全文获取类型
收费全文 | 16750篇 |
免费 | 600篇 |
国内免费 | 6089篇 |
专业分类
安全科学 | 1091篇 |
废物处理 | 1046篇 |
环保管理 | 1335篇 |
综合类 | 9112篇 |
基础理论 | 2914篇 |
环境理论 | 2篇 |
污染及防治 | 5992篇 |
评价与监测 | 649篇 |
社会与环境 | 580篇 |
灾害及防治 | 718篇 |
出版年
2024年 | 3篇 |
2023年 | 245篇 |
2022年 | 752篇 |
2021年 | 604篇 |
2020年 | 465篇 |
2019年 | 477篇 |
2018年 | 589篇 |
2017年 | 730篇 |
2016年 | 761篇 |
2015年 | 959篇 |
2014年 | 1319篇 |
2013年 | 1803篇 |
2012年 | 1398篇 |
2011年 | 1502篇 |
2010年 | 1106篇 |
2009年 | 1086篇 |
2008年 | 1130篇 |
2007年 | 1021篇 |
2006年 | 938篇 |
2005年 | 696篇 |
2004年 | 494篇 |
2003年 | 616篇 |
2002年 | 562篇 |
2001年 | 507篇 |
2000年 | 500篇 |
1999年 | 532篇 |
1998年 | 489篇 |
1997年 | 397篇 |
1996年 | 368篇 |
1995年 | 319篇 |
1994年 | 261篇 |
1993年 | 208篇 |
1992年 | 167篇 |
1991年 | 94篇 |
1990年 | 81篇 |
1989年 | 57篇 |
1988年 | 52篇 |
1987年 | 33篇 |
1986年 | 28篇 |
1985年 | 15篇 |
1984年 | 16篇 |
1983年 | 18篇 |
1982年 | 11篇 |
1981年 | 12篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1976年 | 2篇 |
1975年 | 4篇 |
1974年 | 2篇 |
1966年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
991.
A biomimetic absorbent for removal of trace level persistent organic pollutants from water 总被引:1,自引:0,他引:1
A novel biomimetic absorbent containing the lipid triolein was developed for removing persistent organic pollutants (POPs) from water. The structural characteristics of the absorbent were obtained by SEM and a photoluminescence method. Under optimum preparation conditions, triolein was perfectly embedded in the cellulose acetate (CA) spheres, the absorbent was stable and no triolein leaked into the water. Dieldrin, endrin, aldrin and heptachlor epoxide were effectively removed by the CA--triolein absorbent in laboratory batch experiments. This suggests that CA-triolein absorbent may serve as a good absorbent for those selected POPs. Triolein in the absorbent significantly increased the absorption capacity, and lower residual concentrations of POPs were achieved when compared to the use of cellulose acetate absorbent. The absorption rate for lipophilic pollutants was very fast and exhibited some relationship with the octanol--water partition coefficient of the analyte. The absorption mechanism is discussed in detail. 相似文献
992.
Dissipation of pentachlorophenol (PCP) in soil was investigated and the chemical relationships with soil properties were addressed. The results indicate that the dissipation of extractable PCP residues can be described using first-order kinetics equations, with a half-dissipation time (T(1/2)) ranging from 6.5 to 173.3d. The sharply different patterns of PCP dissipation in different soils were closely related to soil properties. Correlations of stepwise regression equations obtained were significant at 0.01 probability level between soil parameters and extractable PCP residues (R(2)=0.974**) as well as T(1/2) values (R(2)=0.882**). Using pH together with organic carbon content (OC) and soil particle size distribution, the dissipation dynamics of PCP in soil could be accurately predicted. 相似文献
993.
Analysis of patterns and ecological security trend of modern oasis landscapes in Xinjiang, China 总被引:6,自引:0,他引:6
Ecological security has become so important that it will affect the national security and social sustainable development.
In this paper, a case study on the ecological security indexes of modern oasis landscapes in Beitun Oasis, Xinjiang, was carried
out. The spatial neighbouring parameters, such as the contiguous length, measure of area and patch quantity of oasis landscape
patches, affected by desert landscape patches were calculated by using GIS-based buffer analysis, the method of calculating
ecological security indexes of oasis landscape was developed, and the dynamic changes of patterns and ecological security
indexes of the oasis landscapes since recent 30 years were analyzed. The results showed that soil salinization or alkalization
and paludification were major factors affecting the ecological security in Beitun Oasis. Therefore, measures should be taken
actively to prevent and control secondary salinization and paludification. The ecological security indexes of the oasis landscape
in 1972, 1990 and 2005 were 78.91, 82.28 and 83.86, respectively, which showed the degree of security is improving, and the
environment was developing harmoniously between human and nature. The methods of evaluating ecological security based on the
spatial neighbouring relations between landscape patches can be used to reflect preliminarily the ecological security patterns
of landscapes. 相似文献
994.
With dimethyl phthalate as the model pollutant and Ru/Al(2)O(3) as catalyst, this paper systemically investigates the removal of total organic carbon (TOC) of system. Our results have confirmed that Ru/Al(2)O(3) can significantly increase the effect of ozonation. TOC removal in 120 min can reach 72% while only 24% with ozone alone. The optimal catalyst preparing condition was 0.1 wt% Ru content, 600 degrees C calcination temperature, 0.5-1.0mm particle diameter, which is characterized by a high surface area and a large population of surface active sites. The contrasting experiments of ozone alone, catalyst adsorption after ozonation, and catalytic ozonation confirmed that catalytic reaction was the most important process to TOC removal in system with Ru/Al(2)O(3) as catalyst. 相似文献
995.
Monitoring of organochlorine pesticides using PFU systems in Yunnan lakes and rivers, China 总被引:3,自引:0,他引:3
Polyurethane foam unit (PFU) systems were collected from 11 lakes and three rivers in the Yunnan Plateau, China and, the PFU extrusion liquids were analyzed for organochlorine pesticides (OCPs) by gas chromatography with electron capture detection (GC-ECD). The concentrations of pp'-DDE, HCB and HCHs were undetectable to 1.86 microgl-1 (mean 0.27 microgl-1), undetectable to 0.72 microgl-1 (mean 0.11 microgl-1), and 0.24-21.95 microgl-1 (mean 7.39 microgl-1) respectively in lakes; and those in rivers were undetectable to 0.23 microgl-1 (mean 0.08 microgl-1), 0.68-2.93 microgl-1 (mean 1.70 microgl-1), and 2.71-37.56 microgl-1 (mean 17.01 microgl-1) respectively. Notably, some residue levels of OCPs exceeded the US National Recommended Water Quality Criteria, implying Yunnan has levels of OCPs potentially harmful to human health. Further, the contamination by OCPs showed an obvious spatial distribution pattern. Amongst the lakes, Dianchi, Xingyun, Lugu and Yangzonghai had the highest OCP levels dominated by beta-HCH, whereas among rivers, Nujiang and Lancang Rivers had the highest contents of OCPs dominated by alpha-HCH. This demonstrates that HCHs are the predominant contaminants and some point sources of HCHs may still exist in Yunnan. The pollution levels in Yunnan were compared with other studies, suggesting the PFU method is suitable for long-term on-line monitoring of trace OCPs in aquatic ecosystems. Therefore, continuous studies monitoring OCPs in lakes and rivers are needed to further understand the future trend of contamination. 相似文献
996.
A species of bacteria that is capable of utilizing imazaquin as the sole carbon source was isolated from soil with repeated imazaquin applications, and was identified as Arthrobacter crystallopoietes (designated as strain “WWX-1”). This isolate degrades imazaquin as high as 200 μg ml−1, and the estimated dissipation half-lives increased from 1.51 d for the treatment at 50 μg ml−1 to 4.75 d for 200 μg ml−1. Optimal growth of WWX-1 in mineral salt medium with 50 μg ml−1 imazaquin was obtained at 35 °C and a pH of 5.0. Growth of WWX-1 was also observed in mineral salt medium with the addition of other imidazolinone herbicides such as imazethapyr and imazapyr, but not with different classes of herbicides such as metsulfuron-methyl. Two imazaquin metabolites were detected, and spectral analysis with HPLC–MS, 1H NMR, and IR revealed one metabolite with a molecular weight (MW) of 199 as quinoline-2,3-dicarboxylic anhydride. We propose that A. crystallopoietes (WWX-1) could serve as an efficient biodegradation system for remediation of water and soils that are heavily contaminated with imazaquin or other structurally similar chemicals. 相似文献
997.
Kuang YW Zhou GY Da Wen Z Liu SZ 《Environmental science and pollution research international》2007,14(4):270-275
Goal, Scope and Background Rapid urbanization and the expansion of industrial activities in the past several decades have led to large increases in emissions
of pollutants in the Pearl River Delta of south China. Recent reports have suggested that industrial emission is a major factor
contributing to the damages in current natural ecosystem in the Delta area. Tree barks have been used successfully to monitor
the levels of atmospheric metal deposition in many areas, but rarely in China. This study aimed at determining whether atmospheric
heavy metal deposition from a Pb-Zn smeltery at Qujiang, Guangdong province, could be accurately reflected both in the inner
bark and the outer bark of Masson pine (Pinus massoniana L.). The impact of the emission from smeltery on the soils beneath the trees and the relationships of the concentrations
between the soils and the barks were also analyzed.
Methods Barks around the bole of Pinus massoniana from a pine forest near a Pb-Zn smeltery at Qujiang and a reference forest at Dinghushan natural reserve were sampled with
a stainless knife at an average height of 1.5 m above the ground. Mosses and lichens on the surface barks were cleaned prior
to sampling. The samples were carefully divided into the inner bark (living part) and the outer bark (dead part) in the laboratory,
and dried and ground, respectively. After being dry-ashed, the powder of the barks was dissolved in HNO3. The solutions were analyzed for iron (Fe), manganese (Mn), copper (Cu), zinc (Zn), chromium (Cr), nickel (Ni) and cobalt
(Co) by inductively coupled plasmas emission spectrometry (ICP, PS-1000AT, USA) and Cadmium (Cd) and lead (Pb) by graphite
furnace atomic absorption spectrometry (GFAAS, ZEENIT 60, Germany). Surface soils (0–10 cm) beneath the sample trees were
also collected and analyzed for the selected metals.
Results and Discussion Concentrations of the selected metals in soils at Qujiang were far above their environmental background values in the area,
except for Fe and Mn, whilst at Dinghushan, they were far below their background values, except for Cd and Co. Levels of the
metals, in particular Pb and Zn, in the soils beneath the sample trees at Qujiang were higher than those at Dinghushan with
statistical significance. The result suggested that the pine forest soils at Qujiang had a great input of heavy metals from
wet and dry atmospheric deposition, with the Pb-Zn smeltery most probably being the source.
Levels of Cu, Fe, Mn, Zn, Ni and Pb at Qujiang, both in the inner and the outer bark, were statistically higher than those
at Dinghushan. Higher concentrations of Pb, Fe, Zn and Cu may come from the stem-flow of elements leached from the canopy,
soil splash on the 1.5 m height and sorption of metals in the mosses and lichens growing on the bark, which were direct or
indirect results from the atmospheric deposition. Levels of heavy metals in the outer barks were associated well with the
metal concentrations in the soil, reflecting the close relationships between the metal atmospheric deposition and their accumulation
in the outer bark of Masson pine. The significant (p<0.01) correlations of Fe-Cu, Fe-Cr, Fe-Pb, Fe-Ni, Pb-Ni, and Pb-Zn in
the outer barks at Qujiang again suggested a common source for the metals. The correlation only occurred between Pb and Ni,
Cd and Co in the outer barks at Dinghushan, which suggested that those metals must possibly have other uncommon sources.
Conclusions Atmospheric deposition of the selected metals was great at Qujiang, based on the levels in the bark of Pinus massoniana and on the concentrations in the soils beneath the trees compared with that at Dinghushan. Bark of Pinus massoniana, especially the outer bark, was an indicator of metal loading at least at the time of sampling.
Recommendations and Perspectives The results from this study and the techniques employed constituted a new contribution to the development of biogeochemical
methods for environmental monitoring particularly in areas with high frequency of pollution in China. The method would be
of value for follow up studies aimed at the assessment of industrial pollution in other areas similar with the Pearl River
Delta. 相似文献
998.
Yu FC Chen CY Lin SC Lin YC Wu SY Cheung KW 《Environmental monitoring and assessment》2007,132(1-3):419-428
As the embodiment of human activities, the change of regional industrial structure is an essential driving factor of global
environmental change. Consequently, the research on the change of regional industrial structure and associated effects on
the environment is one of the key issues of researches on sustainable development, human–environment relationship, and regional
response to global environment change. However, compared to the flourish of researches on environmental impact assessment
of industrial departments, few studies have been conducted to assess the environmental impact of regional industrial structure.
In this study, based on a synthetic analysis of environmental disturbances of different industrial departments, the environmental
impact coefficient of industrial department associated with the index of environmental impact of industrial structure was
constructed, so as to make a quantitative assessment of environmental impact of the change of regional industrial structure.
And the results of the case study in Lijiang City, a rural region of China, have showed that there are two obvious changes
of industrial structure in the study area from 1992 to 2003, associated with a continuous decreasing of the index of environmental
impact of industrial structure, which indicated a positive environmental effects of the change of regional industrial structure. 相似文献
999.
Strontium (Sr) and calcium (Ca) contents in the otoliths of yellow and silver European eels [Anguilla anguilla (L.)] collected from coastal waters of the Baltic Sea and a freshwater lake in Sweden were examined by wavelength dispersive
X-ray spectrometry with an electron microprobe. The mean Sr/Ca ratios from elver check to otolith edge were significantly
higher for the eels from coastal waters (5.39 ± 1.09‰) than for those from the lake (0.71 ± 0.89‰). The evidence indicates
that European eels in the Baltic Sea do not necessarily migrate into freshwater streams during the growth phase.
Received: 30 September 1999 / Accepted: 6 April 2000 相似文献
1000.