2-Chlorophenol oxidation kinetic by photo-assisted Fenton process

Experimental data are presented to test and validate a kinetic model for the oxidation of 2-chlorophenol wastewater by photo-assisted Fenton process. The data showed that this process had produced good effects under acidic conductions. Up to 90% 2-chlorophenol was removed after 90-minute reaction time with H2O2 of 25% CODCr. in, while in UV/H2O2 system ordy 16.8% 2-chlorophenol was removed after one hour treatment. The optimal pH in this reaction occurred between pH 3.0 and pH 4.0. The reaction kinetics for photo-assisted Fenton process experimented in this research was investigated. Kinetic models were proposed for the treatment of 2-chlorophenol wastewater. The reaction was found to follow the 2nd order. The equations of reaction kinetics are as follows:-d[RH]/dt=KRH[RH][H2O2]0exp(-KH2o2t);-d[CODCr]/dt=KCODCr[CODCr][H2O2]0exp(-K′t).The prediction of the models was found to be in a good agreement with experimental results, thus confimfing the proposed reaction mechanism.     

气浮过程中的界面相互作用

首先讨论了水体颗粒物的基本性质以及气泡的形成过程，而后对气液界面上胶体颗粒的吸附进行分析。其次讨论了气浮过程中，气泡与颗粒物之间的相互作用。对气泡与颗粒物之间的碰撞进行分析。结合紊流气浮的理论与应用，在气浮过程中的界面相互作用分析的基础上。设计了一种新型集成的溶气气浮水处理工艺，即逆流共聚气浮工艺，并对其运行情况进行了研究。探讨了其中的界面相互作用对气浮效果的影响，进一步与传统工艺进行了对比。     

城市适度人口分析方法及其应用

考虑资源承载力 (R)和生活舒适度 (S)对适度人口的影响 ,以不同经济发展水平下的人口现状为依据 ,提出R S双向寻优方法进行城市适度人口分析 .并以广州市为例 ,寻求其最优人口容量 .结果表明 ,现有资源承载力与经济水平下的广州人口规模略高于适度人口规模 ,需要进行人口与经济密度的重新布局 .     

连江地热水排放对水体、土壤和农作物的影响研究

探讨了连江地热水利用排放对水体、土壤农作物、鱼类的影响，为今后保护环境和合理开发利用地热水提供科学依据。     

Catalytic dechlorination of chlorobenzene in water by Pd/Fe bimetallic system

IntroductionChlorinatedorganiccompoundshavebeenusedonalargescaleinthechemical,petrochemical,andelectronicindustries.Inrecentyears ,worldwideattentionhasbeengiventotheenvironmentalandhealthimpactofthemasaclassofcontaminants .Severalareknowntocauseozonedepletion ,whileothersproduceadverseeffectsonthehumancentralnervoussystemandhavebeenlinkedtodiseasessuchascancer.Almostallofthechlorinatedaromaticcompoundsaretoxicandthermallystable .Oncereleasedintoenvironment,theywillaccumulateinthesurroundings…     

Catalysts for decomposing ozone tail gas

The preparation of immobilizing-catalysts for decomposing ozone by using dipping method was studied. XRD, XPS and TEM were used to characterize the catalysts. The three kinds of catalysts were selected preferentially, and their catalytic activities were investigated. The results showed that the catalyst with activated carbon dipping acetate( active components are Mn:Cu = 3:2, active component proportion in catalyst is 15%, calcination temperature is 200℃ ) has the best catalytic activity for ozone decomposing. One gram of catalyst can decompose 17.6g ozone at initial ozone concentration of 2.5g/m^3 and the residence time in reactor of 0.1s. The experimental results also indicated that humidity of reaction system had negative effect on catalytic activity.     

直岗拉卡水电站工程生态环境的影响分析

直岗拉卡水电站地处青藏高原,是黄河上游第4个梯级电站,工程所处区域属生态环境十分敏感和脆弱的青藏高原。论文在阐述直岗拉卡水电站工程影响区生态环境基本特征的基础上,度量了该区域生物多样性及电站运行后对生态环境的影响程度,提出了相关对策。分析表明,直岗拉卡水电站工程在实施严格的环境保护措施后对生态环境的影响是可以接受的。     

糠醛废水处理工程的调试运行实例

本文就糠醛生产工艺与生产废水水质特点 ,采用中和———厌氧———好氧气浮处理技术 ,对工程试运行中的各个环节及处理问题的措施及小试过程效果的应用 ,作系统的介绍。     

次声实验系统及其声学性能分析

为了从环境保护和劳动卫生学的角度研究次声对人的影响 ,本研究基于亥姆霍兹谐振器的基本原理研制了一个次声试验系统。该系统由亥姆霍兹谐振器、电声驱动部分和测控分析部分组成 ,通过对该系统的声学性能进行测试和分析 ,确定了系统所能发出的次声频率和次声级范围 ,讨论了系统发出次声时所产生的高次谐波对系统性能的影响及系统的频响特性 ,检验了谐振腔内部次声场空间分布的均匀性 ,结果表明该系统的声学性能是令人满意的 ,能够满足研究次声及其对人影响的实验要求。     

封闭式芦苇湿地处理钻井泥浆的可行性研究

研究了现场中试条件下芦苇湿地处理钻井泥浆的可行性及钻井泥浆对土壤和芦苇等湿地介质的影响。研究结果表明：在7个月运行期内，单位面积钻井泥浆施入量5kg/m^2,20kg/m^2和40kg/m^2的芦苇湿地对矿物油的迁移降解率分别为75％－85％，78％－90％和65％－90％；钻进泥浆中的矿物油对湿地土壤的污染基本局限于表层，对深层土壤的污染趋势并不明显，一般40cm以下矿物含量已低于对照区表层土的背景值；钻井泥浆能增加芦苇的生物量，对芦苇品质指标的影响很小。