An Ozone Event in Indianapolis

There are doubts concerning the sources of the pollutant ozone in an urban location. Current control regulations,¹ for example, are based on local sources. Many studies suggest that plumes of pollutants released by upwind areas are the cause. For example, New York City has been associated with high O₃ in New England,² Chicago with O₃ in Milwaukee,³ and St. Louis with O₃ in rural Illinois.⁴ Others^5,6 have suggested the problem must be treated on a synoptic scale. In an effort to understand the problem at Indianapolis better, a series of experiments involving aircraft flights were conducted in the Indianapolis area and their results are herein reported. Specifically, a cross country flight of over 100 mi both to the northeast and southwest of Indianapolis, a vertical spiral to 28,000 ft, low level data associated with takeoff and landing of the aircraft, and ground data at four sites, are available for the afternoon of June 9,1976.     

Fluoride Emissions and Forest Growth

Abstract

The October 1995 court decision allowing Ethyl Corporation to offer methylcyclopentadienyl manganese tricarbonyl (MMT) for sale to refiners for introduction into unleaded gasoline as an octane enhancer is likely to result in increased fine (PM_2.5) manganese (Mn) concentrations in ambient air. Concern exists regarding possible health effects. In this paper, recent fine Mn concentrations in three monitoring networks and one U.S. Environmental Protection Agency (EPA) study of personal exposure are analyzed. One network consists mainly of rural sites in national parks in the United States, a second consists mainly of urban sites in California, and the third consists mainly of urban sites in Canada where MMT has been used for a number of years. During the late 1980s and early 1990s, mean ambient concentrations ranged from 1 ng/m³ in the mostly rural network to 3 ng/m³ in the mostly urban California network to 12 ng/m³ in the MMT-impacted Canadian network. Several lines of evidence suggested that some of the fine Mn observed in the United States during the 1986-1992 period was contributed by automobiles using leaded gasoline, for which MMT was a registered fuel additive. However, the near-disappearance of leaded gasoline has resulted in a very small portion of fine Mn being attributed to automobiles in the years since 1992.A source apportionment analysis suggested that crustal contributions to ambient fine Mn are on the order of 1-2 ng/m³ in both the United States and Canada.     

An Overview of EPA’s Quality Assurance Program

Quality Assurance has been defined in many different ways to express concern for the “quality” of the output of some operation or function. For the purpose of this presentation, quality assurance is defined as the sum of those activities within an environmental monitoring or measurement program which are primarily for the purpose of documenting the precision, accuracy, representativeness, and completeness of the data that are produced. Further, we view quality assurance as a management tool which encompasses both administrative and technical functions which generally fall into three categories: (1) Prevention which includes those activities carried out prior to the proper placement and operation of the measurement system; (2) Evaluation which includes the continuous overview and checks on the performance of the systems and operators; and (3) Correction which includes changes made to improve or stabilize the capability and performance of the system.     

R&D Activities,Operating Experience Discussed at Fabric Alternatives Forum

ABSTRACT

Previously reported volatile organic compounds (VOC) radiocarbon (¹⁴C) measurements for 1992 summertime Atlanta, GA, have been compared with chromatographic data and emissions inventory predictions. The chromatographic approach that was used provided a more comprehensive VOC characterization than typically achieved, and the emissions inventory was research-grade level (date-, site-, and time-specific). The comparisons are in general agreement that biogenic emissions contribute only modestly (<10%) to the VOC content of the particular ambient samples that were collected and measured. The choices of sampling site (near city-center) and times (early morning and late evening) are major influences on the results, which consequently should not be regarded as representing the average VOC biogenic impact for the Atlanta area.     

Electrostatic Stimulation of Fabric Filtration

The concept of electrostatic stimulation of fabric filtration (ESFF) has been investigated at pilot scale. The pilot unit consisted of a conventional baghouse in parallel with an ESFF baghouse, allowing direct comparison. All results reported in this paper are for pulse-cleaned bags in which the electric field was maintained parallel to the fabric surface. The performance of the ESFF baghouse has been superior to the parallel conventional baghouse by several measures. The ESFF baghouse demonstrated: (1) a reduced rate of pressure drop increase during a filtration cycle, (2) lower residual pressure drop, (3) stable operation at higher face velocities, and (4) improved particle removal efficiency. These benefits can be obtained with only minor modifications to conventional pulse-jet hardware and at low electrical power consumption. The indicated ability to operate at increased face velocities with only modest expenditure for electrical hardware leads to very favorable economic projections.     

Filter Beds: Energy-Efficient Packing Diameter

Factors which help minimize pressure drop at a given level of collection efficiency for a bed packed with roughly spherical collectors are studied here by using the quality factor, the ratio of the single collector collection efficiency to the force per unit area on the single collector. This analysis indicates that energy-efficient designs can be obtained as follows: choose a representative particle size; if impaction predominates, design for an impaction parameter near one; if interception predominates, design for the smallest packing diameters feasible; if gravitational settling predominates, design for the largest packing diameters possible; if diffusion predominates, design for collector Reynolds numbers near 10². Some more general cases are also discussed.     

Resource Recovery from Flue Gas Desulfurization Systems

The cost effective benefits of yielding a flue gas desulfurization (FGD) sludge predominantly composed of CaSO₄·2H₂O, have been previously established. The recovery of this material as FGD by-product gypsum has been demonstrated abroad. Recently U.S. wallboard manufacturers have recognized the viability of this recovery practice. Such techno-economic decision making variables as a) by-product specification, b) transportation costs, and c) location of suitable FGD systems enable the recognition of FGD by-product recovery. Recent investigations of resultant solids content and chloride washing reflect the technical possibility of delivering a suitable product. Commercial and economic factors favor recovery based upon rising disposal and transportation costs. Existing and near term proposed systems surface the technical and commercial problems faced by utilities considering recovery.

Generation of an oxidized FGD sludge consisting of 90⁺% CaSO₄·2H₂O and dewatered to 80⁺% solids is technically achievable by air sparging within the FGD system. Although the product is suitable for land disposal, electric power utilities should consider and evaluate by-product recovery. U.S. wallboard manufacturers have established technical criteria for FGD by-product gypsum. Percent CaSO₄·2H₂O, final solids content, particle size, and chloride content are primarily technical parameters. Technology exists within the FGD industry to satisfy these criteria and results are discussed.

Economic factors comparing mining costs, transportation costs, and disposal costs are developed for specific utility projects. Such comparison established generalized financial criteria for a given utility to develop the economic reasonableness of considering FGD byproduct recovery.

End product user perspectives are presented providing electric utilities with a realistic appreciation for by-product recovery potential. Location of existing wallboard plants highlight potential recovery regions. Quality control problems are discussed in terms of generating a by-product rather than a disposable material.