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91.
Guangyong Zhu Xian Zhu Zuobing Xiao Rujun Zhou Yalun Zhu Xueliang Wan 《Journal of Material Cycles and Waste Management》2014,16(3):546-556
Biomass is recognized as an important solution to energy and the environmental problems related to fossil fuel usage. The rational utilization of biomass waste is important not only for the prevention of environmental issues, but also for the effective utilization of natural resources. Pyrolysis and hyrolysis in subcritical water are promising processes for biomass waste conversion. This paper deals with hydrolysis and pyrolysis of peanut shells. Hydrolysis and pyrolysis kinetics of peanut shell wastes were investigated for the in-depth exploration of process mechanisms and for the control of the reactions. Hydrolysis kinetics was conducted in a temperature range of 180–240 °C. A simplified kinetic model to describe the hydrolysis of peanut shells was proposed. Hydrolysis activation energy as well as the pre-exponential factor was determined according to the model. The target products of peanut shell hydrolysis, reducing sugars, can reach up to 40.5 % (maximum yield) at 220 °C and 180 s. Pyrolysis characteristics were investigated. The results showed that three stages appeared in this thermal degradation process. Kinetic parameters in terms of apparent pyrolysis activation energy and pre-exponential factor were obtained by the Coats–Redfern method. 相似文献
92.
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94.
Amira Zaouak Fatma Matoussi Mohamed Dachraoui 《Journal of environmental science and health. Part. B》2013,48(10):878-884
The electrochemical oxidation of bifenox acid was studied at a boron-doped diamond thin film by cyclic voltammetry and galvanostatic electrolysis. The course of the electrolysis was monitored by measurement of chemical oxygen demand (COD) and by gas chromatography/mass spectrometry (GC / MS) analysis. It was found that exhaustive electrolysis leads to degradation and, ultimately, to mineralization of the starting herbicide. The degradation intermediates were identified showing that the oxidation process begins with the fragmentation of the molecule followed by reactions involving the hydroxyl radical, which is generated by the discharge of water. The study of the effect of current density and concentration showed that the degradation efficiency increases with decreasing current densities and increasing concentrations. The whole results were interpreted in a mechanistic scheme involving two oxidation pathways, the first is a direct oxidation at the electrode and the second uses hydroxyl radical as mediator of the oxidation. Finally, a kinetic study based on spectrophotometric measurements showed that the degradation process is pseudo first order. 相似文献
95.
Fatma M. El-Demerdash Ali B. Jebur Hoda M. Nasr 《Journal of environmental science and health. Part. B》2013,48(7):593-599
The joint action of pyrethroids, lambda-cyhalothrin (LC) in combination with organophosphates, fenitrothione (FNT) on antioxidant defense system and lipid peroxidation biomarkers in rat testes was studied. The results suggest that incubation of testes homogenate with different concentrations of insecticide mixture for different time intervals significantly decreased the activity of antioxidant enzymes, like glutathione S-transferase (GST), superoxide dismutase (SOD) and catalase (CAT), and the level of reduced glutathione (GSH). In addition, a significant inhibition in transaminases (AST, ALT), phosphatases (AcP, AlP) activity and protein content were observed. On the other hand, FNT plus LC increased the cellular lipid peroxidation (LPO) level and the activity of lactate dehydrogenase (LDH). In conclusion, the use of insecticides mixture might cause marked oxidative damage in a concentration and time-dependent manner. 相似文献
96.
以表面活性剂TritonX-100(TX-100)为洗脱剂,某有机氯农药(organochlorinepesticides,OCPs)污染场地土壤为对象,七氯、氯丹和灭蚁灵为目标污染物,研究微米Cu/Fe双金属对污染土壤洗脱液中OCPs的降解效果。考察了洗脱液中OCPs初始浓度、洗脱液pH值、微米零价铁加入量和cu负载量对Cu/Fe去除OCPs效果的影响。结果表明,微米Cu/Fe可以有效的去除土壤洗脱液中目标污染物。当微米零价铁加入量为1.0g(25g/L),cu负载量为1.0%,洗脱液pH值为6.89时,Cu/Fe对2号土壤洗脱液中七氯、γ-氯丹、α-氯丹和灭蚁灵的去除效果最好,去除率分别为100.0%、99.3%、80.8%和71.1%。洗脱液中OCPs初始浓度越低,微米零价铁加入量越大,Cu/Fe对OCPs去除率越高;偏酸性条件有利于Cu/Fe对γ-氯丹和灭蚁灵的去除,而α-氯丹在中性条件下去除效果最好;1号土壤和2号土壤洗脱液的最佳铜负载量分别为2.O%和1.0%。 相似文献
97.
Zheng J Wu F Yamada M Liao H Liu C Wan G 《Environmental pollution (Barking, Essex : 1987)》2008,152(2):314-321
Studies on the distribution and isotope compositions of fallout Pu are important for source characterization of possible future non-fallout Pu contamination in aquatic environments, and useful for dating of recent sediments to understand the pollution history of environmental contaminants. We present the historical record of atmospheric Pu fallout reconstructed from a sediment core from Lake Hongfeng, China. The Pu activity profile was in agreement with the 137Cs profile. Inventories were 50.7 Bq m(-2) for 239+240Pu and 1586 Bq m(-2) for 137Cs. The average 240Pu/239Pu atom ratio was 0.185+/-0.009, indicating that Pu originated from global stratospheric fallout rather than from direct tropospheric or close-in fallout from the Chinese nuclear testing conducted in the 1970s. Our data suggested that Lake Hongfeng would be an ideal setting for monitoring atmospheric fallout and environmental changes in this region. 相似文献
98.
The concentrations, distribution and sources of PAHs in agricultural soils and vegetables from Shunde, Guangdong, China 总被引:4,自引:0,他引:4
Li YT Li FB Chen JJ Yang GY Wan HF Zhang TB Zeng XD Liu JM 《Environmental monitoring and assessment》2008,139(1-3):61-76
The concentrations, distribution and sources of 16 polycyclic aromatic hydrocarbons (PAHs) were determined in 30 agricultural
soil and 16 vegetable samples collected from subtropical Shunde area, an important manufacturing center in China. The total
PAHs ranged from 33.7 to 350 μg/kg in soils, and 82 to 1,258 μg/kg in vegetables. The most abundant individual PAHs are phenanthrene,
fluoranthene, chrysene, pyrene and benzo(b)fluoranthene for soil samples, and anthracene, naphthalene, phenanthrene, pyrene
and chrysene for vegetable samples. Average vegetable–soil ratios of total PAHs were 2.20 for leafy vegetables and 1.27 for
fruity vegetables. Total PAHs in vegetable samples are not significantly correlated to those in corresponding soil samples.
Principal component analyses were conducted to distinguish samples on basis of their distribution in each town, soil type
and vegetable specie. Relatively abundant soil PAHs were found in town Jun’an, Beijiao, Chencun, Lecong and Ronggui, while
abundant vegetable PAHs were observed in town Jun’an, Lecong, Xingtan, Daliang and Chenchun. The highest level of total PAHs
were found in vegetable soil, followed by pond sediment and “stacked soil” on pond banks. The PAHs contents in leafy vegetables
are higher than those in fruity vegetables. Some PAH compound ratios suggest the PAHs derived from incomplete combustion of
petroleum, coal and refuse from power generation and ceramic manufacturing, and paint spraying on furniture, as well as sewage
irrigation from textile industries. Soil PAHs contents have significant logarithmic correlation with total organic carbon,
which demonstrates the importance of soil organic matter as sorbent to prevent losses of PAHs. 相似文献
99.
A study of chemical and sedimentological parameters integrated with benthic foraminifera investigation was conducted along
the northern coast of Gabes Gulf. Thirty-two samples were studied and a total of 68 benthic foraminiferal species were identified.
Heavy metals enrichment factors and total hydrocarbon concentrations showed both metal and petrogenic pollution related mainly
to phosphogypsum, sewage, and fishing activities. Statistical analysis (bivariate correlation and hierarchical cluster analysis)
show a possible control of these pollutants on density, diversity, as well as the taxonomic composition of the benthic foraminiferal
assemblages. The extent to which the population was found less dense and less diversified corresponded to the degree to which
the sediment was contaminated. In these contaminated sites, an increase in relative abundance of opportunistic species such
Ammonia tepida and Haynesina germanica was found. Far from pollution, foraminiferal assemblages are dominated by species characteristic of Mediterranean shallow
water (Ammonia beccarii, Ammonia parkinsoniana, Elphidium crispum, Elphidium williamsoni, Elphidium advenum, Peneroplis planatus, Peneroplis pertesus). 相似文献
100.
Nesrine Gdoura Abdelwaheb Abdelmouleh Jean-Claude Murat Khansa Chaabouni Fatma Makni-Ayedi Abdelfattah Elfeki 《Environmental Chemistry Letters》2012,10(2):193-199
An adequate human diet should satisfy the requirements for energy and nutritive components including essential polyunsaturated
fatty acids, essential amino acids, mineral components, vitamins, and fat. The benefits of the fish consumption are, however,
often counteracted by toxic metals such as lead present in fish meat. Adverse effects of toxic metals on the aquatic environment
and human health have aroused increasing interest in recent years. The achievement of an appropriate balance between the risks
and benefits associated with fish consumption has therefore become a key health issue in current research. Therefore, we studied
health impacts associated with the consumption of sardine fish, one of the most commonly consumed fish species throughout
the world. Hepatic damages associated with the consumption of white or red muscle of sardine fish were explored and evaluated
using a rat model. Rats were fed for 60 days with white or red sardine meat. Findings revealed (1) an elevated level of uric
acid in the blood, (2) an accumulation of lead in the liver, (3) an atrophy of the liver, (4) an increase in plasma aspartate
aminotransferase and alanine aminotransferase activities, and (5) an oxidative stress in the liver, including increased levels
of lipid peroxidation and enhanced activities of superoxide dismutase, catalase, and glutathione peroxidase. Several abnormalities
were also observed in liver histology. The alterations observed in the animals can be attributed to both the accumulation
of lead and the high levels of purine in the sardine meat. The findings show that special attention should be given to the
health effects associated with high intakes of sardine meat, particularly dark-meat sardine. 相似文献