Natural and man-made organobromine compounds in marine biota from Central Norway

Brominated organic pollutants were found in selected samples of mollusk tissue, fish liver, as well as in the eggs and livers of shag from three sites in Central Norway. More than 80 organobromines were identified owing to the defined isotope ratio acquired by GC/ECNI-MS. However, only a few peaks could be assigned to anthropogenic brominated flame retardants (polybrominated diphenyl ethers). Most of the organobromine compounds detected were unknown or halogenated natural products. The known halogenated natural products MHC-1 and TBA were abundant in all samples and usually between equally abundant, and up to 50 fold more concentrated than the major polybrominated diphenyl ether congener BDE 47. The halogenated natural products BC-2 (2-MeO-BDE 68) and BC-3 (6'-MeO-BDE 47), were on level with BDE 100 which was the second most abundant BDE congener in many samples. The previously identified natural polybrominated hexahydroxanthene derivatives (PBHDs) were detected for the first time in bird eggs. Being major contaminants in bird eggs, PBHDs were only present at low levels in bird liver from nestlings originating from the same clutch. Such differences were detected for several other major contaminants. One unknown tetrabromo compound particularly abundant in mussels from Munkholmen was studied by GC/MS and the molecular ion was detected at m/z 446. The abundance of the most important unknown compounds did not correlate with BDEs and they most likely represent halogenated natural products. This study supports that halogenated natural products have to be treated as serious contaminants of marine coastal waters. Our data suggest that their abundance is highest in habitats along the shoreline. Thorough examination of these compounds in environmental samples is an important task.     

Relationships between stream size,suspended particles,and filter-feeding macroinvertebrates in a great plains drainage network

Suspended fine particles (seston) are an important component of energy and nutrient cycling in streams, but they can also be pollutants. We examined seston dynamics and filter-feeding macroinvertebrate communities in sites representing headwaters to large rivers in the Kansas River drainage, northeastern KS. Seston samples were collected at least seasonally during low to moderate flows for one year beginning in the summer of 1999, and quality was assessed by determining organic content and C to N ratio. A rapid bioassessment approach was used to examine filter-feeders. Relationships between stream size and seston concentrations were markedly influenced by anthropogenic activities. There was no relationship between total seston concentration and stream size across all sites (r = 0.14, p > 0.05), but a significant, positive relationship was evident when impounded and suburban sites were excluded (r = 0.73, p < 0.01); this same trend was evident for organic and inorganic components. Seasonal patterns of C to N ratio were evident, with generally lower values during winter and highest values in summer. However, seasonal patterns were dampened in suburban sites and virtually absent below impoundments. Filter-feeder richness was correlated with average organic seston concentrations (r = 0.8, p < 0.01), but this relationship was also obscured by impoundments and suburban development. In particular, impoundments had a dramatic, negative effect on richness. Abundance of most hydropsychid caddisfly taxa was positively correlated with organic seston concentration. Results indicate there are significant patterns regarding seston, filter-feeders, and stream size in this Great Plains river system, but patterns are strongly influenced by human activities. These relationships are relevant to management issues regarding suspended particles and the potential development of bioassessment techniques.     

Picloram and napropamide sorption as affected by polymer addition and salt concentration

Polymer application to soil is a growing practice to improve soil physical properties and reduce soil erosion. Polymer addition can potentially influence herbicide and pesticide sorption in soil. The one-point distribution coefficient Kd values of two herbicides in the absence and presence of each of 10 polymers (7 polyacrylamides and 3 polysaccharides) were determined by the batch equilibrium method. The results showed that nonionic napropamide [2-(alpha-naphthoxy)-N,N-diethyl propionamide] sorption was essentially unaffected by the presence of any of the polymers. The influence of polymers on anionic picloram (4-amino-3,5,6-trichloropicolinic acid) sorption depends on the charge characteristics of polymers and salt concentrations in the solution. Electrostatic interaction and competition for sorption sites are two primary underlying mechanisms for the polymer influence. At low salt concentration, the increased picloram sorption in the presence of both cationic and anionic polymers was attributed to different electrostatic interactions and polymer partitioning between soil and solution phases. At high salt levels, the presence of polymers had either no influence or a slightly negative influence on the picloram sorption, which was attributed to competition for sorption sites. In field conditions, it is more likely that polymers have no or a slightly negative influence on herbicide sorption due to the presence of salts.     

THE EFFECT OF DATA INDEPENDENCE IN MODEL CALIBRATION AND MODEL TESTING1

ABSTRACT: With the increased use of models in hydrologic design, there is an immediate need for a comprehensive comparison of hydrologic models, especially those intended for use at ungaged locations (i.e., where measured data are either not available or inadequate for model calibration). But some past comparisons of hydrologic models have used the same data base for both calibration and testing of the different models or implied that the results of model calibration are indicative of the accuracy at ungaged locations. This practice was examined using both the regression equation approach to peak discharge estimation and a unit hydrograph model that was intended for use in urban areas. The results suggested that the lack of data independence in the calibration and testing of regression equations may lead to both biased results and misleading statements about prediction accuracy. Additionally, although split-sample testing is recognized as desirable, the split-samples should be selected using a systematic-random sampling scheme, rather than random sampling, because random sampling with small samples may lead to a testing sample that is not representative of the population. A systematic-random sampling technique should lead to more valid conclusions about model reliability. For models like a unit hydrograph model, which are more complex and for which calibration is a more involved process, data independence is not as critical because the data fitting error variation is not as dominant as the error variation due to the calibration process and the inability of the model structure to conform with data variability.     

GAGE DENSITY AND LOCATION FOR ESTIMATING MEAN ANNUAL PRECIPITATION IN MOUNTAINOUS AREAS1

ABSTRACT: Data from a network of 45 shielded precipitation gages on the Reynolds Creek Experimental Watershed in Southwestern Idaho were analyzed to determine the optimum gage density for estimating mean annual precipitation. Four subsets of the 45 gage network were used to derive a curve of mean annual precipitation versus number of gages with a confidence band at the 95 percent level. When less than 20 gages were used in the estimate, the confidence interval widens rapidly. Estimates were improved by stratifying gages on the basis of plant cover class or by elevation bands. Sixty-four percent of the variation in mean annual precipitation was accounted for by elevation and cover class. The aspect and hydrologic soil classification were not statistically significant.     

BENEFITS FROM WATER CONSERVATION DEPEND ON COMPREHENSIVE PLANNING1

: Substantial reductions in municipal water use are feasible without reducing the quality of life. If conservation measures are preplanned, properly engineered, and coordinated, reductions in utility bills for water, waste water, and energy are estimated at $30+per person per year. Installation of devices to reduce water use, engineering plans to prevent malfunctioning of collecting sewers, and engineered process modifications of treatment facilities must be coordinated to achieve full benefits of water conservation. Pollutant discharges to the aquatic environment are reduced in direct proportion to the reduction in water use.     

Slash fire hazard analysis on the Siskiyou National Forest

Potential increase in fire hazard as a result of timber harvesting is a concern of forest managers throughout the United States. Treating fuels can help reduce unacceptable fire hazards. To evaluate alternative fuel treatments, managers need to know their effects on fire hazard. A decision analysis approach to estimating fire hazard in terms of expected burned area was applied to a watershed in the Siskiyou National Forest (Oregon). Three treatment alternatives (do nothing and two levels of yarding unmerchantable material) were evaluated, and the effects of the treatments were projected over a 90-yr period. Initially, the effects of applying a treatment are small. After 50 years of treatment, the most intense alternative can be expected to show almost a 50% reduction in burned area compared to no treatment. The procedure also estimates burned are by fire size and fire intensity classes. Managers may find this useful for estimating expected fire effects associated with a particular fuel treatment regime.