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101.
Kollist-Siigur K Nielsen T Grøn C Hansen PE Helweg C Jonassen KE Jørgensen O Kirso U 《Journal of environmental quality》2001,30(2):526-537
Two different humic acids (HA) and a fulvic acid (FA) were chemically immobilized to a high performance liquid chromatography (HPLC) silica column material. The immobilization was performed by binding amino groups in HA/FA to the free aldehyde group in glutardialdehyde attached to the silica gel. The HPLC column materials were compared with a blank column material made by applying the same procedure but without immobilizing HA or FA. Also, a column was made by binding carbonyl groups in HA to amino groups attached to the silica gel. The humic substances were selected to secure appropriate variation of their structural features. The retention factors of 45 polycyclic aromatic compounds (PAC) to the four columns were determined by HPLC. The advantage of the technique is a large number of compounds can easily be studied. The binding procedure does not appear to cause a drastic selection between the HA molecules. The k' values obtained for the two Aldrich HA columns agree in general reasonably. The retention or sorption of the compounds increased with the size of the PAC and the number of lipophilic substituents, but decreased when polar substituents were present. The PAC retention was much stronger to the two HA columns than to the FA and blank column, both for hydrophobic polycyclic aromatic hydrocarbons (PAH) and the polar PAC. Other factors impacting the PAC binding may be specific interactions with HA and the ionic strength of the aqueous phase. The technique has been applied to do direct determinations of Koc. 相似文献
102.
Carmen A. Lebrón Timothy McHale Robroy Young Dale Williams Matthew G. Bogaart David W. Major Michaye L. McMaster Ian Tasker Naji Akladiss 《补救:环境净化治理成本、技术与工艺杂志》2007,17(2):5-17
An Interstate Technology and Regulatory Council (ITRC) forum was recently held that focused on six case studies in which bioremediation of dense nonaqueous‐phase liquids (DNAPLs) was performed; the objective was to demonstrate that there is credible evidence for bioremediation as a viable environmental remediation technology. The first two case studies from the forum have been previously published; this third case study involves a pilot‐scale demonstration that investigated the effects of biological activity on enhancing dissolution of an emplaced tetrachloroethene (PCE) DNAPL source. It used a controlled‐release test cell with PCE as the primary DNAPL in a porous media groundwater system. Both laboratory tests and a field‐scale pilot test demonstrated that bioaugmentation can stimulate complete dechlorination to a nontoxic end product and that the mass flux from a source zone increases when biological dehalorespiration activity is enhanced through nutrient (electron donor) addition and bioaugmentation. All project goals were met. Important achievements include demonstrating the ability to degrade a PCE DNAPL source to ethene and obtaining significant information on the impacts to the microbial populations and corresponding isotope enrichments during biodegradation of a source area. © 2007 Wiley Periodicals, Inc. 相似文献
103.
104.
Esther del Val Juan Carlos Senar Juan Garrido-Fernández Manuel Jarén Antoni Borràs Josep Cabrera Juan José Negro 《Die Naturwissenschaften》2009,96(7):797-801
Carotenoids may provide numerous health benefits and are also responsible for the integumentary coloration of many bird species.
Despite their importance, many aspects of their metabolism are still poorly known, and even basic issues such as the anatomical
sites of conversion remain controversial. Recent studies suggest that the transformation of carotenoid pigments takes place
directly in the follicles during feather growth, even though the liver has been previously recognised as a storing organ for
these pigments with a certain potential for conversion. In this context, we analysed the carotenoid profile of plasma, liver,
skin and feathers of male Common Crossbills (Loxia curvirostra). Interestingly, the derivative feather pigment 3-hydroxy-echinenone was detected in the liver and in the bloodstream (i.e.
the necessary vehicle to transport metabolites to colourful peripheral tissues). Our results demonstrate for the first time
with empirical data that the liver may act as the main site for the synthesis of integumentary carotenoids. This finding contradicts
previous assumptions and raises the question of possible inter-specific differences in the site of carotenoid conversion in
birds. 相似文献
105.
106.
Jos L. Mateos Paloma Fern ndez Del Pino Francisco J. Guti rrez Ma ero Marí a Ruiz Palomino Juan J. Colon Jos A. Lucas Garcí a Agustí n Probanza 《Chemistry and Ecology》2000,17(2):125-152
Microbial communities (phospholipid fatty acid pattern, bacterial growing strategies, eco-physiological index (EPI) and total bacteria counts, as a number of heterotrophic cuhurable bacteria), substrate-induced respiration (SIR), and nitrogen mineralization were studied in three Mediterranean soils at three different depth levels (A, B and C). Soils were experimentally treated with a final concentration of 1000 ppm of trace metals (Cu2+, Zn2+, Al3+, Fe2+, Pb2+, Ni2+, Mn2+, Cr3+ and Cd2+). Soils were stored in 571 plastic containers for one year, and watered with 1001 during this period. Leachate was recovered through a bottom tap. Samples of the three depths were studied. Soil microbial communities showed different effects to other studies presented in the literature, but carried out on non-Mediterranean soils. Dramatic differences were found between treated soils and untreated ones, but not between soils or horizons. the treated soil displayed a decrease in CFUs, SIR N-mineralization and EPI together with a dominance of r-growing strategists. the relative moles percent of several PLFAs, especially 15:0, 16: 1ω7, cy17: 0, br18:0 and 18: 1ω7 decreased because of the pollution of soils, whereas 10Me16, 18:2ω6, cy19:0, i16:0 and br17:0 showed higher values than in untreated soils. 相似文献
107.
Potentiometric mass titration (PMT) technique has been adapted to determine the pH
pzc of four vegetable wastes: grape stalks, cork, yohimbe bark and olive stones wastes used for Cu(II) removal. The pH at the
point zero charge (pH
pzc), determined by PMT, are compared with that obtained by two classical techniques: mass titration (MT) and immersion technique
(IT). PMT has been found to be an easy and appropriate technique to determine pH
pzc of the studied materials. From the results, the knowledge of sorbents pH
pzc provides information about the possible attraction and repulsion between sorbent and sorbate but in any case enables to ensure
that electrostatic force is one of the mechanisms that takes place in metal sorption. 相似文献
108.
Corals are the primary reef-building organisms, therefore it is key to understand their recruitment patterns for effective reef management. Coral recruitment rates and juvenile coral abundance were recorded in the Wakatobi National Marine Park, Indonesia, on two reefs (Sampela and Hoga) with different levels of environmental degradation (12.5 vs. 44 % coral cover with high and low sedimentation rates, respectively) to examine consistencies in recruitment patterns between years and seasons. Recruitment was measured on multiple panels at two sites on each reef (6–7 m depth) and cleared areas of natural reef. Although coral recruitment was twofold higher in 2008–2009 than in 2007–2008, and seasonal differences were identified, consistent significant differences in recruitment rates were found between the two reefs even though they are separated by only ~1.5 km. Recruitment rates and juvenile abundance were lower on the more degraded reef. These patterns are likely a consequence of differential pre- and post-settlement mortality as a result of the high sedimentation rates and degraded conditions and possibly reduced larval supply. 相似文献
109.
Nelzair A. Vianna Daniel Gonçalves Flavia Brandão Roberta P. de Barros Gilberto M. Amado Filho Rodrigo O. Meire João Paulo M. Torres Olaf Malm Argemiro D’Oliveira Júnior Leonardo R. Andrade 《Environmental science and pollution research international》2011,18(3):416-427
Purpose
The aims of this paper were to quantify the heavy metals (HM) in the air of different sites in Rio de Janeiro (RJ) and Salvador (SA) using Tillandsia usneoides (Bromeliaceae) as a biomonitor, and to study the morphology and elemental composition of the air particulate matter (PM) retained on the Tillandsia surface. 相似文献110.
Dynamic Games in the Economics and Management of Pollution 总被引:1,自引:0,他引:1
Steffen Jørgensen Guiomar Martín-Herrán Georges Zaccour 《Environmental Modeling and Assessment》2010,15(6):433-467
The paper provides a survey of the literature which utilizes dynamic state-space games to formulate and analyze intertemporal,
many decision-maker problems in the economics and management of pollution. 相似文献