocks. 相似文献
673.
The dominant discourse in 20th century UK food and agricultural policies of a liberal, free trade agenda was modified at the
turn of the 21st to embrace ecological sustainability and “food security.” The latter term has a long international history;
the relationship between issues of technical production and equality of distributional access are also much debated. The paper
examines shifts in UK policy discourse in the context of international research, policy, and initiatives to promote food security,
and highlights the implications for social justice in and through the food system. 相似文献
674.
This article gives an overview of the studies on the environment surrounding the Abisko Scientific Research Station in Swedish Lapland. The long-term monitoring of the Station on processes related to the climate, and to the physical, biotic, and chemical environmental conditions is particularly addressed. Some variables are recorded since more than 100 years. The obtained data in combination with results from short-term studies and manipulation experiments are important to understand past and future conditions of the ecosystems. This has practical applications for the planning of tourism, transports, reindeer herding, and for societal purposes. 相似文献
675.
Christensen TR Jackowicz-Korczyński M Aurela M Crill P Heliasz M Mastepanov M Friborg T 《Ambio》2012,41(Z3):207-217
This article reports a dataset on 8 years of monitoring carbon fluxes in a subarctic palsa mire based on micrometeorological eddy covariance measurements. The mire is a complex with wet minerotrophic areas and elevated dry palsa as well as intermediate sub-ecosystems. The measurements document primarily the emission originating from the wet parts of the mire dominated by a rather homogenous cover of Eriophorum angustifolium. The CO(2)/CH(4) flux measurements performed during the years 2001-2008 showed that the areas represented in the measurements were a relatively stable sink of carbon with an average annual rate of uptake amounting to on average -46 g C m(-2) y(-1) including an equally stable loss through CH(4) emissions (18-22 g CH(4)-C m(-2) y(-1)). This consistent carbon sink combined with substantial CH(4) emissions is most likely what is to be expected as the permafrost under palsa mires degrades in response to climate warming. 相似文献
676.
Biodegradation of PCBs by ligninolytic fungi and characterization of the degradation products 总被引:4,自引:0,他引:4
The aim of the present study was to compare the degrading capabilities of eight ligninolytic fungal representatives towards a technical mixture of polychlorinated biphenyls (Delor 103). Axenic cultures of the fungi, either in complex or N-limited liquid media, were spiked with the technical mixture of Delor 103. All of the fungal strains were able to degrade the pollutant significantly after 6weeks of incubation in both media. Outstanding results were achieved by the treatment with Pleurotus ostreatus, which removed 98.4% and 99.6% of the PCB mixture in complex and mineral media, respectively. This fungus was the only one capable of breaking down penta- and hexachlorinated biphenyls in the complex medium. Ecotoxicological assays performed with the luminescent bacterium Vibrio fischeri demonstrated that all of the fungal strains employed in this study were able to remove the toxicity only temporarily (e.g., after 28d of incubation), while P. ostreatus was capable of suppressing the toxicity associated to PCBs along the whole incubation period in both media. We also performed an extensive set of qualitative GC/MS analyses and chlorinated derivatives of hydroxy- and methoxy-biphenyls were detected along with monoaromatic structures, i.e. chlorobenzoic acids, chlorobenzaldehydes and chlorobenzyl alcohols. This results indicate that both intracellular (cytochrome P-450 monooxigenase, aryl-alcohol dehydrogenase and aryl-aldehyde dehydrogenase) and extracellular (ligninolytic enzymes) enzymatic systems could be involved in the biotransformation of PCB by ligninolytic fungi. The data from this work also document that the fungi are able to degrade further the main metabolites on the PCB pathway (i.e. chlorobenzoic acids) simultaneously with PCBs. 相似文献
677.
González-Arias Judith Zhang Zhien Reina Tomás R. Odriozola José A. 《Environmental Chemistry Letters》2023,21(6):3089-3104
Environmental Chemistry Letters - The rising adverse effects of climate change call for a rapid shift to low-carbon energy and reducing our dependence on fossil fuels. For that, biorefineries... 相似文献
678.
Daniel Kozák Marek Svitok Veronika Zemlerová Martin Mikoláš Thibault Lachat Laurent Larrieu Yoan Paillet Arne Buechling Radek Bače William S. Keeton Lucie Vítková Krešimir Begovič Vojtěch Čada Martin Dušátko Matej Ferenčík Michal Frankovič Rhiannon Gloor Jeňýk Hofmeister Pavel Janda Ondrej Kameniar Tomáš Kníř Linda Majdanová Marek Mejstřík Jakob Pavlin Dheeraj Ralhan Ruffy Rodrigo Catalin-Constantin Roibu Michal Synek Ondřej Vostarek Miroslav Svoboda 《Conservation biology》2023,37(3):e14066
Protecting structural features, such as tree-related microhabitats (TreMs), is a cost-effective tool crucial for biodiversity conservation applicable to large forested landscapes. Although the development of TreMs is influenced by tree diameter, species, and vitality, the relationships between tree age and TreM profile remain poorly understood. Using a tree-ring-based approach and a large data set of 8038 trees, we modeled the effects of tree age, diameter, and site characteristics on TreM richness and occurrence across some of the most intact primary temperate forests in Europe, including mixed beech and spruce forests. We observed an overall increase in TreM richness on old and large trees in both forest types. The occurrence of specific TreM groups was variably related to tree age and diameter, but some TreM groups (e.g., epiphytes) had a stronger positive relationship with tree species and elevation. Although many TreM groups were positively associated with tree age and diameter, only two TreM groups in spruce stands reacted exclusively to tree age (insect galleries and exposed sapwood) without responding to diameter. Thus, the retention of trees for conservation purposes based on tree diameter appears to be a generally feasible approach with a rather low risk of underrepresentation of TreMs. Because greater tree age and diameter positively affected TreM development, placing a greater emphasis on conserving large trees and allowing them to reach older ages, for example, through the establishment of conservation reserves, would better maintain the continuity of TreM resource and associated biodiversity. However, this approach may be difficult due to the widespread intensification of forest management and global climate change. 相似文献
679.
Francesco Dalla Longa Teun Strikkers Tom Kober Bob van der Zwaan 《Environmental Modeling and Assessment》2018,23(6):627-637
One of the main goals in pursuing sustainable development is to provide universal access to modern energy services, notably through the use of off-grid renewable energy technologies. To date, integrated assessment models (IAMs) poorly address energy access targets. In the context of research dedicated to energy scenarios and climate change mitigation in Africa, we attempt to advance the representation of energy access in one such IAM by using GIS data. In a case study for Ethiopia with the TIAM-ECN model, we demonstrate that by enriching an IAM with information derived from GIS databases, insights are obtained that better capture the dynamics of energy access developments, in comparison to conventional IAM analysis of energy technology deployment pathways. When duly accounting for the geographical spread in demography and technology costs in a developing country, we find that many people may gain access to electricity in remote areas thanks to the availability of affordable off-grid power production options that render expensive grid extensions unnecessary. This effect is not explicitly accounted for in most traditional IAMs. By the middle of the century, off-grid technologies could provide affordable electricity to 70% of the Ethiopian population, based almost entirely on renewable sources such as wind, solar and hydropower. 相似文献
680.
S. A. Norton I. J. Fernandez J. S. Kahl L. E. Rustad Tomás Navrátil H. Almquist 《Environmental monitoring and assessment》2010,171(1-4):3-21
The Bear Brook Watershed in Maine (BBWM), USA is a paired watershed study with chemical manipulation of one watershed (West Bear = WB) while the other watershed (East Bear = EB) serves as a reference. Characterization of hydrology and chemical fluxes occurred in 1987–1989 and demonstrated the similarity of the ca. 10 ha adjacent forested watersheds. From 1989–2010, we have added 1,800 eq (NH4)2SO4 ha???1 y???1 to WB. EB runoff has slowly acidified even as atmospheric deposition of SO $_{4}^{2-}$ has declined. EB acidification included decreasing pH, base cation concentrations, and alkalinity, and increasing inorganic Al concentration, as SO $_{4}^{2-}$ declined. Organic Al increased. WB has acidified more rapidly, including a 6-year period of increasing leaching of base cations, followed by a long-term decline of base cations, although still elevated over pretreatment values, as base saturation declined in the soils. Sulfate in WB has not increased to a new steady state because of increased anion adsorption accompanying soil acidification. Dissolved Al has increased dramatically in WB; increased export of particulate Al and P has accompanied the acidification in both watersheds, WB more than EB. Nitrogen retention in EB increased after 3 years of study, as did many watersheds in the northeastern USA. Nitrogen retention in WB still remains at over 80%, in spite of 20+ years of N addition. The 20-year chemical treatment with continuous measurements of critical variables in both watersheds has enabled the identification of decadal-scale processes, including ecosystem response to declining SO $_{4}^{-2}$ in ambient precipitation in EB and evolving mechanisms of treatment response in WB. The study has demonstrated soil mechanisms buffering pH, declines in soil base saturation, altered P biogeochemistry, unexpected mechanisms of storage of S, and continuous high retention of treatment N. 相似文献