Toxaphene chemistry: separation and characterisation of selected enantiomers of the Polychloropinene mixtures

The primary goal for the study presented here was the preparation and characterisation of enantiomeric pure chlorobornane standards (Toxaphene). In this context, we partially modeled the procedure for Polychloropinene production in the former USSR. The initial reaction was ionic addition of hydrogen chloride to (1S)-alpha-pinene resulting predominantly in (1S)-2-endo-chlorobornane. Further photochlorination gave mixtures of chlorinated terpenes with different average content of Cl per molecule. The resulting mixtures were separated on a silica-gel column and a number of known hepta to decachlorobornanes were identified in fractions with the help of NMR and GC (using electron capture and mass spectrometric detection)--but in very unusual ratios as compared to the technical Toxaphene mixture formerly produced by Hercules (USA). Also several previously unknown congeners were isolated or detected. Three of the isolated congeners were obtained in crystalline state and X-ray crystallography showed their enantiomeric purity.     

A Novel Stochastic Optimization Model for Reverse Logistics Network Design of End-of-Life Vehicles: A Case Study of Istanbul

Environmental Modeling & Assessment - Waste management is gaining crucial importance as recycling aims at transforming produced waste into value for the economy. As the automotive industry is...     

Validation of the environmental Kuznets curve hypothesis and role of carbon emission policies in the case of Russian Federation

Environmental Science and Pollution Research - Climate change currently observed and expected in the future is associated with risks to security and sustainable development and natural and...     

Seasonal peculiarities of PCDD/Fs levels in bank voles inhabiting sites in the vicinity of the landfill with municipal wastes (Moscow,Russia)

Environmental Science and Pollution Research - Differences in PCDD/Fs concentrations were registered among adult bank voles (Myodes glareolus) inhabiting forest in the vicinity of the Landfill...     

Mutagens in raw ewe milk in Orava region,northern Slovakia: metals

Environmental Science and Pollution Research - The aim of this work was to determine the concentrations of selected mutagenic elements (As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Se) in raw ewe milk...