The Clean Air Act Amendments and Motor Vehicle Inspection/Maintenance

Seventeen days of detailed measurements of NO, NO₂, O₃, HNO₃ and the frequency of NO₂ photolysis—j(NO₂)—were carried out in Claremont, CA, in September 1980. Under conditions when the rate of change of NO concentration is small, there must be a balance between formation and loss processes. In the classical photostationary state this balance is between NO₂ photolysis: NO₂ + hv → NO + O and reaction with ozone: NO + O₃ → NO₂ + O₂. The results show that the latter reaction with ozone is inadequate to balance the formation step; a significant contribution is required from another NO oxidation process, possibly peroxy radical oxidation. If so, the inferred concentration of peroxy radicals shows a diurnal variation, peaking around solar noon.     

Optimization of a horizontal-flow biofilm reactor for the removal of methane at low temperatures

Three pilot-scale, horizontal-flow biofilm reactors (HFBRs 1–3) were used to treat methane (CH₄)-contaminated air to assess the potential of this technology to manage emissions from agricultural activities, waste and wastewater treatment facilities, and landfills. The study was conducted over two phases (Phase 1, lasting 90 days and Phase 2, lasting 45 days). The reactors were operated at 10 °C (typical of ambient air and wastewater temperatures in northern Europe), and were simultaneously dosed with CH₄-contaminated air and a synthetic wastewater (SWW). The influent loading rates to the reactors were 8.6 g CH₄/m³/hr (4.3 g CH₄/m² TPSA/hr; where TPSA is top plan surface area). Despite the low operating temperatures, an overall average removal of 4.63 g CH₄/m³/day was observed during Phase 2. The maximum removal efficiency (RE) for the trial was 88%. Potential (maximum) rates of methane oxidation were measured and indicated that biofilm samples taken from various regions in the HFBRs had mostly equal CH₄ removal potential. In situ activity rates were dependent on which part of the reactor samples were obtained. The results indicate the potential of the HFBR, a simple and robust technology, to biologically treat CH₄ emissions.

Implications: The results of this study indicate that the HFBR technology could be effectively applied to the reduction of greenhouse gas emissions from wastewater treatment plants and agricultural facilities at lower temperatures common to northern Europe. This could reduce the carbon footprint of waste treatment and agricultural livestock facilities. Activity tests indicate that methanotrophic communities can be supported at these temperatures. Furthermore, these data can lead to improved reactor design and optimization by allowing conditions to be engineered to allow for improved removal rates, particularly at lower temperatures. The technology is simple to construct and operate, and with some optimization of the liquid phase to improve mass transfer, the HFBR represents a viable, cost-effective solution for these emissions.     

Alternatives to biodiversity offsets for mitigating the effects of urbanization on stream ecosystems

Globally, offset schemes have emerged in many statutory frameworks relating to development activities, with the aim of balancing biodiversity conservation and development. Although the theory and use of biodiversity offsets in terrestrial environments is broadly documented, little attention has been paid to offsets in stream ecosystems. Here we examine the application of offset schemes to stream ecosystems and explore whether they suffer similar shortcomings to those of offset schemes focused on terrestrial biodiversity. To challenge the applicability of offsets further, we discuss typical trajectories of urban expansion and their cascading physical, chemical and biological impacts on stream ecosystems. We argue that the highly connected nature of stream ecosystems and urban drainage networks can transfer impacts of urbanization across wide areas, complicating the notion of like‐for‐like exchange and the prospect of effectively mitigating biodiversity loss. Instead, we identify in‐catchment options for stormwater control, which can avoid or minimize the impacts of development on downstream ecosystems, while presenting additional public and private benefits. We describe the underlying principles of these alternatives, some of the challenges associated with their uptake, and policy initiatives being trialed to facilitate adoption. In conclusion, we argue that stronger policies to avoid and minimize the impacts of urbanization provide better prospects for protecting downstream ecosystems, and can additionally, stimulate economic opportunities and improve urban liveability.     

Synoptic evaluation of regional PM2.5 concentrations

By comparing short-term fluctuations in PM2.5 species concentrations among nearby air quality monitors and among species, it becomes possible to understand the regional and local events leading to higher concentrations. This approach was applied at thirteen sites in the Maryland area for the 2001–2006 timeframe in order to identify and explain the behavior of eighteen different analytes as well as the daily Air Quality Index.Findings included identification of local upwind events such as fireworks displays, construction and demolition, the spatial extent of sulfate, nitrate, and ammonium correlations between ground-level monitors, correlations between some crustal species to indicate similar emissions sources in urban areas, and indicators of particle adsorption as a rate-limiting step for certain species. For example, the bromine behavior suggests that bromine concentrations on particulate matter may be limited by the particle adsorption rate and thus show a dependence on the Air Quality Index measurements.     

Oil spill response capabilities and technologies for ice-covered Arctic marine waters: A review of recent developments and established practices

Renewed political and commercial interest in the resources of the Arctic, the reduction in the extent and thickness of sea ice, and the recent failings that led to the Deepwater Horizon oil spill, have prompted industry and its regulatory agencies, governments, local communities and NGOs to look at all aspects of Arctic oil spill countermeasures with fresh eyes. This paper provides an overview of present oil spill response capabilities and technologies for ice-covered waters, as well as under potential future conditions driven by a changing climate. Though not an exhaustive review, we provide the key research results for oil spill response from knowledge accumulated over many decades, including significant review papers that have been prepared as well as results from recent laboratory tests, field programmes and modelling work. The three main areas covered by the review are as follows: oil weathering and modelling; oil detection and monitoring; and oil spill response techniques.     

Summer Transport Patterns Affecting the Mohave Power Project Emissions

The Mohave Power Project (MPP) is an isolated 1580-MW coal-fired electric generating plant located in Laughlin, NV. Laughlin is a small desert gambling town situated in the lower Colorado River Valley near the junction of three states: Nevada, California, and Arizona. The location of the MPP is approximately 115 km southwest of the western end of the Grand Canyon National Park and about 240 km southwest from the Grand Canyon Village. This paper describes the summer transport patterns of the MPP emittants using illustrated examples from the Project MOHAVE (Measurements of Haze and Visual Effects) 1992 summer intensive study. The intensive study lasted 50 days from mid-July through August and encompassed the major meteorological patterns associated with southwestern U.S. summer meteorology. The MPP emittants were transported toward the Grand Canyon (north to the northeast) during more than 80% of the total hours. Airflow was from the south most of the time due to a combination of the semi-permanent thermal low, differential heating between the Gulf of California and lower Colorado River Valley, and upslope heating of the southern and western slopes of the nearby Colorado Plateau.     

Quantifying changes to historic fish habitat extent on north coast NSW floodplains,Australia

Global degradation of coastal ecosystems is influencing the provision of ecosystem services, including fisheries maintenance services. Degradation of the Australian coastal zone and its resources following European occupation has been recognised for some time. This includes the loss of ecologically important coastal wetlands, which have strong trophic and habitat links to fisheries. In NSW, structural flood mitigation works are a principle driver of the decline of coastal wetlands; however, little action has been taken to quantify the extent of decline due to limited information of the pre-European settlement extent of coastal wetlands. We use spatial data sets in GIS to quantify prime fish habitat and calculate the loss of fish habitat for the large coastal floodplains of northern NSW, which are significant contributors to the commercial and recreational fisheries of NSW. The technique is validated by comparison with early maps of wetland distribution. We identified pre-European distribution of available fish habitat of approximately 477,000 ha, of which 87,000 ha was identified as prime fish habitat. Approximately 62,000 ha of prime fish habitat was impacted by drainage of the coastal floodplains in association with flood mitigation works which intensified in the mid-1950s and were largely completed by 1971, equating to a loss of approximately 72 % of prime fish habitat. The declining value of the ecosystem services provided by prime fish habitat following drainage is likely to be substantial. Some actions have taken place to restore the functions of this habitat although significant opportunities remain to reverse this decline through management actions that restore natural drainage and reinstate tidal exchange. These actions become even more important as pressures on coastal wetlands increase with climate change and associated sea-level rise.     

Identification of fungal proteases potentially suitable for environmentally friendly cleaning-in-place in the dairy industry

Fourteen fungi were screened for ability to produce proteases with activity on milk protein. The proteases produced were assessed on a lab-scale in terms of their potential suitability for cleaning-in-place (CIP) in the dairy industry. Cleaning performance was assessed by determining the ability of the enzymes to remove an industrial-like milk fouling deposit from stainless steel. Based on the results observed, the extracellular protease activity produced by Schizophyllum commune was selected as most suitable for potential CIP application. A CIP procedure involving a sodium carbonate rinse followed by enzymatic cleaning with this fungal enzyme activity was developed. Satisfactory cleaning, judged by quantification of residual organic matter and protein on the stainless steel surface after cleaning, was achieved using the developed CIP procedure at 40 °C. This CIP procedure, based on biodegradable enzymes working at low temperature is more environmentally favourable than conventional CIP methods using caustic based cleaning solutions at 70-80 °C. Potential environmental benefits of the developed enzymatic CIP procedure include reduced energy consumption, decreased chemical usage and a reduced requirement for pH neutralisation of the resultant waste prior to release.     

Impediments and Solutions to Sustainable,Watershed-Scale Urban Stormwater Management: Lessons from Australia and the United States

In urban and suburban areas, stormwater runoff is a primary stressor on surface waters. Conventional urban stormwater drainage systems often route runoff directly to streams and rivers, thus exacerbating pollutant inputs and hydrologic disturbance, and resulting in the degradation of ecosystem structure and function. Decentralized stormwater management tools, such as low impact development (LID) or water sensitive urban design (WSUD), may offer a more sustainable solution to stormwater management if implemented at a watershed scale. These tools are designed to pond, infiltrate, and harvest water at the source, encouraging evaporation, evapotranspiration, groundwater recharge, and re-use of stormwater. While there are numerous demonstrations of WSUD practices, there are few examples of widespread implementation at a watershed scale with the explicit objective of protecting or restoring a receiving stream. This article identifies seven major impediments to sustainable urban stormwater management: (1) uncertainties in performance and cost, (2) insufficient engineering standards and guidelines, (3) fragmented responsibilities, (4) lack of institutional capacity, (5) lack of legislative mandate, (6) lack of funding and effective market incentives, and (7) resistance to change. By comparing experiences from Australia and the United States, two developed countries with existing conventional stormwater infrastructure and escalating stream ecosystem degradation, we highlight challenges facing sustainable urban stormwater management and offer several examples of successful, regional WSUD implementation. We conclude by identifying solutions to each of the seven impediments that, when employed separately or in combination, should encourage widespread implementation of WSUD with watershed-based goals to protect human health and safety, and stream ecosystems.     

Reproductive health indicators of fishes from Pennsylvania watersheds: association with chemicals of emerging concern

Fishes were collected at 16 sites within the three major river drainages (Delaware, Susquehanna, and Ohio) of Pennsylvania. Three species were evaluated for biomarkers of estrogenic/antiandrogenic exposure, including plasma vitellogenin and testicular oocytes in male fishes. Smallmouth bass Micropterus dolomieu, white sucker Catostomus commersonii, and redhorse sucker Moxostoma species were collected in the summer, a period of low flow and low reproductive activity. Smallmouth bass were the only species in which testicular oocytes were observed; however, measurable concentrations of plasma vitellogenin were found in male bass and white sucker. The percentage of male bass with testicular oocytes ranged from 10 to 100 %, with the highest prevalence and severity in bass collected in the Susquehanna drainage. The percentage of males with plasma vitellogenin ranged from 0 to 100 % in both bass and sucker. Biological findings were compared with chemical analyses of discrete water samples collected at the time of fish collections. Estrone concentrations correlated with testicular oocytes prevalence and severity and with the percentage of male bass with vitellogenin. No correlations were noted with the percentage of male sucker with vitellogenin and water chemical concentrations. The prevalence and severity of testicular oocytes in bass also correlated with the percent of agricultural land use in the watershed above a site. Two sites within the Susquehanna drainage and one in the Delaware were immediately downstream of wastewater treatment plants to compare results with upstream fish. The percentage of male bass with testicular oocytes was not consistently higher downstream; however, severity did tend to increase downstream.