全文获取类型
收费全文 | 3953篇 |
免费 | 33篇 |
国内免费 | 14篇 |
专业分类
安全科学 | 87篇 |
废物处理 | 251篇 |
环保管理 | 290篇 |
综合类 | 494篇 |
基础理论 | 807篇 |
环境理论 | 7篇 |
污染及防治 | 1427篇 |
评价与监测 | 365篇 |
社会与环境 | 262篇 |
灾害及防治 | 10篇 |
出版年
2023年 | 47篇 |
2022年 | 104篇 |
2021年 | 153篇 |
2020年 | 62篇 |
2019年 | 65篇 |
2018年 | 154篇 |
2017年 | 148篇 |
2016年 | 214篇 |
2015年 | 126篇 |
2014年 | 242篇 |
2013年 | 378篇 |
2012年 | 276篇 |
2011年 | 277篇 |
2010年 | 210篇 |
2009年 | 135篇 |
2008年 | 217篇 |
2007年 | 251篇 |
2006年 | 184篇 |
2005年 | 154篇 |
2004年 | 111篇 |
2003年 | 95篇 |
2002年 | 86篇 |
2001年 | 48篇 |
2000年 | 38篇 |
1999年 | 23篇 |
1998年 | 16篇 |
1997年 | 12篇 |
1996年 | 10篇 |
1995年 | 15篇 |
1994年 | 9篇 |
1993年 | 5篇 |
1992年 | 6篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1988年 | 3篇 |
1970年 | 3篇 |
1967年 | 5篇 |
1966年 | 5篇 |
1965年 | 4篇 |
1964年 | 11篇 |
1963年 | 5篇 |
1962年 | 5篇 |
1961年 | 7篇 |
1960年 | 5篇 |
1959年 | 8篇 |
1958年 | 18篇 |
1957年 | 8篇 |
1956年 | 3篇 |
1955年 | 5篇 |
1931年 | 2篇 |
排序方式: 共有4000条查询结果,搜索用时 15 毫秒
91.
Mouna Hassine-Zaafrane Khira Sdiri-Loulizi Jérôme Kaplon Imen Ben Salem Pierre Pothier Mahjoub Aouni Katia Ambert-Balay 《Food and environmental virology》2014,6(2):125-131
Noroviruses (NoVs) are responsible for numerous cases of waterborne and foodborne gastroenteritis every year. They are released in the sewage and their detection in this environment can reflect the epidemiology of the viral strains circulating in the community. A three-year (2007–2010) survey was conducted in order to evaluate the presence of human NoVs using RT-PCR in 518 sewage samples collected at the entrance and exit of two biological sewage treatment plants located in Monastir region, Tunisia. In this study, we aimed to genetically characterize the most prevalent GI and GII NoV strains, in order to obtain a rough estimate of the efficacy of disinfection treatments and to compare the results with clinical data documented in the same area during the same period. This work confirms the wide circulation and the genetic diversity of NoVs in Tunisia and the widespread distribution of NoV variants in both raw and treated wastewater. Indeed, NoV was detected in 192 (37.1 %) sewage samples, among them mixed infections with group A rotavirus were detected in 125 (65.1 %) cases. The genotypes of the GI NoVs were GI.1, GI.2, GI.4, GI.5, and GI of unassigned genotype (GI.UA), and the genotypes of the GII NoVs were all GII.12. This study enhances the currently poor environmental virological data gathered in Tunisia, demonstrates the benefit of environmental surveillance as a tool to determine the epidemiology of NoVs circulating in a given community, and underlines the need for the design and support of similar long-term studies in our country, in order to compensate for the absence of a national surveillance system for gastroenteric viruses. 相似文献
92.
Katarzyna?Wojczulanis-JakubasEmail authorView authors OrcID profile Ma?gorzata?E.?Chrostek Frédéric?Jiguet Carlos?Zumalacárregui?Martínez David?Miguélez Júlio?M.?Neto 《Die Naturwissenschaften》2017,104(11-12):101
Differential migration has been extensively reported in spring, but less so in autumn, particularly in relation to sex in monomorphic bird species. Here, we analysed the autumn passage of a monomorphic, globally threatened passerine, the Aquatic Warbler Acrocephalus paludicola throughout Western Europe, with regard to age and sex. We showed that, overall, adults migrated earlier than first-year birds, and males migrated earlier than females during the autumn migration. This may be caused by an overall social dominance of adults over immatures, and differentiated migration strategy of males and females. In addition, we found male-skewed sex proportions, with a tendency to an equalised ratio in more southern stopover sites. This may indicate a male bias in the global population or different migration strategies of the sexes. Differential migration may cause the age and sex classes to be exposed differently to various threats affecting demographic structure of the species. 相似文献
93.
Mateos S Daza P Domínguez I Cárdenas JA Cortés F 《Environmental pollution (Barking, Essex : 1987)》2008,153(3):590-593
A field study was carried out in the south of the Iberian Peninsula in an industrial area in the neighbourhood of Huelva city, SW Spain, and in a natural area (Do?ana National Park) for comparison, to estimate the genetic risk induced by environmental pollution in wild mice. Genotoxic effects in a sentinel organism, the Algerian mice (Mus spretus) free living in the industrial area were compared with animals of the same species living in the natural protected area. The single cell gel electrophoresis, or Comet assay, was performed as a genotoxicity test in peripheral blood of mice. Our results clearly show that mice free living in the contaminated area bear a high burden of genetic damage as compared with control individuals. The results suggest that the assessing of genotoxicity levels by the Comet assay in wild mice can be used as a valuable test in pollution monitoring and environmental conservation. 相似文献
94.
Lobpreis T Vrana B Dominiak E Dercová K Mills GA Greenwood R 《Environmental pollution (Barking, Essex : 1987)》2008,153(3):706-710
Passive sampling of pollutants in water has been gaining acceptance for environmental monitoring. Previously, an integrative passive sampler (the Chemcatcher) was developed and calibrated for the measurement of time weighted average concentrations of hydrophobic pollutants in water. Effects of physicochemical properties and environmental variables (water temperature and turbulence) on kinetic and thermodynamic parameters characterising the exchange of analytes between the sampler and water have been published. In this study, the effect of modification in sampler housing geometry on these calibration parameters was studied. The results obtained for polycyclic aromatic hydrocarbons show that reducing the depth of the cavity in the sampler body geometry increased the exchange kinetics by approximately twofold, whilst having no effect on the correlation between the uptake and offload kinetics of analytes. The use of performance reference compounds thus avoids the need for extensive re-calibration when the sampler body geometry is modified. 相似文献
95.
Hernández-Moreno D Soler-Rodríguez F Míguez-Santiyán MP Pérez-López M 《Journal of environmental science and health. Part. B》2008,43(5):395-404
The effect of a long-term exposure of tenchs to different concentrations (10 and 100 micro g/L) of the pesticide carbofuran has been evaluated. Microsomal hepatic cytochrome P450 subfamily 1A (CYP1A) and 3A (CYP3A) activities, as well as the phase II enzyme uridine diphospho-glucuronosyltransferase (UDPGT) activity were evaluated as adequate biomarkers of fish exposure to environmentally relevant concentrations of the pesticide carbofuran in freshwater ecosystems. A clear time-dependent inhibition of both CYP1A and UDPGT activities was observed in fish exposed to the highest dose of carbofuran with respect to controls, whereas in the case of CYP3A activity, values of exposed animals did not show a clear pattern of alteration during the experiment. The results of the present study demonstrated that hepatic CYP1A and UDPGT activities from tench could be considered as sensitive biomarkers for carbamate pesticides in polluted water, thus allowing future and ecologically relevant biomonitoring studies with this species. 相似文献
96.
Ureña-Amate MD Socías-Viciana MM González-Pradas E Cantos-Molina A Villafranca-Sánchez M López-Teruel C 《Journal of environmental science and health. Part. B》2008,43(2):141-150
The adsorption of chloridazon (5-amine-4-chloro-2-phenylpyridazin-3(2H)-one) on kerolite samples heated at 110 degrees C (K-110), 200 degrees C (K-200), 400 degrees C (K-400), 600 degrees C (K-600) and acid-treated with H(2)SO(4) solutions of two different concentrations (0.25 and 0.5 M) (K-0.25 and K-0.5, respectively) from pure water at 25 degrees C has been studied by using batch and column experiments. The adsorption experimental data points were fitted to the Freundlich equation in order to calculate the adsorption capacities (K(f)) of the samples; K(f) values ranged from 184.7 mg kg(-1) (K-0.5) up to 2253 mg kg(-1) (K-600). This indicated that the heat treatment given to the kerolite greatly increases its adsorption capacity for the herbicide whereas the acid treatment produces a clear decrease in the amount of chloridazon adsorbed. The removal efficiency (R) was also calculated; R values ranging from 52.8% (K-0.5) up to 88.3% (K-600). Thus, the results showed that the 600 degrees C heat-treated kerolite was more effective in relation to adsorption of chloridazon and it might be reasonably used in removing this herbicide from water. 相似文献
97.
Kinetic extractions to assess mobilization of Zn, Pb, Cu, and Cd in a metal-contaminated soil: EDTA vs. citrate 总被引:4,自引:0,他引:4
Labanowski J Monna F Bermond A Cambier P Fernandez C Lamy I van Oort F 《Environmental pollution (Barking, Essex : 1987)》2008,152(3):693-701
Kinetic EDTA and citrate extractions were used to mimic metal mobilization in a soil contaminated by metallurgical fallout. Modeling of metal removal rates vs. time distinguished two metal pools: readily labile (QM1) and less labile (QM2). In citrate extractions, total extractability (QM1+QM2) of Zn and Cd was proportionally higher than for Pb and Cu. Proportions of Pb and Cu extracted with EDTA were three times higher than when using citrate. We observed similar QM1/QM2 ratios for Zn and Cu regardless of the extractant, suggesting comparable binding energies to soil constituents. However, for Pb and Cd, more heterogeneous binding energies were hypothesized to explain different kinetic extraction behaviors. Proportions of citrate-labile metals were found consistent with their short-term, in-situ mobility assessed in the studied soil, i.e., metal amount released in the soil solution or extracted by cultivated plants. Kinetic EDTA extractions were hypothesized to be more predictive for long-term metal migration with depth. 相似文献
98.
Alonso R Elvira S Sanz MJ Gerosa G Emberson LD Bermejo V Gimeno BS 《Environmental pollution (Barking, Essex : 1987)》2008,155(3):473-480
A sensitivity analysis of a proposed parameterization of the stomatal conductance (g(s)) module of the European ozone deposition model (DO(3)SE) for Quercus ilex was performed. The performance of the model was tested against measured g(s) in the field at three sites in Spain. The best fit of the model was found for those sites, or during those periods, facing no or mild stress conditions, but a worse performance was found under severe drought or temperature stress, mostly occurring at continental sites. The best performance was obtained when both f(phen) and f(SWP) were included. A local parameterization accounting for the lower temperatures recorded in winter and the higher water shortage at the continental sites resulted in a better performance of the model. The overall results indicate that two different parameterizations of the model are needed, one for marine-influenced sites and another one for continental sites. 相似文献
99.
In field arsenic removal from natural water by zero-valent iron assisted by solar radiation 总被引:1,自引:0,他引:1
Cornejo L Lienqueo H Arenas M Acarapi J Contreras D Yáñez J Mansilla HD 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):827-831
An in situ arsenic removal method applicable to highly contaminated water is presented. The method is based in the use of steel wool, lemon juice and solar radiation. The method was evaluated using water from the Camarones River, Atacama Desert in northern Chile, in which the arsenic concentration ranges between 1000 and 1300 μg L−1. Response surface method analysis was used to optimize the amount of zero-valent iron (steel wool) and the citrate concentration (lemon juice) to be used. The optimal conditions when using solar radiation to remove arsenic from natural water from the Camarones river are: 1.3 g L−1 of steel wool and one drop (ca. 0.04 mL) of lemon juice. Under these conditions, removal percentages are higher than 99.5% and the final arsenic concentration is below 10 μg L−1. This highly effective arsenic removal method is easy to use and inexpensive to implement. 相似文献
100.
Levels of perfluorochemicals in water samples from Catalonia,Spain: is drinking water a significant contribution to human exposure? 总被引:2,自引:0,他引:2
Ericson I Nadal M van Bavel B Lindström G Domingo JL 《Environmental science and pollution research international》2008,15(7):614-619
Background, aim, and scope In recent years, due to a high persistence, biomagnification in food webs, presence in remote regions, and potential toxicity,
perfluorochemicals (PFCs) have generated a considerable interest. The present study was aimed to determine the levels of perfluorooctane
sulfonate (PFOS), perfluorooctanoic acid (PFOA), and other PFCs in drinking water (tap and bottled) and river water samples
from Tarragona Province (Catalonia, Spain).
Materials and methods Municipal drinking (tap) water samples were collected from the four most populated towns in the Tarragona Province, whereas
samples of bottled waters were purchased from supermarkets. River water samples were collected from the Ebro (two samples),
Cortiella, and Francolí Rivers. After pretreatment, PFC analyses were performed by HPLC-MS. Quantification was done using
the internal standard method, with recoveries between 68% and 118%.
Results In tap water, PFOS and PFOA levels ranged between 0.39 and 0.87 ng/L (0.78 and 1.74 pmol/L) and between 0.32 and 6.28 ng/L
(0.77 and 15.2 pmol/L), respectively. PFHpA, PFHxS, and PFNA were also other detected PFCs. PFC levels were notably lower
in bottled water, where PFOS could not be detected in any sample. Moreover, PFHpA, PFHxS, PFOA, PFNA, PFOS, PFOSA, and PFDA
could be detected in the river water samples. PFOS and PFOA concentrations were between <0.24 and 5.88 ng/L (<0.48 and 11.8 pmol/L)
and between <0.22 and 24.9 ng/L (<0.53 and 60.1 pmol/L), respectively.
Discussion Assuming a human water consumption of 2 L per day, the daily intake of PFOS and PFOA by the population of the area under evaluation
was calculated (0.78–1.74 and 12.6 ng, respectively). It was found that drinking water might be a source of exposure to PFCs
as important as the dietary intake of these pollutants.
Conclusions The contribution of drinking water (tap and bottled) to the human daily intake of various PFCs has been compared for the first
time with data from dietary intake of these PFCs. It was noted that in certain cases, drinking water can be a source of exposure
to PFCs as important as the dietary intake of these pollutants although the current concentrations were similar or lower than
those reported in the literature for surface water samples from a number of regions and countries.
Recommendations and perspectives Further studies should be carried out in order to increase the knowledge of the role of drinking water in human exposure to
PFCs. 相似文献