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191.
Since 2007, the ecosystem of the Gulf of Lions has shifted to a different regime, characterised by a low anchovy (Engraulis encrasicolus) and sardine (Sardina pilchardus) biomass and a remarkably high sprat (Sprattus sprattus) biomass. Surprisingly, the abundance and recruitment of anchovy and sardine remained high. To understand which processes (bottom-up or top-down control, etc.) could have caused this shift, we studied the changes in body condition, growth and size and age of anchovy, sardine and sprat over 1984–1985 and 1992–2012, using data from scientific surveys. The annual age structure of anchovy and sardine was estimated using Bayesian mixture models based on size frequency data with priors on the age–length relationship derived from independent otolith readings. The results indicated periods during which anchovy and sardine were in an average (1992–2004), good (2005–2007) or poor (2008–2012) overall state of condition. For sardine, the shift towards smaller fish observed during these past 4 years was explained by a combination of slower growth and the disappearance of older individuals (ages 2+). Despite the increase in biomass of sprat since 2008, indications were found that sprat was also smaller than in the past. As growth and condition decreased and overexploitation has not been documented or suspected for those three species in this area, we propose that the current decline in sardine and anchovy biomass could be due to qualitative and/or quantitative modifications in the planktonic production (i.e. a bottom-up control) or mass mortalities of adults due to an epidemic disease.  相似文献   
192.
The feeding habits of pelagic, juvenile rockfishes (Sebastes spp.) collected off Oregon in 2002, and Oregon and Washington in 2006, were examined using stomach content and stable isotope analyses. Sampling occurred along a series of transects across the shelf between Crescent City, California (Lat. 41°54.0′), and Newport, Oregon (Lat. 44°39.0′), in 2002, and off Willapa Bay, Washington (Lat. 46°40.0′), and the Columbia River, Oregon (Lat. 46°10.0′), in 2006. Species composition varied both years with distance from shore, but the predominant species were darkblotched (Sebastes crameri), canary (S. pinniger), yellowtail (2006 only; S. flavidus), and widow (S. entomelas) rockfishes. Stomach content analysis revealed that darkblotched rockfish had highly variable diets, and canary, yellowtail, and widow rockfishes exhibited a high degree of overlap in 2006. Multivariate analysis showed significant differences in diet based on distance from shore where caught, fish size, and species. Stable isotope analysis indicated that all species were feeding at about the same trophic level within each year, with a 1.5 ‰ difference in δ15N between years and regions. The difference in δ15N values may indicate a greater contribution of mesotrophic zooplankton such as euphausiids, hyperiid amphipods, and chaetognaths to fish diets in 2006. Depleted 13C values were indicative of diets based on primary production from a more offshore origin, suggesting that these rockfish had previously inhabited offshore waters. These results add to our understanding of some of the important environmental factors that affect young-of-the-year rockfishes during their pelagic phase.  相似文献   
193.
The results of a study of photocatalytic degradation of phenol using aqueous oxygenated TiO2 (anatase) suspensions in a batch Pyrex photoreactor are reported. The influence on the photodegradation rate of various parameters as pH, phenol and TiO2 content, oxygen partial pressure, anions present in the dispersions was investigated. A complete oxidation of phenol was observed. Intermediate compounds, catechol and quinone, were detected. It was observed that the photodegradation also proceeded with sunlight radiation. A mechanistic and kinetic model, which accounts for the results obtained, is given. Likely reasons for inactivity of the rutile modification for this reaction are also given.  相似文献   
194.
A method for the preparation of single crystals of PCB 35 suitable for single crystal X‐ray structure determination was developed. This method has already been proven suitable for 2,4'‐dichlorobiphenyl and may prove useful for other PCBs or related compounds. The crystals of PCB 35 are orthorhombic, spacegroup P21221 (a= 10.665(8), 6 = 3.825(3), c= 14.086(9) Å) and the structure was refined to R = 0.094 for 156 unique observed reflections and 43 parameters. Although the crystals were of poor quality, the structure determination unequivocally confirmed the substitution pattern of the biphenyl moiety by Cl atoms inferred previously from spectroscopic methods. The dihedral angle between the planes of the two phenyl rings is 33(2)°.  相似文献   
195.
Leaching of granular solids can be described in terms of specific mass transfer functions of a simple mathematical form.

The parameters can be determined by column leaching experiments under well known flow conditions.

Initially available concentrations are obtained from batch experiments at high dilution. Total concentrations in the solids are determined independently to calculate the available fractions.

The determination of the flow pattern is done by radiotracer measurements. Leachates are analyzed by various analytical methods including AAS and INAA. Total concentrations in the solids are determined by INAA preferably.  相似文献   
196.
The relationship between human resilience and environmental degradation was studied in the Sahel. The strongest predictors of human resilience were rate of environmental degradation, avoidance, problem solving and locus of control. Compared to pastoralists, agriculturalists were more stressed and marginalized. Women in all groups scored higher on marginalization and stress than men.  相似文献   
197.
Erionite, a mineral series within the zeolite group, is classified as a Group 1 known respiratory carcinogen. This designation resulted from extremely high incidences of mesothelioma discovered in three small villages from the Cappadocia region of Turkey, where the disease was linked to environmental exposures to fibrous forms of erionite. Natural deposits of erionite, including fibrous forms, have been identified in the past in the western United States. Until recently, these occurrences have generally been overlooked as a potential hazard. In the last several years, concerns have emerged regarding the potential for environmental and occupational exposures to erionite in the United States, such as erionite-bearing gravels in western North Dakota mined and used to surface unpaved roads. As a result, there has been much interest in identifying locations and geologic environments across the United States where erionite occurs naturally. A 1996 U.S. Geological Survey report describing erionite occurrences in the United States has been widely cited as a compilation of all US erionite deposits; however, this compilation only focused on one of several geologic environments in which erionite can form. Also, new occurrences of erionite have been identified in recent years. Using a detailed literature survey, this paper updates and expands the erionite occurrences database, provided in a supplemental file (US_erionite.xls). Epidemiology, public health, and natural hazard studies can incorporate this information on known erionite occurrences and their characteristics. By recognizing that only specific geologic settings and formations are hosts to erionite, this knowledge can be used in developing management plans designed to protect the public.  相似文献   
198.
A site- and receptor-specific risk management strategy for groundwater pollution based on the measurement of contaminant mass flux is proposed. The approach is useful and compatible with the demands formulated in the European Water Framework Directive, its Groundwater Daughter Directive and the regulations applicable in the EU member states. The proposed CMF method focuses on the following: (1) capture zones, (2) the location of control planes, (3) the definition of the maximum allowed contaminant mass discharge and (4) contaminant mass flux measurements. For every control plane, such a maximum allowed contaminant mass discharge is derived and is crucial for the receptor risk management strategy. The method is demonstrated for a large area of groundwater pollution present in the industrial area of Vilvoorde–Machelen located in Flanders, Belgium.  相似文献   
199.
Trait-based community assembly theory suggests that trait variation among co-occurring species is shaped by two main processes: abiotic filtering, important in stressful environments and promoting similarity, and competition, more important in productive environments and promoting dissimilarity. Previous studies have indeed found trait similarity to decline along productivity gradients. However, these studies have always been done on single trophic levels. Here, we investigated how interactions between trophic levels affect trait similarity patterns along environmental gradients. We propose three hypotheses for the main drivers of trait similarity patterns of plants and herbivores along environmental gradients: (1) environmental control of both, (2) bottom-up control of herbivore trait variation, and (3) top-down control of grass trait variation. To test this, we collected data on the community composition and trait variation of grasses (41 species) and grasshoppers (53 species) in 50 plots in a South African savanna. Structural equation models were used to investigate how the range and spacing of within-community functional trait values of both grasses and their insect herbivores (grasshoppers; Acrididae) respond to (1) rainfall and fire frequency gradients and (2) the trait similarity patterns of the other trophic level. The analyses revealed that traits of co-occurring grasses became more similar toward lower rainfall and higher fire frequency (environmental control), while showing little evidence for top-down control. Grasshopper trait range patterns, on the other hand, were mostly directly driven by vegetation structure and grass trait range patterns (bottom-up control), while environmental factors had mostly indirect effects via plant traits. Our study shows the potential to expand trait-based community assembly theory to include trophic interactions.  相似文献   
200.
The field of disaster risk reduction (DRR) has risen to prominence since the declaration of the International Decade of Disaster Risk Reduction between 1990 and 2000. This decade provided the impetus for a change from the predominant paradigm of disaster response to that of disaster risk reduction as a means of addressing the underlying drivers that lead to disasters. In an effort to promote risk reduction, the UNISDR (the principal agency for disaster risk reduction within the UN structure) formulated policies and strategies to provide both conceptual and practical guidance as to how risk should be reduced. However noble the efforts, this paper contends that the current approach to and understanding of risk within the international community might not be cognisant of complex adaptive systems (CAS) concepts such as the edge of chaos. Specifically, this concept argues that risk (or chaos) within a system is actually a fundamental requirement to the functioning of all resilient socio-ecological systems. Therefore, the reduction of risk without an understanding of the role of that risk within the larger socio-ecological system might actually end up reducing the system’s overall level of disaster resilience. This paper aims to explore the concept of edge of chaos through a literature review of key theoretical works on the topic, followed by a discussion on its implications for the predominant paradigm of risk reduction within disaster risk management policy and practice.  相似文献   
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