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81.
Yunxue Xia Dong Qiu Zhong Lyv Jianshuai Zhang Narendra Singh Kaimin Shih Yuanyuan Tang 《Frontiers of Environmental Science & Engineering》2023,17(5):61
82.
Shih L. Chen John C. Kramlich W. Randall Seeker David W. Pershing 《Journal of the Air & Waste Management Association (1995)》2013,63(10):1375-1379
This paper summarizes an experimental study which was conducted to investigate the chemical constraints of the reburning process and identify reburning configurations for optimal NOx reduction in coal-fired boilers. Tests were performed on a bench scale tunnel furnace to characterize and optimize the fuel-rich reburning zone and the fuel-lean burnout zone independently. Detailed measurements ofunburned hydrocarbons, CO, NH3, and HCN were made at the reburning zone exit. The influence of the concentrations of reactive species was examined as were temperature effects for both the reburning and burnout zone. Results indicated that reburning zone chemistry was not rate limiting. The impacts of temperature and burnout zone oxidation were of major importance. Integration of the optimum reburning and burnout zone configurations resulted in increased NOx reduction. Over 85 percent reduction in NOx emissions was achieved with ammonium sulfate injection in the burnout zone under optimum reburning conditions. 相似文献
83.
Shih JS Burtraw D Palmer K Siikamäki J 《Journal of the Air & Waste Management Association (1995)》2008,58(9):1117-1129
The animal husbandry industry is a major emitter of ammonia (NH3), which is a precursor of fine particulate matter (PM2.5)--arguably, the number-one environment-related public health threat facing the nation. The industry is also a major emitter of methane (CH4), which is an important greenhouse gas (GHG). We present an integrated process model of the engineering economics of technologies to reduce NH3 and CH4 emissions at dairy operations in California. Three policy options are explored: PM offset credits for NH3 control, GHG offset credits for CH4 control, and expanded net metering policies to provide revenue for the sale of electricity generated from captured methane (CH4) gas. Individually these policies vary substantially in the economic incentives they provide for farm operators to reduce emissions. We report on initial steps to fully develop the integrated process model that will provide guidance for policy-makers. 相似文献
84.
Tung-Sheng Shih Minliang Shih Wen-Jhy Lee Sheng-Lung Huang Lin-Chi Wang Yu-Cheng Chen Perng-Jy Tsai 《Chemosphere》2009,74(11):1463-1470
This study measured particle size distributions of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in two workplace atmospheres of the sintering grate and rough roll shredder in a sintering plant, and to assess their workers’ health-related exposures. We found that the PCDD/F concentration of the sintering grate (site A = 14.47 pg m−3) was lower than that of the rough roll shredder (site B = 17.20 pg m−3). Particle size distributions of PCDD/Fs were in the form of the unimodal with the mass median aerodynamic diameter (MMAD) of 4.74 μm and 5.23 μm, and geometric standard deviation (σg) of 3.15 and 2.15 for the site A and B, respectively. The above results suggest that the workplace of the site A had a less fraction of coarse particles than that of the site B. The estimated PCDD/F concentrations of the inhalable fraction (11.0 pg m−3) and thoracic fraction (8.89 pg m−3) of the site A were lower than those of the site B (12.4 and 9.39 pg m−3, respectively). But to the contrary the estimated respirable fraction of the site A (5.05 pg m−3) was slightly higher than that of the site B (4.93 pg m−3). Our results clearly indicate the importance to conduct particle size segregating samplings for assessing human PCDD/F exposures. 相似文献
85.
Yuanyuan Tang Xiaoye Xin Kaimin Shih Ziyi Wang 《Journal of Material Cycles and Waste Management》2018,20(4):2110-2116
With aluminum as the predominant element, incineration residues from municipal solid waste and sewage sludge may be reused as precursors for zinc stabilization. As solid-state reactions are influenced by the crystal sizes of the reactants, the aluminum-containing components with different crystal sizes in the incineration residues may affect zinc transformation and immobilization. In this study, Al2O3 was prepared with a variety of crystal sizes to simulate the aluminum-rich incineration residue matrix, and ZnO was mixed with Al2O3 to study the zinc incorporation mechanisms. The crystal sizes of Al2O3 were determined using Rietveld refinement. Quantification results showed that ~?30% of zinc was incorporated into the ZnAl2O4 spinel when Al2O3 with the largest crystal size was used. However, the zinc transformation was enhanced twofold when the Al2O3 precursor had the smallest crystal size. This study confirmed the potential enhancement of zinc immobilization by nanoscale crystals in simulated aluminum-rich incineration residues. By improving zinc stabilization efficiencies using poorly crystallized aluminum-containing compounds instead of increasing the energy consumption by increasing the sintering temperatures, we can achieve an economic and environmental win–win scenario for the beneficial utilization of incineration residues of municipal solid waste and sewage sludge. 相似文献
86.
Triclosan (2,4,4'-trichloro-2'-hydroxydiphenyl ether) is a widely used antibacterial agent. However, it was concerned recently that triclosan might act as an antibiotic and will cause resistant bacterial strains. Furthermore, possible formation of toxic chloroform was also reported when the triclosan contained in household dishwashing soaps reacted with the chlorinated water. To assess the associate risks from possible exposures, concentrations of triclosan in household food detergents of Taiwan were determined in this study. High performance liquid chromatography (HPLC) with UV detector at 280 nm was used to analyze the triclosan in samples. Factors that might affect the residual characteristics of triclosan from detergents on dishware and fruits, including the concentrations of detergents used, the temperature and immersion time for water before the cleaning processes, the temperatures of water used for the cleaning processes, and the materials of dishware made of, were evaluated under the orthogonal experiment design by the Taguchi method. By the analysis of variance, the orders of importance of different parameters were determined. The concentrations of triclosan detected in household food detergents were found to be 1.7 x 10(-2) -5.6 x 10(-1) (triclosan/detergent, mg g(-1)). For residual characteristics, the concentration of detergents used as well as the materials of dishware were found to be the significant factors that will affect the triclosan left on the dishware. On the other hand, the concentration of triclosan in the detergents was found to be the only factor that will affect the triclosan left on fruits. The maximum dose of triclosan exposures from the use of household food detergents in Taiwan was also estimated in the study. 相似文献
87.
Lai Yoke Lee Jiang Yong Hu Say Leong Ong How Yong Ng Shih Wei Wong Yaoyu Feng Xiaolan Tan 《Water environment research》2008,80(8):725-731
The application of immunofluorescent labeling using quantum dots for detection of inactivated Cryptosporidium parvum oocysts in spiked water samples (reservoir water, treated wastewater effluent, permeate of a membrane bioreactor, and tap water) provided more consistent results compared with the organic fluorophores label. The varying degree of particles present in the different water samples (with turbidity ranging from 0.2 to 6.1 NTU) in nonconcentrated water samples had insignificant interference on the labeled counts (2-sample t-tests, p > 0.236) using the quantum dot label, while the quantum dot label provided an advantage of approximately 50% lower interference in concentrated water samples compared with the organic fluorophores label. 相似文献
88.
Industrial wastewater sludge was treated by microwave processes to enhance the stabilization of laden copper. The effects of additives, processing time, microwave adsorbents, moisture content, reaction atmosphere, and cooling gas were investigated. The stabilization results were significantly enhanced by metal powder additives, prolonged microwave processing time, proper moisture content, the addition of carbonaceous materials, and a reaction environment with inert gas. It was also found that the moisture content would increase the homogeneity of applied microwave energy, and thus achieve a better overall efficiency between stabilizing agents and copper. The added metal powders may reduce Cu(II) to Cu(0) in the sludge or TCLP. The resulting thermal energy of microwave radiation, and microarcing process and the oxidation heat of Al powder may also assist the transformation of Cu(II) into CuO and CuAl2O4 phases. Part of the sludge was vitrified within inert gas environment when the processing time was longer than 18 min and active carbon dosage was more than 3g. Reduction reactions also occurred in the hybrid microwave processes, leading to the reduction of sulfates and metal ions, and the formation of Cu2S and FeS. Moreover, the microwave radiation can also enhance the feasibility of co-treating of inorganic and organic solid waste. 相似文献
89.
Hsiao-Ku Shih 《International Journal of Green Energy》2016,13(15):1585-1589
Nano-textured polysilicon (poly-Si) solar absorption films are to be applied to the solar receiver of solar thermal electricity Stirling engine. These films were fabricated by deposition of hydrogenated amorphous silicon films (a-Si:H) into poly-Si films, using the pulse-wave modulation plasma and furnace annealing of the a-Si:H films. This is followed by wet etching of poly-Si films into nano-textured structures. The films are then coated with a-SiNx:H films as the antireflection and protection layers. It was observed that increasing the pulsed plasma turn-on (ton) time leads to deposition of less dense a-Si:H film with high hydrogen content and void density. This results in films having low dielectric constant and refractive index, and high optical bandgap. Less-dense a-Si:H film can be transferred into large grain size poly-Si film, using annealing. Also, highly rough nano-textured surface structure can be produced, by etching. The denser a-Si:H film, large grain size poly-Si film, and nano-textured surface poly-Si film can enhance the absorbance of sunlight and reduce the emissivity of far infrared light. The nano-textured poly-Si film coated with an a-SiNx:H layer can effectively increase the absorbance of sunlight to approximately 85% and reduce the emissivity of far infrared light to 49%. The nano-textured poly-Si/a-SiNx:H films can be used as efficient solar absorption films for solar thermal electricity Stirling engine. 相似文献
90.
Cheng‐Shin Jang Chen‐Wuing Liu Shih‐Kai Chen Wen‐Sheng Lin 《Journal of the American Water Resources Association》2012,48(1):61-73
Jang, Cheng‐Shin, Chen‐Wuing Liu, Shih‐Kai Chen, and Wen‐Sheng Lin, 2011. Using a Mass Balance Model to Evaluate Groundwater Budget of Seawater‐Intruded Island Aquifers. Journal of the American Water Resources Association (JAWRA) 48(1): 61‐73. DOI: 10.1111/j.1752‐1688.2011.00593.x Abstract: The study developed a mass balance model to evaluate the groundwater budget of seawater‐intruded island aquifers using limited available data. The Penghu islands were selected as a study area. As sparse observed data were available in the islands, methods of combining water and chloride balances were used to determine the amounts of groundwater pumping, seawater intrusion, aquifer storages, and safe yields in the shallow and deep aquifers. The groundwater budget shows that seawater intrusion to freshwater aquifers was 1.38 × 106 and 0.29 × 106 m3/year in the shallow and deep aquifers, respectively, indicating that the seawater intrusion is severe in the both aquifers. The safe yield of the shallow aquifer was 14.56 × 106 m3/year in 2005 which was four times higher than that of the deep aquifer (3.70 × 106 m3/year). However, the annual pumping amounts in the shallow and deep aquifers were 4.77 × 106 and 3.63 × 106 m3/year, respectively. Although the safe yield of the shallow aquifer is enough for all water resources demands, only 55% of exploitation amount was extracted from the shallow aquifer due to its poor water quality. Groundwater exploitation in the deep aquifer should be significantly reduced and regulated by a dynamic management of pumping scheme because the annual pumping amounts are close to the safe yield and seawater intrusion occurs continually. Additionally, to alleviate further aquifer salination, at least half of the current annual groundwater abstraction should be reduced. 相似文献