A multi-stage sampling strategy for the delineation of soil pollution in a contaminated brownfield

A multi-stage sampling strategy, based on sequential Gaussian simulation, was presented to optimize the step-wise selection of a small numbers of additional samples to delineate soil pollution. This strategy was applied to a Belgian brownfield of 5.2 ha polluted with lead (Pb). Starting from an initial number of 240 samples in stage 1, additional samples were added, 25 per stage, and the reduction of the uncertainty in the Pb delineation was monitored. Twenty stages were used. Already in stage 6 a local optimum was found based on the median conditional coefficient of variation. An independent validation confirmed that this index was to be preferred over the median conditional variance. So for the brownfield considered our procedure indicated that 365 selected samples would have been sufficient, representing a gain of 70.7% in sampling effort compared to current practice which resulted in a sampling effort of 1245 samples.     

Reduced nitrogen has a greater effect than oxidised nitrogen on dry heathland vegetation

We investigated the effects of different ratios of reduced (NH4+) versus oxidised (NO3(-)) nitrogen in deposition on heathland and species-rich grassland vegetation at high nitrogen deposition levels in large mesocosms filled with nutrient-poor soils to which different NH4+/NO3(-) ratios were applied. The response of the forbs, Antennaria dioica, Arnica montana, Gentiana pneumonanthe, Thymus serpyllum, the grasses Danthonia decumbens, Deschampsia flexuosa, Nardus stricta and the shrub Calluna vulgaris was recorded. The forb A. dioica and the grass D.decumbens preferred low NH4+/NO3(-) ratios and were characterised by a negative correlation between NH4+/NO3(-) ratios and biomass and survival, whereas the grasses N. stricta and D. flexuosa showed no correlation with NH4+/NO3(-) ratios. Lime addition eliminated the negative effects of high NH4+ concentrations in deposition for A. dioica and the grass D. decumbens. The implications of these findings for heathland vegetations are discussed.     

Stress responses of Calluna vulgaris to reduced and oxidised N applied under 'real world conditions'

Effects and implications of reduced and oxidised N, applied under 'real world' conditions, since May 2002, are reported for Calluna growing on an ombrotrophic bog. Ammonia has been released from a 10 m line source generating monthly concentrations of 180-6 microg m(-3), while ammonium chloride and sodium nitrate are applied in rainwater at nitrate and ammonium concentrations below 4mM and providing up to 56 kg N ha(-1) year(-1) above a background deposition of 10 kg N ha(-1) year(-1). Ammonia concentrations, >8 microg m(-3) have significantly enhanced foliar N concentrations, increased sensitivity to drought, frost and winter desiccation, spring frost damage and increased the incidence of pathogen outbreaks. The mature Calluna bushes nearest the NH3 source have turned bleached and moribund. By comparison the Calluna receiving reduced and oxidised N in rain has shown no significant visible or stress related effects with no significant increase in N status.     

Organizational diversity,integration and performance

This research examines how integrative methods of open communications, involvement, and conflict resolution in implementing an organizational change initiative moderate the relationship between cognitive diversity among employees and organization performance. In this longitudinal study of 37 medical clinics, we find that the interaction of integrative methods and diversity of models for organizing among employees has a significant positive effect on clinic revenue, productivity, and patient satisfaction. An important practical implication of these findings is that instead of seeking consensus on a singular vision of a strategic change initiative, managers are more likely to improve organization performance by focusing their interventions on creating integrative methods for encouraging and learning from diverse and opposing views of an organizational change initiative. Copyright © 2007 John Wiley & Sons, Ltd.     

Improved interpretation of in-diffusion measurements with confined swelling clays

Diffusion is considered the principal transport mechanism of radio-nuclides and other low-molecular-weight pollutants in compacted clays used as barriers at various disposal and storage sites, for example, at projected deep repositories for radioactive waste. Porous filters are routinely used to confine swelling clays in diffusion studies of radio-tracers. The presence of the filter gives rise to considerable mass-transfer limitations at the clay boundary that result in erroneous diffusion parameters. We have solved the problem of in-diffusion with due account for this phenomenon by means of Fourier transforms. By using literature data on the in-diffusion of traces of radioactive cesium in an argillaceous rock (Opalinus clay) and a compacted bentonite (FEBEX bentonite), we have demonstrated that taking into account the mass-transfer limitations considerably improves the quality of the theoretical fit of the time evolution of radio-tracer concentration in the reservoir. Besides that, we have shown that ignoring the mass-transfer limitations leads to a noticeable underestimation of both the effective diffusion coefficient and the specific sorption capacity of the clay.     

Penguin colonies as secondary sources of contamination with persistent organic pollutants

Although long-range atmospheric transport has been described as the predominant mechanism for exposing polar regions to persistent organic pollutants (POPs), recent studies have suggested that bird activity can also contribute substantially to contaminant levels in some environments. However, because the species so far reported have all been migratory, it has not been demonstrated conclusively whether locally elevated contamination represents transport from lower latitudes by the migrating birds or, alternatively, redistribution and concentration of contaminants that were already present in the high-latitude environments. The present study demonstrates, for the first time, that several POPs are present in elevated concentrations in an environment frequented by a non-migratory species (Adélie penguins) that spends its entire life in the Antarctic. Levels of POPs, such as p,p'-DDE, hexachlorobenzene (HCB), chlordanes (CHLs) and polychlorinated biphenyls (PCBs), were 10 to 100-fold higher in soil samples from penguin colonies than from reference areas. This significant difference is likely related to local penguin activity, such as a higher abundance of guano and the presence of bird carcasses. This hypothesis is also supported by a higher percentage of persistent congeners (PCB 99, 118, 138 and 153) in the soil from the colonies compared to the reference areas. This profile of PCB congeners closely matched profiles seen in penguin eggs or penguin blood.     

Geomechanical analysis of the Naylor Field,Otway Basin,Australia: Implications for CO2 injection and storage

A geomechanical assessment of the Naylor Field, Otway Basin, Australia has been undertaken to investigate the possible geomechanical effects of CO₂ injection and storage. The study aims to evaluate the geomechanical behaviour of the caprock/reservoir system and to estimate the risk of fault reactivation. The stress regime in the onshore Victorian Otway Basin is inferred to be strike–slip if the maximum horizontal stress is calculated using frictional limits and DITF (drilling induced tensile fracture) occurrence, or normal if maximum horizontal stress is based on analysis of dipole sonic log data. The NW–SE maximum horizontal stress orientation (142°N) determined from a resistivity image log is broadly consistent with previous estimates and confirms a NW–SE maximum horizontal stress orientation for the Otway Basin.An analytical geomechanical solution is used to describe stress changes in the subsurface of the Naylor Field. The computed reservoir stress path for the Naylor Field is then incorporated into fault reactivation analysis to estimate the minimum pore pressure increase required to cause fault reactivation (ΔP_p).The highest reactivation propensity (for critically-oriented faults) ranges from an estimated pore pressure increase (ΔP_p) of 1 MPa to 15.7 MPa (estimated pore pressure of 18.5–33.2 MPa) depending on assumptions made about maximum horizontal stress magnitude, fault strength, reservoir stress path and Biot's coefficient. The critical pore pressure changes for known faults at Naylor Field range from an estimated pore pressure increase (ΔP_p) of 2 MPa to 17 MPa (estimated pore pressure of 19.5–34.5 MPa).     

Pashmina production and socio‐economic changes in the Indian Changthang: Implications for natural resource management

A unique pastoral community uses the arid rangelands of eastern Ladakh, known as Changthang, northern India. The nomadic people rear a variety of livestock such as sheep, goats, horses and yaks, which provide them with various goods and services. Nevertheless, the needs and aspirations of the people are changing. There is a trend towards increasing the livestock population, especially of a breed of goat that produces one of the finest natural fibres: Pashmina, which is the mainstay of their economy. This increase in goat population, however, is jeopardising the long‐term survival of the wild herbivores in the region, and as such is not sustainable. We present information on the current trends in socio‐economy, Pashmina production, wildlife conservation, and the conflicts of interest between wildlife and nomads in the region. On the basis of this information, we make suggestions for the conservation of natural resources in the region. We recommend preserving the historical societal norms and notions of the people, and capitalising on them to manage natural resources. We also recommend joint management of natural resources by the local people, State and non‐governmental organisations. Our findings provide a platform on which a grazing policy for the region may be formulated.     

Citizens’ Views on Farm Animal Welfare and Related Information Provision: Exploratory Insights from Flanders,Belgium

The results of two independent empirical studies with Flemish citizens were combined to address the problem of a short fall of information provision about higher welfare products. The research objectives were (1) to improve our understanding of how citizens conceptualize farm animal welfare, (2) to analyze the variety in the claimed personal relevance of animal welfare in the food purchasing decision process, and (3) to find out people’s needs in relation to product information about animal welfare and the extent to which the current information caters to these needs. The first study consisted of a survey conducted in three consecutive years (2000–2002, n = 521) and was complemented with more recent qualitative data from four focus group discussions (2006, n = 29). Citizens’ conceptualization of farm animal welfare matched reasonably well with those in the scientific literature, although it is clearly influenced by a lower level of practical experience and a higher weight of empathy. In general, respondents indicated that animal welfare was an important product attribute, although it was less important than primary product attributes such as quality, health, and safety. Moral issues, rather than a perception of higher quality, were the main influence on preferences for higher welfare products. At present, higher standards of animal welfare are mostly guaranteed within more general quality assurance schemes. Yet people’s decisions to not choose higher welfare products seems to be related to the perceptual disconnection between eating animal food products and the living producing animals. Respondents generally thought better information provision was required and the present level of provision was strongly criticized. In combination, the findings of both studies help inform the discussion about how citizens can be informed about animal welfare and the preferred content, source, and medium of such information. The paper also provides insights into citizens’ semantic interpretation of the concept of animal welfare (what wordings they use) and the range of relevance that animal welfare has for different groups that, in turn is useful in identifying which segments can be targeted. This can contribute to a more effective valorization of animal welfare as a product attribute.