Adsorption selectivity of salicylic acid and 5-sulfosalicylic acid onto hypercrosslinked polymeric adsorbents

Both bottle-point and column-feeding experiments involving different solutes and sorbents were carried out to investigate the adsorption selectivity and separation performance of salicylic acid and 5-sulfosalicylic acid. Their adsorption isotherms onto such hypercrosslinked polymeric adsorbents as NDA-100 and NDA-99 could be well described by the Freundlich equations whose characteristics describe extrathermic and favorable adsorption processes. The adsorption towards NDA-100 mainly depended on the π-π interaction, while that towards NDA-99 was extremely influenced by the static-electric interaction. Additionally, the adsorptive capacity of salicylic acid on NDA-99 decreased while it increased on NDA-100 with the presence of 5-sulfosalicylic acid in the adsorptive environment as the competitive component. Comparatively, the adsorption capacity of 5-sulfosalicylic acid decreased on both resins with salicylic acid as the competitive component. In fact, the difference in the interaction between adsorbent and adsorbate resulted in the straight antagonism on the effective adsorption sites on the adsorbent. In conclusion, the adsorption selectivity of salicylic acid onto NDA-100 was obviously larger than that onto NDA-99 with the existence of 5-sulfosalicylic acid in the adsorptive environment. A satisfactory separation and recovery of tested solutes in aqueous phase could be foreseeably achieved by the sequencing adsorption technique involving NDA-100 as well as NDA-99. Translated from Environmental Pollution & Control, 2005, 27(8): 570–574 [译自: 环境污染与防治]     

微生物法治理Cr(Ⅵ)污染的研究应用现状与展望

对传统方法与微生物法治理C(rⅥ)污染进行了比较,总结了微生物法的优点;其次,介绍了目前为止已成功筛选出的对Cr(Ⅵ)有解毒作用的细菌、真菌及其在国内外的研究应用现状;最后,总结了微生物治理C(rⅥ)污染的机理并指出此法存在的不足,展望了此法今后的发展方向。     

国内河流水污染现状及防治对策的探讨

对水环境造成的危害进行了论述，分析认为：城市河流污染形势严重。14个大中型城市河段中，63．8％的河段污染较重，为Ⅳ类至劣于Ⅴ类水质。在47个环保重点河段中，29．8％为类于Ⅴ类水质。文中提出了河流水环境污染治理对策。     

多种染料的微生物脱色研究

从印染、毛纺等废水处理场的生物膜和活性污泥中分离到13株对36种染料有脱色能力的细菌。其中三株转化单胞菌D_(32),D_(33),D_4分别对29种染料有良好的脱色作用,其完整细胞对单一染料的脱色活力达2.6mg·g~(-1)(细胞湿重)·h~(-1)。对脱色反应的条件和机理进行了初探。     

与玢岩铁矿有关的两类蚀变再认识

长江下游陆相火山岩地区分布着规模巨大的玢岩铁矿及其有关蚀变岩石,铁矿形成后普遍受到古风化淋滤和剥蚀作用的影响,并在浸蚀面上堆积的火山碎屑岩层的底部,发育有含铁矿石和蚀变岩石角砾的碎屑岩层。在此基础上又生成一套直接受火山作用控制的蚀变,称为火山蚀变,它在火山碎屑岩中分布很广泛,其中有黄铁矿化、黄铜矿化、明矾石化、硬石膏化、叶腊石化、硅化、高岭土化和水云母化等。上述两类蚀变是不同时期不同地质作用的结果,在成因上没有直接关系。     

清洁生产实现形式的研究

针对世界范围的清洁生产实践，通过多角度考察，文章提出了实现清洁生产的５种形式：（１）企业自觉开展清洁生产；（２）在国际公约约束下实现清洁生产；（３）清洁生产示范点；（４）企业发展中实现清洁生产；（５）政府对清洁生产的推动。     

中国东南沿海中生代火山作用基本特征

中国东南沿海自晚侏罗世到白垩纪火山活动分为二期、四个旋回,在空间上有迁移性,在时间上与侵入活动呈交替式演变。建立火山碎屑流等五种岩相模式,岩浆爆发占主导地位,同时存在蒸气岩浆爆发。确定破火山口、火山穹隆和锥火山为火山构造基本类型。由火山作用与区域构造作用、沉积作用控制形成火山沉积洼地、火山构造洼地和火山构造隆起。提出不同类型火山构造组合形式和相互演化关系。火山岩系列属高钾钙碱系列,晚期则具双模式性质。它们的地球化学型式兼具大陆边缘和大陆板内双重特性。     

离子强度、pH值和Ca2+/Al3+对马尾松幼苗的铝毒影响

测定了在不同溶液酸度、不同离子强度和Ca~(2+)/Al~(3+)比下,铝对马尾松幼苗生长状况的影响。结果表明,溶液酸度增加,离子强度减小时,铝的毒害作用增大。钙对铝毒有明显缓解作用,当Ca~(2+)/Al~(3+)增大时,铝的毒性减小,但其缓解作用与铝浓度有关,当铝浓度增加,钙的缓解能力下降。     

钱塘地区早石炭世地层和植物群

本文主要论述钱塘地区早石炭世地层和植物群。将早石炭世地层中产的植物化石分为三个组合:1.Lepidodendropsis hirmeri,Bothrodendron fuyangense组合.时代为晚泥盆世至早石炭世早期,笔者认为它是Lept ophloeum rhombicum Sublepi-dodendron mirabile组合与Lepidodendron gaolishanense Eolepidodeudraou spp.Sublepidodendron mirnbile组合之间一个过渡型组合。2.Anisopteris cf.transitionis- Archaeocalamites scrobieulatus组合。它与湘中测水组植物群为代表的韦宪中期Cardiopteridium spet sbergense-Triphyllopteris collombicum组合或C.spet sber-gense-Adiantitea gothanii组合对比。时代为早石炭世韦宪期或我国的大塘阶。3.Neuropteris schlehani f.rectinervis-Mariopteris acuta f.obtusa组合。它与江西梓山群佛岭组、广东测水组上段和忠信组中段的Archaeopteridium-Sphenopterisobtusiloba组合相当,时代为早石炭世韦宪晚期。