Silane removal at ambient temperature by using alumina-supported metal oxide adsorbents

Copper, zinc, and cerium oxide adsorbents supported on alumina were used to remove silane gas (SiH4). The adsorbents were prepared using a coprecipitation method and characterized by the inductively coupled plasma mass spectrometry, X-ray powder diffractometer, and Brunauer-Emmett-Teller method (BET). The silane removal efficiency and adsorption capacity of the adsorbents were investigated in this study. Test results showed that the adsorbents containing active species had a removal efficiency >99.9% for SiH4 before breakthrough. Adsorbents containing mixed oxides (CuO-CeO2/ Al2O3 and CuO-ZnO/Al2O3), which showed well-dispersed active species and high BET surface areas, had a greater adsorption capacity than the adsorbents containing single metal oxide. However, when the CuO-ZnO/ Al2O3 adsorbents contain >40 wt% of active metal oxides, the increase of active species lowered the BET surface area leading to a decrease of the adsorption capacity. Additionally, when the content of the active metal oxides was between 20% and 40%, the CuO-ZnO/Al2O3 adsorbents demonstrated higher adsorption capacity.     

The Application of Water Quality Monitoring Data in a Reservoir Watershed Using AMOS Confirmatory Factor Analyses

This study investigates six water quality monitoring stations in the watershed of the Feitsui Reservoir. It uses nine parameters of water quality collected in an interval of two and half years for factor analyses, which was first conducted to determine four types of factors, respectively, those for organic pollution, eutrophication, seasonal influence, and sediment pollution. The analysis results effectively help to determine water quality in the watershed of the reservoir. The authors reutilize analysis of moment structures (AMOS) to acquire further results in order to confirm the goodness of fit of the previous factor analysis model. During the confirmation, we examine the hypothesized orthogonal results as well as utilize oblique rotation to explore the goodness of fit of the reflective indicators of the orthogonal rotation. As shown in the algorithm results, as long as the covariance curve is included in the four factors, no related issues are detected in the goodness of fit of reflective indicators and interior and external quality is reported with excellence. The orthogonal model, thus, stands. Additionally, when the analysis of structural equation modeling (SEM) is conducted, sample data mismatches the hypotheses of multivariate normality. Therefore, this study adopts the generalized least square (GLS) for an algorithm. Research results of this study have been submitted to the reservoir management authorities in Taiwan for the improvement of statistical application and strategic evaluation of water quality monitoring data in order to strengthen the managerial effectiveness of water quality in watersheds.     

Study of the ambient air metallic elements Cr,Cu, Zn,Cd and Pb at HAF sampling sites

This study characterized diurnal variations in the compositions of total suspended particulates (TSP) and dry deposits of particulates from ambient air, and the metallic elements that are contained in them at harbor, airport and farmland (HAF) sampling sites from August, 2013 to July, 2014. Two-way ANOVA of the amounts of metallic elements in the TSP and dry deposits was carried out in all four seasons at the HAF sampling sites. The metallic elements Cr and Cu originated in local emission sources at the airport. Metallic elements Zn and Pb originated in local emission sources at the harbor. Finally, metallic element Cd originated in local emissions form farmland. The following results were also obtained. (1) The metallic composition of the TSP differed significantly from that of the dry deposits in all four seasons at the harbor and farmland sampling sites, but not at the airport sampling site. (2) High correlations coefficients were found between the amounts of metallic elements Cr and Cu in the TSP and those in the dry deposits at the airport sampling site. (3) Pb was present in the TSP and the dry deposits at the harbor sampling site.     

Annual ambient atmospheric mercury speciation measurement from Longjing,a rural site in Taiwan

The main purpose of this study was to monitor ambient air particulates and mercury species [RGM, Hg(p), GEM and total mercury] concentrations and dry depositions over rural area at Longjing in central Taiwan during October 2014 to September 2015. In addition, passive air sampler and knife-edge surrogate surface samplers were used to collect the ambient air mercury species concentrations and dry depositions, respectively, in this study. Moreover, direct mercury analyzer was directly used to detect the mercury Hg(p) and RGM concentrations. The result indicated that: (1) The average highest RGM, Hg(p), GEM and total mercury concentrations, and dry depositions were observed in January, prevailing dust storm occurred in winter season was the possible major reason responsible for the above findings. (2) The highest average RGM, Hg(p), GEM and total mercury concentrations, dry depositions and velocities were occurred in winter. This is because that China is the largest atmospheric mercury (Hg) emitter in the world. Its Hg emissions and environmental impacts need to be evaluated. (3) The results indicated that the total mercury ratios of Kaohsiung to that of this study were 5.61. This is because that Kaohsiung has the largest industry density (~60 %) in Taiwan. (4) the USA showed average lower mercury species concentrations when compared to those of the other world countries. The average ratios of China/USA values were 89, 76 and 160 for total mercury, RGM and Hg(p), respectively, during the years of 2000–2012.     

Nitrous oxide emissions from wastewater treatment and water reclamation plants in southern California

Nitrous oxide (N?O) is a long-lived and potent greenhouse gas produced during microbial nitrification and denitrification. In developed countries, centralized water reclamation plants often use these processes for N removal before effluent is used for irrigation or discharged to surface water, thus making this treatment a potentially large source of N?O in urban areas. In the arid but densely populated southwestern United States, water reclamation for irrigation is an important alternative to long-distance water importation. We measured N?O concentrations and fluxes from several wastewater treatment processes in urban southern California. We found that N removal during water reclamation may lead to in situ N?O emission rates that are three or more times greater than traditional treatment processes (C oxidation only). In the water reclamation plants tested, N?O production was a greater percentage of total N removed (1.2%) than traditional treatment processes (C oxidation only) (0.4%). We also measured stable isotope ratios (δN and δO) of emitted N?O and found distinct δN signatures of N?O from denitrification (0.0 ± 4.0 ‰) and nitrification reactors (-24.5 ± 2.2 ‰), respectively. These isotope data confirm that both nitrification and denitrification contribute to N?O emissions within the same treatment plant. Our estimates indicate that N?O emissions from biological N removal for water reclamation may be several orders of magnitude greater than N?O emissions from agricultural activities in highly urbanized southern California. Our results suggest that wastewater treatment that includes biological nitrogen removal can significantly increase urban N?O emissions.     

The establishment of a standard operation procedure for psychiatric service after an earthquake

This study presents information on the design and creation of a standard operation procedure (SOP) for psychiatric service after an earthquake. The strategies employed focused on the detection of survivors who developed persistent psychiatric illness, particularly post-traumatic stress and major depressive disorders. In addition, the study attempted to detect the risk factors for psychiatric illness. A Disaster-Related Psychological Screening Test (DRPST) was designed by five psychiatrists and two public health professionals for rapidly and simply interviewing 4,223 respondents within six months of the September 1999 Chi-Chi earthquake. A SOP was established through a systemic literature review, action research, and two years of data collection. Despite the limited time and resources inherent to a disaster situation, it is necessary to develop an SOP for psychiatric service after an earthquake in order to assist the high number of survivors suffering from subsequent psychiatric impairment.     

Interactive analysis and environmental policy for mitigating the consumption of potent greenhouse gases in Taiwan

Taiwan, although not a Party to the Montreal Protocol on Substances That Deplete the Ozone Layer and the UN Framework Convention on Climate Change Kyoto Protocol, has diligently strived to advance technological and social changes for mitigating the use of potent greenhouse gases, including hydrochlorofluorocarbons (HCFCs) and hydrofluorocarbons (HFCs). The objective of this paper is to present an interactive analysis of HCFCs and HFCs consumptions under the regulatory framework and policy promotion in Taiwan during the period of 2000–2009. It was concluded that the consumption of HCFCs was on the significant decrease during this period because they are being replaced now by HFCs. In response, the consumption of HFCs with relatively low global warming potentials was on increasing trend from 861 t in 2000 to 2,923 t in 2009. Based on the inventory of HFCs, the most important source for the emissions of HFCs in Taiwan should be from HFC-134a, which was consistent with the East Asian countries such as Japan and South Korea. Finally, global HCFCs production and consumption was analyzed in comparison with Taiwan’s HCFCs demand trend.     

Full-scale experimental studies for backdraft using solid materials

The backdraft experiments involved three full-scale room fire tests that used solid furnishing, loveseats. From experimental data, a backdraft caused two temperature peaks. The first one was below 600 °C. Then, an abrupt opening of the front door led to a supply of a large amount of fresh air, followed by an indication of sudden temperature rise. The second peak temperature was over 600 °C. Meanwhile, the deflagration resulted in the gases heating and expanding within the fire space, thus forcing unburned gases out of the vent ahead of the flame front. Comparing both cases with natural gas and solid loveseat as the fuel in backdraft, the former can achieve pre-mixture state and readily create an instant explosion wave phenomenon; however, this wave disappeared immediately. On the other hand, the solid loveseat used as the fuel in this study produced backdraft within 30–50 s after opening of the door. After the occurrence of backdraft, fire maintained a period of fully developed stage, which was consistent with the conditions in actual fires.     

Southeastward transport of Asian dust: Source,transport and its contributions to Taiwan

Atmospheric Aluminum measured in northern Taiwan from 2003 to 2006 is used as a dust tracer, from which dust concentrations are derived, and major Asian dust events are determined. The source locations for the major dust events are traced back and identified, and the processes leading to the southeastward transport of Asian dust is investigated. The derived dust concentrations are compared to the local PM₁₀ (particle with size less than 10 μm) concentrations, and the impacts of Asian dust on the air quality of Taiwan are quantified.According to the backward trajectory and dust observation analyses, most of the southeastward transport of major Asian dust events originate from Mongolia and Inner Mongolia in northern China, and only one out of 16 events is generated from western China. Modeling studies and weather analyses of dust events suggest that the southeastward transport of Asian dust is usually generated behind a surface front and transported downwind behind the associated upper level trough. The associated upper level trough is usually deep, in which the northwesterly wind behind the trough favors the southeastward transport of dust to lower latitudes. Dust transported to Taipei generally occur during periods of large-scale subsidence.Asian dust contributes about 15 μg m^?3 of aerosol particles to northern Taiwan during winter monsoon, which accounts for about 24–30% of the PM₁₀ concentrations to the northern Taiwan. The contributions of Asian dust are raised pronouncedly to about 60–70% during major dust events. The impacts of Asian dust on Taiwan's air quality are most substantial in December. The Asian dust impacts decrease in other months, but still remain at around 30% in the late winter to early spring.     

Observation of SO2 dry deposition velocity at a high elevation flux tower over an evergreen broadleaf forest in Central Taiwan

A 60-m flux tower was built on a 2100 m mountain for the measurement of the air pollutant concentration and the evaluation of dry deposition velocity in Central Taiwan. The tower was constructed in an evergreen broadleaf forest, which is the dominant species of forest in the world. Multiple-level SO₂ concentrations and meteorological variables at the site were measured from February to April 2008. The results showed that the mean dry deposition velocities of SO₂ were 0.61 cm s^?1 during daytime and 0.27 cm s^?1 during nighttime. From the comparison of the monthly data, a tendency was observed that the dry deposition velocity increases with LAI and solar radiation. Furthermore, it was observed that the deposition velocity was larger over wet canopy than over dry canopy, and that higher deposition velocities in the wet season were mainly caused by non-stomatal uptake of wet canopy. Over wet canopy, the mean dry deposition velocities of SO₂ were estimated to be 0.83 cm s^?1 during daytime and 0.47 cm s^?1 during nighttime; and 0.44 cm s^?1 during daytime and 0.19 cm s^?1 during nighttime over dry canopy. There is good agreement between the results of this study and those in other studies and the predictions of Zhang et al. (2003a). The medians (geometric means) of derived r_c during daytime are 233 (266) m s^?1 over dry canopy and 147 (146) m s^?1 over wet canopy. It was found that solar radiation is the critical important meteorological variable determining stomatal resistance during daytime. For non-stomatal resistance, clear dependencies were observed on the friction velocity and relative humidity.