Step-up multiple regression model to compute Chlorophyll a in the coastal waters off Cochin, southwest coast of India

The interaction effects of abiotic processes in the production of phytoplankton in a coastal marine region off Cochin are evaluated using multiple regression models. The study shows that chlorophyll production is not limited by nutrients, but their physiological regulations (responses to nutrients, pH, temperature and salinity) are mainly responsible for the increased biological production. The model explaining 77% of variability for chlorophyll a production is indicative of preconditioning of the coastal waters. The phytoplankton production is found to be sensitive to the environment, which varies seasonally. Further, the study suggests that supply of organic matter and grazing of zooplankton (not included) would improve the model efficiency. Despite this, the good agreement in the computed and measured chlorophyll a values shows that step-up multiple regression model is a useful tool to understand the influence of environmental variables on the production of phytoplankton in these coastal waters.     

Precipitation composition and wet deposition temporal pattern in Central Serbia for the period from 1998 to 2004

Bulk samples collected on a daily basis at three principal meteorological stations in central Serbia were analyzed on chloride (Cl(-)), nitrate [Formula: see text], sulfate [Formula: see text], sodium (Na(+)), ammonium [Formula: see text], potassium (K(+)), calcium (Ca(2+)), and magnesium (Mg(2+)) in addition to precipitation amount, pH and conductivity measurements over the period 1998-2004. The data were subjected to variety of analyses (linear regression, principal component analysis, time series analysis) to characterize precipitation chemistry in the study area. The most abundant ion was [Formula: see text] with annual volume weighted mean concentration of 242 microeq L(-1). Neutralization of precipitation acidity occurs both as a result of the dissolution of alkaline compounds containing Ca(2+), Mg(2+), and K(+) as well as the absorption of ammonia. The ratio of [Formula: see text] was above 5, which indicated that the combustion process of low-grade domestic lignite for electricity generation from coal-fired thermal power plants was the main source of pollution in the investigated area. A considerable mean annual bulk wet deposition of SO(4)-S determined by precipitation amount and concentrations of sulfate in the precipitation was calculated to be 12-35 kg ha(-1).     

Heavy metal concentration in fish tissues inhabiting waters of “Buško Blato” reservoar (Bosnia and Herzegovina)

Heavy metals concentration (mercury, lead, cadmium, arsenic, copper, zinc and chromium) in tissues (muscles, liver, kidney and gonads) of Dalmatian barbelgudgeon, the nase, the souffie and brown trout, inhabiting waters of Busko Blato reservoir in Bosnia and Herzegovina, has been determined by atomic absorption spectrophotometry. The meat of the tested fish sorts does not contain elevated concentration of most analyzed heavy metals with exception of lead (higher than MAC in Italy, Germany and Denmark) and mercury (in muscles of brown trout higher than MAC in most countries). The lowest level of all heavy metals is always detected in gonads, with higher values in fry compared to milt for copper, zinc, chromium and arsenic. The highest copper concentration is observed in the liver from the souffie which is suggested as a suitable biomonitor for copper intoxication. In muscles of all fish sorts, lead was always present in much higher concentration than cadmium, while in kidneys of most fish sorts, lead and cadmium concentrations were similar. We showed that bioaccumulation of some heavy metals in the fish sorts analyzed is tissue and sex dependent. Also, we concluded that the small water exchange in reversible shallow reservoir does not induce elevated concentration of heavy metals in fish tissues inhabiting Busko Blato.     

Application of GIS in the study of mass transport of pollutants by Adyar and Cooum Rivers in Chennai, Tamilnadu

Residential, industrial, commercial, institutional and recreational activities discharge degradable and non-degradable wastes that reach the coastal water through rivers and cause coastal pollution. In the present study, mass transport of pollutants by Adyar and Cooum Rivers to the coastal water as a result of land-based discharges was estimated during low tide. The lowest and the highest flow recorded in Adyar varied from 514.59 to 2,585.08×10⁶ litres/day. Similarly, the flow in Cooum River fluctuated between 266.45 and 709.34×10⁶ litres/day. The present study revealed that the Adyar River transported 53.89–454.11 t/d of suspended solids, 0.06–19.64 t/d of ammonia, 15.95–123.24 t/d of nitrate and 0.4–17.86 t/d of phosphate, 0.004–0.09 kg/d of cadmium, 0.15–1.29 kg/d of lead and 3.03–17.58 kg/d of zinc to the coastal water owing to its high discharge. Similarly, the Cooum River transported 11.87–120.06 t/d of suspended solids, 0.08–58.7 t/d of ammonia, 6.11–29.25 t/d of nitrate and 0.66–10.73 t/d of phosphate, 0.003–0.021 kg/d of cadmium, 0.02–0.44 kg/d of lead and 1.36–3.87 kg/d of zinc. A higher concentration of suspended solids was noticed in post monsoon and summer months. An increase in the mass transport of ammonia, nitrate, phosphate in summer months (April and May) and an increase in the mass transport of cadmium, lead and zinc were observed in monsoon months (October–December) in both the rivers. Thus mass transport of pollutants study reveal that Cooum and Adyar Rivers in Chennai contribute to coastal pollution by transporting inorganic and trace metals significantly through land drainage.     

Inputs of chemicals from recreational activities into the Norwegian coastal zone

Wastewater treatment works effluent is often considered to be one of the most important point sources of a wide range of anthropogenic contaminants to aquatic systems, however, this paper discusses other potential sources. With the aim of establishing the important sources of UV filters, insect repellent and biocides to the aquatic environment, samples were collected from sites with direct (bathing areas and marinas) and indirect (sites receiving wastewater effluent) human influences. Sunscreens containing UV filters are used in large volumes during the summer months and often applied shortly before a person enters the water for swimming activities. The results presented here demonstrate that washing directly from the skin is an important point source of 4 UV filters to the Oslofjord. The insect repellent, diethyl toluamide, was also measured and it was concluded that washing from the skin was not such an important point source into the fjord. Concentrations of the biocide Irgarol 1051 were also measured and were elevated in the small boat marina and surrounding enclosed area. This work demonstrates that man recreational water-based activities are a diffuse source of some contaminants into coastal and fjord environments and this study provides an initial assessment of the levels being released.     

Kinetics of sorption of lead on bed sediments of River Hindon, India

A number of low cost waste sorbent have been used for removal of heavy metals, however, few studies have been carried out on the sorption process on riverbed sediments in their natural state of occurrence. Stream sediments adsorb certain solutes from streams, thereby significantly changing the solute composition, but little is known about quantitatively describing sorption phenomena and rates of these processes. In the present investigation, sorption of lead ions on river bed sediments of river Hindon, a tributary of river Yamuna, India has been studied to demonstrate the role of bed sediments in controlling metal pollution. The effect of various operating variables, viz., initial concentration, solution pH, sediment dose, contact time and particle size has been studied. The sorption of lead ions increased with respect to pH and sorbent dose and decreased with sorbent particle size. Two important geochemical phases, iron and manganese oxide, also play important role in the sorption process. The sorption data were analysed using Langmuir and Freundlich isotherm models to determine the mechanistic parameters related to the sorption process. Further, although lead ions have more affinity for the fine fraction of the sediment, but the overall contribution of coarser fraction to sorption is more as compared to clay and silt fraction. The kinetic data suggest that the sorption of lead on bed sediments is an endothermic process, which is spontaneous at low temperature. The uptake of lead is controlled by both bulk and intraparticle diffusion mechanism.     

Cover estimation versus density counting in species-rich pasture under different grazing intensities

Two methods for monitoring of grassland vegetation were compared: visual estimation of plant cover (C) and plant densities counting (D). C and D were performed in monthly intervals for three vegetation growing seasons after imposing different grazing regimes on abandoned grassland in 1998. Species scores obtained from paired redundancy analyses (RDA) of C and D data were compared and Spearman's rank correlations were used to show if the two methods give comparable results. Results of C and D were highly correlated in the first two growing seasons only. In the third season, correlation was substantially lower as the sward structure was more heterogeneous due to creation of differently defoliated patches especially under extensive grazing. Presence of the same plant species with different habit in frequently and in infrequently grazed patches, reduced significance of Spearman's rank correlations. Cover estimation can fully substitute plant density counting in grassland with lower proportion of frequently and infrequently grazed patches only, but caution should be used when comparing different management regimes in long term analyses.     

Multivariate statistical study of seasonal variation of BTEX in the surface water of Savitri River

Volatile organic compounds (VOCs) analysis was carried out for the surface water of the Savitri river during the period of June 2005 to June 2007. BTEX compounds (Benzene, Toluene, Xylene & Ethyl benzene) were analyzed by using micro extraction technique (Purge & Trap). Concentrations of these BTEX compounds were ranging from 0.1 to 1.5 ppm during sampling period. Higher concentrations of BTEX were found at sampling location VI. Concentration of ethyl benzene was very low as compare to other compounds. However, the concentration of benzene was very high. Seasonal variations in conc. of BTEX compounds were observed and higher concentration was detected during the summer season. Salting-out effect had given higher quantification values. In PCA and PFA, the component loading for all the variables are positively correlated. Death of fishes was observed in the river that is indication of severe pollution problem.     

Identification and quantification of microcystins from a Nostoc muscorum bloom occurring in Oukaïmeden River (High-Atlas mountains of Marrakech, Morocco)

Atmospheric BTEX [benzene, toluene, ethylbenzene, o-xylene and (m + p)-xylene] concentrations have been determined in the Naples metropolitan area (NMA) and in two suburban areas located on the north within about 25 km, during 2006. The pollutants were collected by passive samplers (24-h samplings), and analysed by GC-MS. In all the areas analysed the average atmospheric benzene concentrations were higher than the limit value fixed by the European Union for 2010 and in NMA the average concentration (9.8 microg m(-3)) also exceeded the limit fixed for 2006. High linear correlation coefficients between the average daily concentrations of the different BTEX are indicative of a single major source, most likely the vehicular traffic. The temporal and spatial distribution of BTEX relative concentrations suggest that massive emissions in NMA negatively affect the quality of the air in northern suburban areas, prevalently during the hottest months of the year, probably due to transport by local seasonal winds. The ratios between BTEX daily concentrations showed a clear dependence on the intensity of solar actinic flow, indicating a major role of photochemical processes in the air cleaning from these volatile organic pollutants.     

Identification of air pollutant sampling period using horizontal dilution potential

A new model is proposed for estimating horizontal dilution potential of an area using wind data. The mean wind speed and wind direction variation are used as a measure of linear and angular spread of pollutant in the atmosphere. The methodology is applied to monitored hourly wind data for each month of 1 year for wind data collected at Vadodara, Gujarat and monthly dilution potential is estimated. It is found that there is a gradual variation of horizontal dilution potential over a year with limited dilution during post monsoon period i.e., October and November and a high dilution in pre monsoon period i.e., May and June. This information can be used to design air quality sampling network and duration of sampling for source apportionment study. Air pollutant sampling during high dilution period can be carried out for identifying urban and rural dust and wind blown dust from mining activity. Air pollutant sampling during low dilution period can be carried out for capturing large amount of particulate matter from anthropogenic sources like elevated stack of furnace.