Effect of process integration on the exergy balance of a two-stage process for fermentative hydrogen production

In this paper, a process for the fermentative production of hydrogen is analysed with respect to its exergy efficiency. Parametric studies show the influence of used feedstock, applied process parameters as well as process and heat integration measures on exergy efficiency. It is shown that heat integration and recirculation of fermentor effluents reduce process irreversibilites and the amount of exergy leaving the process in waste streams. Nevertheless, depending on the used feedstock, a large amount of exergy leaves the process via by-products. Internal use of by-products and waste materials for providing process heat could increase chemical exergy efficiency up to 74%.     

Floral odor learning within the hive affects honeybees’ foraging decisions

Honeybees learn odor cues quickly and efficiently when visiting rewarding flowers. Memorization of these cues facilitates the localization and recognition of food sources during foraging flights. Bees can also use information gained inside the hive during social interactions with successful foragers. An important information cue that can be learned during these interactions is food odor. However, little is known about how floral odors learned in the hive affect later decisions of foragers in the field. We studied the effect of food scent on foraging preferences when this learning is acquired directly inside the hive. By using in-hive feeders that were removed 24 h before the test, we showed that foragers use the odor information acquired during a 3-day stimulation period with a scented solution during a food-choice situation outside the nest. This bias in food preference is maintained even 24 h after the replacement of all the hive combs. Thus, without being previously collected outside by foragers, food odors learned within the hive can be used during short-range foraging flights. Moreover, correct landings at a dual-choice device after replacing the storing combs suggests that long-term memories formed within the colony can be retrieved while bees search for food in the field.     

Separation and remediation of environmental pollutants using metal–organic framework-based tailored materials

Environmental Science and Pollution Research - Metal–organic frameworks (MOFs) are a polymer hybrid family of compounds comprising metal ions that have been deliberately incorporated in...     

Do Energy‐Based PET Models Require More Input Data than Temperature‐Based Models? — An Evaluation at Four Humid FluxNet Sites

It is well established that wet environment potential evapotranspiration (PET) can be reliably estimated using the energy budget at the canopy or land surface. However, in most cases the necessary radiation measurements are not available and, thus, empirical temperature‐based PET models are still widely used, especially in watershed models. Here we question the presumption that empirical PET models require fewer input data than more physically based models. Specifically, we test whether the energy‐budget‐based Priestley‐Taylor (P‐T) model can reliably predict daily PET using primarily air temperature to estimate the radiation fluxes and associated parameters. This method of calculating PET requires only daily minimum and maximum temperature, day of the year, and latitude. We compared PET estimates using directly measured radiation fluxes to PET calculated from temperature‐based radiation estimates at four humid AmeriFlux sites. We found good agreement between P‐T PET calculated from measured radiation fluxes and P‐T PET determined via air temperature. In addition, in three of the four sites, the temperature‐based radiation approximations had a stronger correlation with measured evapotranspiration (ET) during periods of maximal ET than fully empirical Hargreaves, Hamon and Oudin methods. Of the three fully empirical models, the Hargreaves performed the best. Overall, the results suggest that daily PET estimates can be made using a physically based approach even when radiation measurements are unavailable.     

Analysing household decision-making on oil palm cultivation in Thailand

This paper analyses the dynamics of land use via the perspectives, motivations and behaviours of local landowners looking at land-use change (through the landowner’s eyes) in the way that the landowners would prefer to do and not to do in various situations. The dynamics are explored in the context of an oil-palm-based biodiesel development in Thailand where the advent of oil palm (OP) has caused the loss of paddy areas. A sequential mixed-method strategy, including 10 in-depth interviews and 180 responses to a questionnaire survey, indicates that the likelihood of a landowner switching traditional land for OP cultivation is affected by a number of factors including age and education of the head of household, number of household farming labourers, amount and source of income, land size and land right. Moreover, the results indicate that success of switching land to OP cultivation was determined by factors influencing willingness and capacity to change. Willingness-related factors are relevant to outcome expectation and social networks and connections while capacity-related factors are relevant to finance, labour, capital, land rights and transportation.     

Testing of chemical substances for environmental effects—an important task for the chemical industry

Recently the heterogeneous reactions are increasingly recognised as significant in polluted areas. In this work the reactions of gases with solid alkali‐halide crystals at temperatures 200K and 300K were examined by using a recently proposed thermodynamic model (Varotsos et al., 1988) which provides the interconnection of entropy and enthalpy for various processes with well known macroscopic properties of the bulk solid.     

Demography, demand, death, and the seasonal allocation of labor in the Florida harvester ant (Pogonomyrmex badius)

As a self-organizing entity, an ant colony must divide a limited number of workers among numerous competing functions. Adaptive patterns of labor allocation should vary with colony need across each annual cycle, but remain almost entirely undescribed in ants. Allocation to foraging in 55 field colonies of the Florida harvester ant (Pogonomyrmex badius) followed a consistent annual pattern over 4 years. Foragers preceded larvae in spring and peaked during maximal larval production in summer (0.37). In spring, proportion foraging increased due to an increase in forager number and reduction in colony size, and in late summer, it decreased as colony size increased through new worker birth and a loss of ～3 % of foragers per day. The removal of 50 % of the forager population revealed that, at the expense of larval survival, colonies did not draw workers from other castes to fill labor gaps. To determine if labor allocation was age specific, whole colonies were marked with cuticle color-specific wire belts and released, and each cohort's time to first foraging was noted. Workers that eclosed in summer alongside sexual alates darkened quickly and became foragers at ～43 days of age, whereas autumn-born workers required 200 or more days to do so. Following colony reproduction, these long-lived individuals foraged alongside short-lived, summer-born sisters during the next calendar year. Therefore, the large-scale, predictable patterns of labor allocation in P. badius appear to be driven by bimodal worker development rate and age structure, rather than worker responsiveness to changes in colony demand.     

Risk communication in emergency response to a simulated extreme flood

Risk communication in flood incident management can be improved through developing hydrometeorological and engineering models used as tools for communicating risk between scientists and emergency management professionals. A range of such models and tools was evaluated by participating flood emergency managers during a 4-day, real-time simulation of an extreme event in the Thamesmead area in the Thames estuary close to London, England. Emergency managers have different communication needs and value new tools differently, but the indications are that a range of new tools could be beneficial in flood incident management. Provided they are communicated large model uncertainties are not necessarily unwelcome among flood emergency managers. Even so they are cautious about sharing the ownership of weather and flood modelling uncertainties.     

Prospects for Development of an Index of Biotic Integrity for Evaluating Habitat Degradation in Coastal Systems

A multivariate index for assessment of habitat quality and its degradation, the Index of Biotic Integrity (IBI), has been developed for stream fish communities. the extension of the IBI concept to coastal waters is proposed by the development of an estuarine IBI based on macrobenthos and submerged aquatic vegetation. Eleven variables are proposed for inclusion in this index, although further consideration of the appropriateness of several variables is required. It is concluded that development of an IBI for coastal systems is feasible.     

Predicting barrier passage and habitat suitability for migratory fish species

Fish migrate to spawn, feed, seek refuge from predators, and escape harmful environmental conditions. The success of upstream migration is limited by the presence of barriers that can impede the passage of fish. We used a spatially explicit modeling strategy to examine the effects of barriers on passage for 21 native and non-native migratory fish species and the amount of suitable habitat blocked for each species. Spatially derived physical parameter estimates and literature based fish capabilities and tolerances were used to predict fish passage success and habitat suitability. Both the fish passage and the habitat suitability models accurately predicted fish presence above barriers for most common, non-stocked species. The fish passage model predicted that barriers greater than or equal to 6 m block all migratory species. Chinook salmon (Oncorhynchus tshawytscha) was expected to be blocked the least. The habitat suitability model predicted that low gradient streams with intact habitat quality were likely to support the highest number of fish species. The fish passage and habitat suitability models were intended to be used by environmental managers as strategy development tools to prioritize candidate dams for field assessment and make decisions regarding the management of migratory fish populations.