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481.
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484.
BaO/γ-Al2O3同时吸附脱除一氧化氮和二氧化硫 总被引:1,自引:0,他引:1
利用固定床连续流动反应器研究了BaO/γ—Al2O,同时吸附模拟烟气中NO和SO2的工艺条件和再生循环使用性能,对BaO/γ—Al2O3进行了比表面积和程序升温表面反应(TPSR)等表征分析。结果表明,BaO/γ—Al2O3的适宜工艺条件是SO2与NO体积比为2.9~8.4、原料气中O2体积分数大于4.5%、吸附温度448~523K。BaO/γ—Al2O3在循环使用过程中吸附能力下降。与NOXSO吸附催化剂Na2CO3/γ—Al2O3相比,BaO/γ-Al2O3同时吸附SO2和NO的能力大、再生循环使用性能好、适宜的SO2与NO体积比范围宽、热稳定性好。将BaO/γ—Al2O3应用于NOXSO工艺可望提高该工艺的脱硫、脱氮效率。 相似文献
485.
采用微波消解-光度法处理钻井液废水中的总铬。该方法克服了常规消解方法的缺点,测定步骤简单、快速,准确性高。通过实验探讨了微波功率、加热时间、样品体积对样品消解的影响。与常压的硫酸-硝酸消解法进行比较的结果表明,用微波消解-光度法处理泥浆废水可将消解时间由原来的6h缩短为20min,加标回收率由60%提高到92%,降低了工作强度,改善了工作环境。 相似文献
486.
采用改性活性炭粉末对用纯净水加氟化钠配制而成的含氟水溶液进行动态电吸附去除实验.研究不同电压、电吸附时间,以及Cl-和SO2-4对氟离子去除的影响,并探讨吸附动力学和吸附方程.实验结果表明:活性炭对氟离子的吸附等温方程符合Freundlich方程,吸附动力学符合一级动力学方程;活性炭对氟离子去除与所施加的电位、吸附时间等因素有关,施加的电位越大,去除效果越好;随着吸附去除时间的延长,氟离子浓度下降趋缓;Cl-对氟离子去除影响很小,而SO2-4对氟离子去除有显著的不利影响. 相似文献
487.
Removal of selenate from water by zerovalent iron 总被引:1,自引:0,他引:1
Zerovalent iron (ZVI) has been widely used in the removal of environmental contaminants from water. In this study, ZVI was used to remove selenate [Se(VI)] at a level of 1000 microg L(-1) in the presence of varying concentrations of Cl-, SO(2-)4, NO(-)3, HCO(-)3, and PO(3-)4. Results showed that Se(VI) was rapidly removed during the corrosion of ZVI to iron oxyhydroxides (Fe(OH)). During the 16 h of the experiments, 100 and 56% of the added Se(VI) was removed in 10 mM Cl- and SO(2-)4 solutions under a closed contained system, respectively. Under an open condition, 100 and 93% of the added Se(VI) were removed in the Cl- and SO(2-)4 solutions, respectively. Analysis of Se species in ZVI-Fe(OH) revealed that selenite [Se(IV)] and nonextractable Se increased during the first 2 to 4 h of reaction, with a decrease of Se(VI) in the Cl- experiment and no detection of Se(VI) in the SO(2-)4 experiment. Two mechanisms can be attributed to the rapid removal of Se(VI) from the solutions. One is the reduction of Se(VI) to Se(IV), followed by rapid adsorption of Se(IV) to Fe(OH). The other is the adsorption of Se(VI) directly to Fe(OH), followed by its reduction to Se(IV). The results also show that there was little effect on Se(VI) removal in the presence of Cl- (5, 50, and 100 mM), NO(-)3 (1, 5, and 10 mM), SO(2-)4 (5 mM), HCO(-)3 (1 and 5 mM), or PO(3-)4 (1 mM) and only a slight effect in the presence of SO(2-)4 (50 and 100 mM), HCO(-)3 (10 mM), and PO(3-)4 (5 mM) during a 2-d experiment, whereas 10 mM PO(3-)4 significantly inhibited Se(VI) removal. This work suggests that ZVI may be an effective agent to remove Se from Se-contaminated agricultural drainage water. 相似文献
488.
Status and fuzzy comprehensive assessment of combined heavy metal and organo-chlorine pesticide pollution in the Taihu Lake region of China 总被引:13,自引:0,他引:13
The status of combined heavy metal and organo-chlorine pesticide (OCPs; i.e. HCH and DDT) pollution was investigated and the soil environmental quality of the Taihu Lake watershed, one of the most developed regions in China, was evaluated using a fuzzy comprehensive assessment. Statistical analyses showed the presence of combined pollution in the soil. At many sampling sites, heavy metal concentrations were above corresponding background values, indicating the effects of extraneous pollutants. It has been over 20 years since China banned the use of OCPs, but they can still be found in soil samples of this region. HCH levels at all investigated sites were below the Chinese Environmental Quality Standard for Soils. Fuzzy comprehensive assessment showed that the overall soil quality in this region could be categorized as class I. Nevertheless, the high coefficients of variation for levels of DDT, Cd and Hg indicated the existence of some point-source pollution. Continuous monitoring and further studies of the region are recommended to prevent pollution of farmland from these sources. 相似文献
489.
Liu Sinuo Lei Yin Zhao Jinsong Yu Shuxia Wang Ling 《Environmental science and pollution research international》2021,28(3):2995-3007
Environmental Science and Pollution Research - Water conservation and soil retention are two essential regulating services that are closely related, and their relationship might produce synergies... 相似文献
490.
Jiade Wang Binxun Hong Xinyang Tong Shufeng Qiu 《Journal of the Air & Waste Management Association (1995)》2016,66(12):1268-1275
The process of recovering waste sulfuric acids using H2O2 catalytic oxidation is studied in this paper. Activated carbon was used as catalyst. Main operating parameters, such as temperature, feed rate of H2O2, and catalyst dosage, have effects on the removal of impurities from waste sulfuric acids. The reaction kinetics of H2O2 catalytic oxidation on impurities are discussed. At a temperature of 90°C, H2O2 feeding rate of 50 g (kg waste acid)?1 per hour, and catalyst dosage of 0.2 wt% (waste acid weight), the removal efficiencies of COD and chrominance were both more than 99%, the recovery ratio of sulfuric acid was more than 95%, and the utilization ratio of H2O2 was 88.57%.Implications: Waste sulfuric acid is a big environmental problem in China. The amount of waste sulfuric acid is huge every year. Many small and medium-sized businesses produced lots of waste acids, but they don’t have an appropriate method to treat and recover them. H2O2 catalytic oxidation has been used to treat and recover waste sulfuric acid and activated carbon is the catalyst here. Main parameters, such as temperature, feed rate of H2O2, and catalyst dosage, have been investigated. The reaction kinetics are discussed. This method can be economical and feasible for most small and medium-sized businesses. 相似文献