Distribution of suspended particulate matter with trace element composition and apportionment of possible sources in the Raniganj coalfield,India

Ambient air monitoring for suspended particulate matter was carried over a period of one year in some coal mining areas of the Raniganj coalfield. Concentrations of seven elements in suspended particulate matter were determined. The set of data obtained was analysed to determine the sources of trace elements by factor analysis. The data could be interpreted on the basis of five factors. These factors are attributed to various sources of particulate matter by noting the dependence of factors on the elements.     

Fly-ash-induced oxidative stress and tolerance in Prosopis juliflora L. grown on different amended substrates

Field experiments were conducted to study the impact of metal accumulation on malondialdehyde (MDA), cysteine and non-protein thiol (NPSH) contents in the plants of Prosopis juliflora grown on the fly ash (FA) amended with soil, blue green algae (BGA) biofertilizer, farm yard manure, press mud and Rhizobium inoculation. The analysis of data revealed that the level of MDA, cysteine and NPSH was higher in the roots of the plant than leaves, which was found positively correlated with metal accumulation. An increase of 361.14, 64.25 and 305.62% in MDA, cysteine and NPSH contents, respectively was observed after 45 days in the roots of the plants grown in 100% FA as compared to 100% garden soil (GS). The level of MDA, cysteine and NPSH was found less in the plants grown on various amendments of FA showing ameliorating effect on the toxicity induced due to the accumulation of metals. The decrease in MDA, cysteine and NPSH contents was higher in Rhizobium-inoculated plants as compared to uninoculated plants grown on 100% FA. The results showed a high tolerance potential of the plant, which is further increased by inoculating the plant with FA-tolerant Rhizobium showing feasibility of using P. juliflora in environmental monitoring of FA landfills.     

Extractive Spectrofluorometric Determination of Quinalphos Using Fluorescein in Environmental Samples

A simple, sensitive, convenient and low cost spectrofluorometric technique for determination of quinalphos is described. Quinalphos is decomposed with sodium ethoxide. Resultant sodium diethyl thiophosphate (Na-DETP) is extracted with a cationic fluorescein as ion pair complex into 1-chloro-2-nitrobenzene. The fluorescence of the ion pair, fluorescein-DETP is measured at 530 nm after excitation at 490 nm. This technique is applicable for the determination of quinalphos in water, food grains and vegetable samples up to ng level with Amberlite XAD-4.     

Air Pollution and Heat Exposure Study in the Workplace in a Glass Manufacturing Unit in India

Air pollution in the workplace environment due to industrial operation have been found to cause serious occupational health hazard. Similarly, heat stress is still most neglected occupational hazard in the tropical and subtropical countries like India. The hot climate augments the heat exposure close to sources like furnaces. In this study an attempt is made to assess air pollution and heat exposure levels to workers in the workplace environment in glass manufacturing unit located in the State of Gujarat, India. Samples for workplace air quality were collected for SPM, SO₂, NO₂ and CO₂ at eight locations. Results of workplace air quality showed 8-hourly average concentrations of SPM: 165–9118 μg/m³, SO₂: 6–9 μg/m³ and NO₂: 5–42 μg/m³, which were below the threshold limit values of workplace environment. The level of CO₂ in workplace air of the plant was found to be in the range 827–2886 μg/m³, which was below TLV but much higher than the normal concentration for CO₂ in the air (585 mg/m³). Indoor heat exposure was studied near the furnace and at various locations in an industrial complex for glass manufacturing. The heat exposure parameters including the air temperature, the wet bulb temperature, and the globe parameters were measured. The Wet Bulb Globe Temperature (WBGT), an indicator of heat, exceeded ACGIH TLVs limits most of the time at all the locations in workplace areas. The recommended duration of work and rest have also been estimated.     

Microbial population dynamics at effluent treatment plants

The requirements for treated wastewater are becoming increasingly more stringent, and therefore the improved efficiency of biological treatment processes is indispensable at industrial effluent treatment plants (ETPs). Microorganisms such as bacteria play an important role in the natural cycling of materials and particularly in the decomposition of organic wastes. The knowledge of the interactions among these microbial populations needs to be harnessed for optimum evaluation and functioning of effluent treatment plants. Modern molecular techniques have revolutionized the methods of assessing these microbial populations. The combination of the results of these microbial assessments along with the on-site parameters at ETPs would favor an efficient treatment. In this review, the various approaches and importance of correlating the microbial population dynamics and treatment of wastewater at industrial ETPs has been elaborated.     

Aerosol Scavenging: Model Application and Sensitivity Analysis in the Indian Context

Sulfate aerosols have been found to bethe major contributors to precipitation acidity. Thus,in view of the long-term ecological repercussions theyhave on aquatic ecosystems and their acidity-potential,the present analysis focuses on a case study applicationof the layer-averaged aerosol-scavenging model (Okita et al., 1996) for predicting values of the wet scavengingcoefficient and sulfate concentrations in precipitationsamples on the basis of the information available forsome selected Indian cities. Through sensitivityanalysis (Pandey et al., 1997) the scavengingcoefficient has been found to be very strongly dependenton precipitation intensity. Comparison of modelpredictions has been done with the measured values forDelhi, Mumbai, Calcutta and Chennai in India.     

Monitoring of Seasonal Vegetables for Pesticide Residues

Market samples (60) of six seasonal vegetables were monitoredduring 1996–1997 to determine the magnitude of pesticidalcontamination. The estimation of insecticide residuesrepresenting four major chemical groups i.e. organochlorine,organophosphorous, synthetic pyrethroid and carbamate, was doneby adopting a multiresidue analytical technique employingGC-ECD and GC-NPD systems with capillary columns. The testedsamples showed 100% contamination with low but measurableamounts of residues. Among the four chemical groups, theorganophosphates were dominant followed by organochlorines,synthetic pyrethroids and carbamates. About 23% of the samplesshowed contamination with organophosphorous compounds abovetheir respective MRL values. More extensive studies coveringdifferent regions of Haryana state are suggested to get a clearidea of the magnitude of vegetable contamination with pesticideresidues.     

An integrated assessment model for cross-country pipelines

The cross-country petroleum pipelines are environmentally sensitive because they traverse through varied terrain covering crop fields, forests, rivers, populated areas, desert, hills and offshore. Any malfunction of these pipelines may cause devastating effect on the environment. Hence, the pipeline operators plan and design pipelines projects with sufficient consideration of environment and social aspects along with the technological alternatives. Traditionally, in project appraisal, optimum technical alternative is selected using financial analysis. Impact assessments (IA) are then carried out to justify the selection and subsequent statutory approval. However, the IAs often suggest alternative sites and/or alternate technology and implementation methodology, resulting in revision of entire technical and financial analysis. This study addresses the above issues by developing an integrated framework for project feasibility analysis with the application of analytic hierarchy process (AHP), a multiple attribute decision-making technique. The model considers technical analysis (TA), socioeconomic IA (SEIA) and environmental IA (EIA) in an integrated framework to select the best project from a few alternative feasible projects. Subsequent financial analysis then justifies the selection. The entire methodology has been explained here through a case application on cross-country petroleum pipeline project in India.     

Evaluation of the Industrial Source Complex short-term model in a large-scale multiple source region for different stability classes

The original Industrial Source Complex Model (ISCST, 90346) and its latest version, the ISCST2 (92090), are evaluated for the 1- and 24-hour averaging periods, using six statistical parameters. The confidence limits on two parameters were obtained using the bootstrap, jacknife, seductive, and robust resampling techniques. Evaluation is conducted in a multiple point source environment and in all the different stability categories, using a year of meteorological data, emission inventory of the Lucas County, in Toledo, Ohio, and monitoring data from two nearby stations for the year 1987. This was representative of a real time situation in which the ISCST is generally applied for regulatory work. The sensitivity analysis shows that the ISC is a poor performing model in the 1-h and 24-h averaging period, neutral and stable categories, and modifications to it are necessary in order to improve its performance. Its performance changes depending on the chosen paired values. A better relative performance is observed in the unstable category relative to the neutral and stable categories. Improved model performance may be achieved by applying modifications to the physics on which the model is based.