A complex investigation of the extent of pollution in sediments of the Sava River: part 2: persistent organic pollutants

Sediment pollution of the biggest Danube tributary, the Sava River, was investigated within the sixth framework European Union project “Sava River Basin: Sustainable Use, Management and Protection of Resources” (SARIB). The extent of pollution was estimated by determining the amount of inorganic and persistent organic pollutants in sediment samples at 20 selected sampling sites along the Sava River. For the purpose of clarity, the findings are presented and published separately (part I: selected elements and part II: persistent organic pollutants). This study presents an investigation into the presence of organic pollutants in the Sava River sediment. According to the Water Framework Directive, the following persistent organic pollutants were investigated: polycyclic aromatic hydrocarbons (PAH), polychlorinated biphenyls (PCB), selected chlorinated pesticides and organotin compounds. The results reveal that PAHs were present in moderate concentrations (sum of 16 PAHs: up to 4,000 ng g^???1) and their concentrations increased downstream. Concen trations of PCB were low (sum of seven indicator PCBs: below 4 ng g^???1) and among the pesticides analyzed only p,p-dichlorodiphenyltrichloroethane was found in moderate concentrations at two sampling sites in Croatia (up to 3 ng g^???1) and hexachlorobenzene was found in a high concentration in the city of Belgrade (91 ng g^???1), although the use of these persistent pesticides has been banned for decades. Repeated sampling at the same location revealed point pollution near Belgrade. Among the organic pollutants surveyed, organotin compounds were not detected. Overall results reveal the presence of persistent organic pollutants in 20 of the Sava River sediments tested that is, in general, comparable or lower than the levels in the Danube River and other moderately polluted European rivers.     

Transitioning to sustainable production – Part I: application on machining technologies

This two part paper presents general issues, methods and a case study for achieving production sustainability on a machining technology level. In order to tackle these issues, the paper promotes sustainable production via the alternative machining technologies, namely cryogenic and high pressure jet assisted machining that have a high potential to cut costs and improve competitiveness by reducing resource consumption and thus creating less waste. The general issues of sustainable technologies pointed out with a comparative case study life cycle assessment performed for alternative machining processes are covered in part I of the work, concluding that future of sustainable production is going to entail the use of alternative machining technologies to reduce consumption rates, environmental burdens, and health risks simultaneously, while increasing performances and profitability. As an upgrade to this part, overall cost evaluation is covered by a case study in part II of this work.     

Critical evaluation of the use of the hydroxyapatite as a stabilizing agent to reduce the mobility of Zn and Ni in sewage sludge amended soils

The leachability of zinc (Zn) and nickel (Ni) was investigated in various soil types amended with sewage sludge and sewage sludge treated with hydroxyapatite. Sandy, clay and peat soils were investigated. For leachability tests, plastic columns (diameter 9 cm, height 50 cm) were filled with moist samples up to a height of 25 cm. Sewage sludge (1 kg) was mixed with 4.6 kg of clay and sandy soils and with 6.7 kg of peat soil. For sewage sludge mixtures treated with hydroxyapatite, 0.5 kg of the hydroxyapatite was added to 1 kg of the sewage sludge. Neutral (pH 7) and acid precipitation (pH 3.5) were applied. Acid precipitation was prepared from concentrated HNO(3), H(2)SO(4) and fresh doubly distilled water. The amount of precipitation corresponded to the average annual precipitation for the city of Ljubljana, Slovenia. It was divided into eight equal portions and applied sequentially on the top of the columns. The results indicated that the leachabilities of Zn in sewage sludge amended peat and clay soils were low (below 0.3% of total Zn content) and of Ni in sewage sludge amended sandy, clay and peat soil below 1.9% of total Ni content. In sewage sludge amended sandy soil, the leachability of Zn was higher (11% of Zn content). The pH of precipitation had no influence on the leachability of either metal. Treatment of sewage sludge with hydroxyapatite efficiently reduced the leachability of Zn in sewage sludge amended sandy soil (from 11% to 0.2% of total Zn content). In clay and peat sewage sludge amended soils, soil characteristics rather than hydroxyapatite treatment dominate Zn mobility.     

Transitioning to sustainable production – part II: evaluation of sustainable machining technologies

This paper presents a case-study that highlights the importance of sustainable machining technologies in achieving sustainable development objectives. A technology evaluation was undertaken to understand the likely impacts of the use of technology on sustainability performance measures. The evaluation is more than an experimental method for supporting the design of technology and an instrument for supporting decision-making. It is also a tool for supporting technology policy and for encouraging its adoption and application in industry. More specifically, a sustainability evaluation of cryogenic and high pressure jet-assisted machining in comparison to conventional machining is examined. Sustainability performance measures refer to environmental impact, energy consumption, safety, personal health, waste management, and cost. The case-study refers to the machining of high-temperature Ni-alloy (Inconel 718). It is shown that tooling costs represent the major contribution to the overall production cost, which contradicts previous analyses, and that sustainable machining alternatives offer a cost-effective route to improving economic, environmental, and social performance in comparison to conventional machining.     

Effect of soil management systems on erosion and nutrition loss in vineyards on steep slopes

Green cover in vineyards on steep slopes may play an important role in the reduction of soil erosion. The main objective of this study was to investigate the effect of a permanent green cover (PGC) on soil erosion, together with any loss of nutrients, and to compare it with periodic soil tillage (PST). PST took place in the spring (May) and summer (August), in each second area between rows, in a vineyard with permanent green cover. In the case of PST experimental treatments, on average, 1892 kg of soil ha-1 yr-1 eroded, together with the nutrients. In the case of PGC treatments, the amountof soil erosion was only 92 kg ha-1 yr-1. The greater portion of erosive events occurred after tillage in summer, which was accompanied by heavy rainfall and slow renewal of grass cover (slower than in spring). PGC treatment provided a better environment for the activities of soil macro-organisms (i.e., earthworms belonging to the family Lumbricidae), and mostof the organisms were close to the soil surface. In PST treatment, the majority of macro-organisms were below the area disturbed by the tillage (between 10 and 20 cm). The results of our investigation indicate that, in order to adjust wine production activities to climatic changes in vineyards with permanent green cover, PST in area between rows is more advisable in spring (end of May) than in summer (first decade of August) owing to an earlier establishment of effective grass cover.     

Environmental impacts of asphalt mixes with electric arc furnace steel slag

Electric arc furnace (EAF) steel slag can be used as an alternative high-quality material in road construction. Although asphalts with slag aggregates have been recognized as environmentally acceptable, there is a lack of data concerning the potential leaching of toxic Cr(VI) due to the highly alkaline media of EAF slag. Leaching of selected water extractable metals from slag indicated elevated concentrations of total chromium and Cr(VI). To estimate the environmental impacts of asphalt mixes with slag, leachability tests based on diffusion were performed using pure water and salt water as leaching agents. Compact and ground asphalt composites with natural aggregates, and asphalt composites in which the natural aggregates were completely replaced by slag were prepared. The concentrations of total chromium and Cr(VI) were determined in leachates over a time period of 6 mo. After 1 and 6 mo, the concentrations of some other metals were also determined in the leachates. The results indicated that chromium in leachates from asphalt composites with the addition of slag was present almost solely in its hexavalent form. However, the concentrations were very low (below 25 μg L) and did not represent an environmental burden. The leaching of other metals from asphalt composites with the addition of slag was negligible. Therefore, the investigated EAF slag can be considered as environmentally safe substitute for natural aggregates in asphalt mixes.