Quantitative structure - activity study on the reductivedehalogenation potency of the halogenated aromatics

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基于有限元法的双层底板立式储罐可靠性分析

针对双层底板结构储罐上层底板变形过大产生强度失效问题的隐患,通过对装满辛烷的储罐结构力学行为进行有限元分析,研究了不同底板支撑结构形式及不同格栅间距情况下,上层底板的挠度变形及储罐的应力分布情况.研究结果表明在双层底板立式储罐的设计过程中应注重罐壁底部位置加强措施.     

Comparing dark- and photo-Fenton-like degradation of emerging pollutant over photo-switchable Bi2WO6/CuFe2O4: Investigation on dominant reactive oxidation species

The extensive use of tetracycline hydrochloride (TCH) poses a threat to human health and the aquatic environment. Here, magnetic p-n Bi₂WO₆/CuFe₂O₄ catalyst was fabricated to efficiently remove TCH. The obtained Bi₂WO₆/CuFe₂O₄ exhibited 92.1% TCH degradation efficiency and 50.7% and 35.1% mineralization performance for TCH and raw secondary effluent from a wastewater treatment plant in a photo-Fenton-like system, respectively. The remarkable performance was attributed to the fact that photogenerated electrons accelerated the Fe(III)/Fe(II) and Cu(II)/Cu(I) conversion for the Fenton-like reaction between Fe(II)/Cu(I) and H₂O₂, thereby generating abundant ?OH for pollutant oxidation. Various environmental factors including H₂O₂ concentration, initial pH, catalyst dosage, TCH concentration and inorganic ions were explored. The reactive oxidation species (ROS) quenching results and electron spin resonance (ESR) spectra confirmed that ?O₂^? and ?OH were responsible for the dark and photo-Fenton-like systems, respectively. The degradation mechanisms and pathways of TCH were proposed, and the toxicity of products was evaluated. This work contributes a highly efficient and environmentally friendly catalyst and provides a clear mechanistic explanation for the removal of antibiotic pollutants in environmental remediation.     

微絮凝-超滤技术处理城市污水厂出水研究

利用微絮凝超滤组合技术处理某城市污水厂二级出水,结果表明:各主要污染物指标优于城市杂用水水质标准,并能满足反渗透进水水质要求;采用微絮凝代替传统的絮凝方法节省了絮凝剂;同时结合不断向膜组件曝气以及膜清洗等措施控制膜污染,效果显著。     

悬浮膜(CFM)分离技术在油田废水处理中的应用

应用微电解等技术对油田废水进行预处理,然后用悬浮膜进行分离,使其中的油、微生物和固体物与水相分离,使其达到回注用水要求。重点对CFM分离设备的结构及原理加以介绍,以期推进过滤技术的进步,提高油田废水的处理水平。     

短程硝化颗粒污泥的快速培养与硝化特性研究

以城市污水处理厂剩余污泥为种泥,以2 min沉淀时间为选择压,在序批式反应器(SBR)中快速培养出好氧颗粒污泥。经过60个周期(20 d),反应器内出现砂粒状颗粒,并持续稳定运行120 d。成熟的颗粒污泥平均粒径856.56μm,具有良好的硝化性能。SBR反应器以固定曝气时间方式运行,亚硝酸盐积累率达80%以上,实现了稳定短程硝化。试验结果表明:絮体污泥(即接种污泥)与颗粒污泥的硝化过程相似但略有差异。二者差别在于,氨氮氧化结束后,继续曝气120 min,絮体污泥将亚硝酸盐完全转化为硝酸盐,而颗粒污泥仅将部分亚硝酸盐转化且过程比较缓慢。     

TiO2/硅藻土光催化氧化降解甲基橙的研究

使用经过预处理的硅藻土做载体,采用溶胶-凝胶法制备硅藻土负载二氧化钛光催化剂,利用XRD和EDS对其进行表征.通过分析光催化反应的主要影响因素,研究了硅藻土负载二氧化钛光催化剂对甲基橙的催化降解效果.结果表明：负载3次,在550℃焙烧2h,制备出的负载型催化剂催化活性较高,催化剂上的TiO2为锐钛矿结构.当催化剂投加量为lg/L,溶液初始浓度为15 mg/L,pH为3,H2O2为2 mmol/L时,对甲基橙的降解效果达到最佳.     

崂山水库的浮游植物群落特征及变化研究

2007年-2011年连续5年,采用生物群落法,对崂山水库浮游植物的群落结构进行了监测分析.结果为：2011年崂山水库共检出浮游植物8门93种,库区优势种为尖针杆藻（S.acus）、小胶鞘藻（P.tenue）、卵形隐藻（Cryptomonas ovata）、尖尾蓝隐藻（Chroomonas acuta）.5年来群落结构相对稳定,浮游植物细胞密度呈上升趋势.库区为B-中污型水体.     

Two-step accelerated mineral carbonation and decomposition analysis for the reduction of CO2 emission in the eco-industrial parks

Carbon dioxide（CO2） emissions are a leading contributor to the negative effects of global warming. Globally, research has focused on effective means of reducing and mitigating CO2 emissions. In this study, we examined the efficacy of eco-industrial parks（EIPs） and accelerated mineral carbonation techniques in reducing CO2 emissions in South Korea.First, we used Logarithmic Mean Divisia Index（LMDI） analysis to determine the trends in carbon production and mitigation at the existing EIPs. We found that, although CO2 was generated as byproducts and wastes of production at these EIPs, improved energy intensity effects occurred at all EIPs, and we strongly believe that EIPs are a strong alternative to traditional industrial complexes for reducing net carbon emissions. We also examined the optimal conditions for using accelerated mineral carbonation to dispose of hazardous fly ash produced through the incineration of municipal solid wastes at these EIPs. We determined that this technique most efficiently sequestered CO2 when micro-bubbling, low flow rate inlet gas, and ammonia additives were employed.     

蓝藻预警监测数据管理系统开发与应用研究

太湖蓝藻预警监测一直是政府及环保部门关注的重点工作并已经成为日常监测任务,但由于数据汇总和日统计评价工作量大,每项指标评判靠人工处理效率明显低下,蓝藻预警监测数据管理系统的开发很好的解决了这一问题.该系统以蓝藻监测和上报的实际业务需求为基础,综合了地表水各项指标的评价功能,并运用网络平台方便灵活地与其他部门共享蓝藻监测信息,极大地提高了综合分析人员工作效率,同时还为环境管理部门提供了更加全面的趋势分析.