Oil/Suspended Particulate Material Interactions and Sedimentation

The interactions of physically dispersed oil droplets with suspended particulate material (SPM) can be important for the transport of bulk quantities of spilled crude oil and polycyclic aromatic hydrocarbons (PAH) to subtidal sediments. The literature regarding oil/SPM interactions is reviewed, and results from whole-oil droplet/SPM interaction kinetics and pure-component (Prudhoe Bay crude oil distillate cut) equilibrium partitioning experiments are presented. The effects of oil type, SPM characteristics, and salinity on the interaction rates are examined, and the importance of whole-oil droplet/SPM interactions on particle agglomeration and settling behavior are discussed. Whole-oil droplet/SPM interactions are retarded as oil droplet dispersion into the water column is inhibited by oil viscosity increases due to evaporation weathering and water-in-oil emulsification. Compared to whole oil droplet/SPM interactions, dissolved-component/SPM adsorption is not as significant for transport of individual components to sediments. The information presented in this paper can be used to augment computer-based models designed to predict oil-spill trajectories, oil-weathering behavior, and spilled oil impacts to the marine environment.     

The use of enhanced bioremediation at the Savannah River Site to remediate pesticides and PCBs

Enhanced bioremediation is quickly developing into an economical and viable technology for the remediation of contaminated soils. Until recently, chlorinated organic compounds have proven difficult to bioremediate. Environmentally recalcitrant compounds, such as polychlorinated biphenyls (PCBs) and persistent organic pesticides (POPs) such as dichlorodiphenyl trichloroethane (DDT) have shown to be especially arduous to bioremediate. Recent advances in field‐scale bioremedial applications have indicated that biodegradation of these compounds may be possible. Engineers and scientists at the Savannah River Site (SRS), a major DOE installation near Aiken, South Carolina, are using enhanced bioremediation to remediate soils contaminated with pesticides (DDT and its metabolites, heptachlor epoxide, dieldrin, and endrin) and PCBs. This article reviews the ongoing remediation occurring at the Chemicals, Metals, and Pesticides (CMP) Pits using windrow turners to facilitate microbial degradation of certain pesticides and PCBs. © 2003 Wiley Periodicals, Inc.     

In situ remediation of arsenic in contaminated soils

In situ chemical fixation represents a promising and potentially cost‐effective treatment alternative for metal‐contaminated soils. This article presents the findings of the use of iron‐bearing soil amendments to reduce the leachability and bioaccessibility of arsenic in soils impacted by stack fallout from a zinc smelter. The focus of this investigation was to reduce the lead bioaccessibility of the soils through addition with phosphorus‐bearing amendments. However, as phosphorus addition was expected to increase arsenic mobility, the fixation strategy also incorporated use of iron‐bearing amendments to offset or reverse these effects. The findings of this investigation demonstrated that inclusion of iron‐bearing chemicals in the amendment formulation reduced arsenic leachability and bioaccessibility without compromising amendment effectiveness for reducing lead bioaccessibility. These results suggest that in situ chemical fixation has the potential to be an effective strategy for treatment of the impacted soils. © 2003 Wiley Periodicals, Inc.     

Local Environmental Investments and Sustainable Development: the evaluation of environmental projects in Scotland supported by the European Agriculture Guidance and Guarantee Fund

In the UK for the period 1994-99, a broad range of environmental projects were given financial support through the European Agriculture Guidance and Guarantee Fund under the Objective 1 and Objective 5b programmes. This paper is concerned with the ex-post evaluation of these projects set within a Sustainable Development framework. The aim was to identify project types or characteristics that offered the greatest return on investment. A classification of six broad project types was adopted. The evaluation revealed that there were significant differences between individual projects with respect to the type and scale, and temporal and social distribution of the benefits they delivered. In particular, as well as delivering environmental and economic benefits, many projects made a significant contribution to the development of human and social capital. The paper concludes that it is possible to improve the basis for future project selection in order to maximise the returns on environmental investments in the context of sustainable development.     

Implications of Land Use Changes on Carbon Dynamics and Sequestration—Evaluation from Forestry Datasets, India

Forests and soils are a major sink of carbon, and land use changes can affect the magnitude of above ground and below ground carbon stores and the net flux of carbon between the land and the atmosphere. Studies on methods for examining the future consequences of changes in patterns of land use change and carbon flux gains importance, as they provide different options for CO₂ mitigation strategies. In this study, a simulation approach combining Markov chain processes and carbon pools for forests and soils has been implemented to study the carbon flows over a period of time. Markov chains have been computed by converting the land use change and forestry data of India from 1997 to 1999 into a matrix of conditional probabilities reflecting the changes from one class at time t to another class time t+1. Results from Markov modeling suggested Indian forests as a potential sink for 0.94 Gt carbon, with an increase in dense forest area of about 75.93 Mha and decrease of about 3.4 Mha and 5.0 Mha in open and scrub forests, if similar land use changes that occurred during 1997–1999 would continue. The limiting probabilities suggested 34.27 percent as dense forest, 6.90 as open forest, 0.4 percent mangrove forest, 0.1 percent scrub and 58 percent as non-forest area. Although Indian forests are found to be a potential carbon sink, analysis of results from transition probabilities for different years till 2050 suggests that, the forests will continue to be a source of about 20.59 MtC to the atmosphere. The implications of these results in the context of increasing anthropogenic pressure on open and scrub forests and their contribution to carbon source from land use change and forestry sector are discussed. Some of the mitigation aspects to reduce greenhouse gas emissions from land use change and forestry sector in India are also reviewed in the study.     

The Water Poverty Index: Development and application at the community scale

The article details the development and uses of the water poverty index (WPI). The index was developed as a holistic tool to measure water stress at the household and community levels, designed to aid national decision makers, at community and central government level, as well as donor agencies, to determine priority needs for interventions in the water sector. The index combines into a single number a cluster of data directly and indirectly relevant to water stress. Subcomponents of the index include measures of: access to water; water quantity, quality and variability; water uses (domestic, food, productive purposes); capacity for water management; and environmental aspects.
The WPI methodology was developed through pilot projects in South Africa, Tanzania and Sri Lanka and involved intensive participation and consultation with all stakeholders, including water users, politicians, water sector professionals, aid agency personnel and others. The article discusses approaches for the further implementation of the water poverty index, including the possibilities of acquiring the necessary data through existing national surveys or by establishing interdisciplinary water modules in school curricula. The article argues that the WPI fills the need for a simple, open and transparent tool, one that will appeal to politicians and decision makers, and at the same time can empower poor people to participate in the better targeting of water sector interventions and development budgets in general.     

Strategies for sustainable development of the small-scale gold and diamond mining industry of Ghana

The small-scale gold and diamonds mining industry is of great importance to Ghana. Since its regularization in 1989 the sector has produced and sold over 1.5 million troy ounces of gold and 8.0 million carats of diamonds. During the same period the sector also provided direct employment to over 100,000 people and improved the socioeconomic life of many individuals and communities. However, these were largely achieved at a cost to the environment in areas where mining is carried out and there is the need to develop the industry in a sustainable manner. This paper looks at the developments in the small-scale gold and diamonds mining industry in Ghana and proposes some strategies on how the concepts of sustainable development could be applied to the industry.     

INCORPORATING NATURAL VARIABILITY,UNCERTAINTY, AND RISK INTO WATER QUALITY EVALUATIONS USING DURATION CURVES1

ABSTRACT: Quantifying natural variability, uncertainty, and risk with minimal data is one of the greatest challenges facing those engaged in water quality evaluations, such as development of total maximum daily loads (TMDL), because of regulatory, natural, and analytical constraints. Quantification of uncertainty and variability in natural systems is illustrated using duration curves (DCs), plots that illustrate the percent of time that a particular flow rate (FDC), concentration (CDC), or load rate (LDC; “TMDL”) is exceeded, and are constructed using simple derived distributions. Duration curves require different construction methods and interpretations, depending on whether there is a statistically significant correlation between concentration (C) and flow (Q), and on the sign of the C‐Q regression slope (positive or negative). Flow DCs computed from annual runoff data vary compared with an FDC developed using all data. Percent exceedance for DCs can correspond to risk; however, DCs are not composed of independent quantities. Confidence intervals of data about a regression line can be used to develop confidence limits for the CDC and LDC. An alternate expression to a fixed TMDL is suggested as the risk of a load rate being exceeded and lying between confidence limits. Averages over partial ranges of DCs are also suggested as an alternative expression of TMDLs. DCs can be used to quantify watershed response in terms of changes in exceedances, concentrations, and load rates after implementation of best management practices.     

ECOSYSTEM DYNAMICS AND POLLUTION EFFECTS IN AN OZARK CAVE STREAM1

ABSTRACT: Subterranean ecosystems harbor globally rare fauna and important water resources, but ecological processes are poorly understood and are threatened by anthropogenic stresses. Ecosystem analyses were conducted from 1997 to 2000 in Cave Springs Cave, Arkansas, situated in a region of intensive land use, to determine the degree of habitat degradation and viability of endangered fauna. Organic matter budgeting quantified energy flux and documented the dominant input as dissolved organic matter and not gray bat guano (Myotis grisescens). Carbon/nitrogen stable isotope analyses described a trophic web of Ozark cavefish (Amblyopsis rosae) that primarily consumed cave isopods (Caecidotea stiladactyla), which in turn appeared to consume benthic matter originating from a complex mixture of soil, leaf litter, and anthropogenic wastes. Septic leachate, sewage sludge, and cow manure were suspected to augment the food web and were implicated in environmental degradation. Water, sediment, and animal tissue analyses detected excess nutrients, fecal bacteria, and toxic concentrations of metals. Community assemblage may have been altered: sensitive species‐grotto salamanders (Typhlotriton spelaeus) and stygobro‐mid amphipods—were not detected, while more resilient isopods flourished. Reduction of septic and agricultural waste inputs may be necessary to restore ecosystem dynamics in this cave ecosystem to its former undisturbed condition.