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71.
Donald Ward Jr. Thomas Gentile Henry Felton 《Journal of the Air & Waste Management Association (1995)》2019,69(8):956-966
The United States Environmental Protection Agency (EPA) reduced their National Ambient Air Quality Standard (NAAQS) for lead (Pb) an order of magnitude to a concentration level of 0.15 micrograms per cubic meter (µg/m3) when the new rule was promulgated in 2008. At that time, the possibility of revising the Pb sampling method from total suspended particulate (TSP) to particulate matter less than or equal to 10 µm in diameter (PM10) was considered due to potential measurement bias of the Pb-TSP monitoring technique. The New York State Department of Environmental Conservation (NYSDEC) has been operating source-orientated colocated TSP and PM10 monitors documenting ambient air lead (Pb) concentrations since 2011 at a site adjacent to a secondary Pb smelter in Wallkill, New York. The colocated Wallkill data show a very strong correlation between the readings recorded by these two sampling techniques. After the range of the variability in the individual Pb-PM10/Pb-TSP ratios was reduced by using a 0.005 µg/m3 concentration cut point, because of the concerns about the measurements at low concentrations, an adjustment factor (AF) of 1.49 was calculated using the remaining data set. This AF can be used to estimate Pb-TSP concentrations from Pb-PM10 readings at this Wallkill source-orientated location. It was stated by the EPA that there is only a limited data set in situations where Pb-TSP and Pb-PM10 are colocated, especially for those sites considered to be source-oriented, so the analyses performed and summarized herein for the Wallkill colocated airborne Pb concentration data add to that limited data set.
Implications: These data analyses add to the limited data set in situations where Pb-TSP and Pb-PM10 are colocated to help refine the derivation of a site-specific adjustment factor for estimating TSP Pb concentrations from measured PM10 Pb concentrations. This could assist the EPA in transitioning away from the use of the Pb-TSP monitoring technique, with its indicated measurement bias, for the Pb NAAQS to the use of Pb-PM10 instead. An adjustment factor of 1.49 was calculated that could be used to estimate Pb-TSP concentrations from Pb-PM10 values collected around this source-orientated location. 相似文献
72.
Robert C. Ward 《Journal of the American Water Resources Association》1979,15(2):369-380
ABSTRACT: Regulatory water quality monitoring has evolved to the point where it is a rather complex system encompassing many monitoring purposes and involving many monitoring activities. Lack of a system's perspective of regulatory monitoring hinders the development of effective and efficient monitoring programs to support water quality management. In this paper the regulatory water quality monitoring system is examined in a total systems context. The purposes of regulatory monitoring are reviewed and categorized according to their legal evolution. The activities of regulatory monitoring are categorized and organized into a system which follows the flow of information through the monitoring program. The monitoring purposes and activities are combined to form a monitoring system matrix - a framework within which the total regulatory water quality monitoring system is defined. The matrix, by defining the regulatory monitoring system and clarifying many interactions within the system, provides a basis upon which a more thorough approach to managing, evaluating, and eventually optimizing regulatory monitoring can be developed. 相似文献
73.
Thomas C. Peterson Robert C. Ward 《Journal of the American Water Resources Association》1989,25(2):349-357
ABSTRACT: A bacterial transport model, developed to analyze bacterial translocation in coarse-grained soils, is presented. The complex governing equation is presented first, followed by analyses of each of the major processes influencing bacterial transport. These analyses suggest simplification of the governing equation is feasible when input data on specific processes are limited or unavailable. Model parameters, including bacterial die-off, bacterial distribution, input bacterial concentration, and saturated hydraulic conductivity, were randomly generated using a procedure known to produce either a normal or log-normal distribution of random numbers. Monte Carlo simulations were completed, and the resulting output was used to generate cumulative frequency distributions showing the probability of bacterial transport beyond various soil depths. Results from these simulations indicate that bacteria have a high probability of traveling through coarse-grained soils when low clay content and soil water temperatures limit bacterial retention and die-off. 相似文献
74.
Ward Lyles 《Journal of Environmental Planning and Management》2015,58(11):1961-1987
Broad stakeholder involvement cannot be assumed in all environmental planning and management processes that have critical land use dimensions. This paper illustrates how concepts and techniques from social network analysis (SNA) can be used to examine and better understand the roles of one type of stakeholders, planners, in environmentally oriented planning and management processes led by other professions. Two cases of natural hazard mitigation planning led by emergency managers illustrate the usefulness of three SNA concepts of network structural characteristics in understanding how differences in planner involvement may influence incorporation of land use approaches in local natural hazard mitigation plans aimed at reducing long term risks from natural hazards. 相似文献
75.
76.
Kamalakkannan R Zettel V Goubatchev A Stead-Dexter K Ward NI 《Journal of environmental monitoring : JEM》2004,6(3):175-181
Chemical (polycyclic aromatic hydrocarbon - PAH and heavy metal) levels in stormwater and sediment samples collected from the London Orbital (M25) motorway drainage dry detention pond at Oxted, Surrey, UK were determined. Such chemicals are derived from vehicular combustion products and the wear and tear materials deposited onto the motorway surface. Gas chromatography-mass spectrometry (GC-MS) was used for the qualitative and quantitative determination of 16 USEPA priority PAHs in motorway drainage sediments. The GC-MS method, incorporating a solid phase extraction step, provides detection limits ranging from 0.17 to 0.41 mg kg(-1)(dry weight). Almost all of the 16 USEPA listed PAHs were detected. Phenanthrene, fluoranthene, pyrene, benzo(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(a)pyrene and benzo(g,h,i)perylene (PAH numbers 5, 7, 8, 9, 10, 11, 13 and 16) were among the PAHs found at "higher" levels (ranging from 0.3-10.2 mg kg(-1), dry weight) in the sediment samples. PAH levels show little change along the motorway drainage silt trap (facility for reducing the levels of suspended particulate matter in the stormwater). PAH concentrations are considerably higher in the dry detention pond outflow interceptor. Statistical analysis showed that significant correlation coefficients (based on a t-test at the 95% confidence interval) were obtained between those PAHs found at high concentrations over all of the sampling sites. Several PAHs were dispersed beyond the treatment facility and accumulation in the sediment of the deer park resulted in levels ranging from 0.3-1.6 mg kg(-1), dry weight. These PAHs found beyond the treatment facility (in the local farm deer park) may contribute a serious health threat to farm animals or even fish in the aquatic environment. Heavy metal levels (V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Mo, Cd, Sb and Pb) of the drainage stormwater and sediments were determined by inductively coupled plasma mass spectrometry (ICP-MS), with quality control evaluation using two certified reference materials. Typical detection limits were found to be below 0.1 [micro sign]g l(-1) for stormwater and 0.005 mg kg(-1) for acid digested sediments. Raised heavy metal levels were found throughout the dry detention pond facility and only decrease when the stormwater is diluted following discharge into the river Eden. Statistical analysis also confirms that some significant correlations exist between various heavy metals and PAHs. However, no overall conclusive trend is found indicating that a particular PAH is deposited in sediment relative to a specific heavy metal/s. These results raise some serious concerns about the dispersion and accumulation of chemicals in the sediments of motorway stormwater drainage systems and the need for maintenance and clean-up of contaminated material from such systems. 相似文献
77.
Johansen MP Hakonson TE Whicker FW Breshears DD 《Journal of environmental quality》2003,32(6):2150-2157
Of the natural processes that concentrate dispersed environmental contaminants, landscape fire stands out as having potential to rapidly concentrate contaminants and accelerate their redistribution. This study used rainfall simulation methods to quantify changes in concentration of a widely dispersed environmental contaminant (global fallout 137Cs) in soils and surface water runoff following a major forest fire at Los Alamos, New Mexico, USA. The 137Cs concentrations at the ground surface increased up to 40 times higher in ash deposits and three times higher for the topmost 50 mm of soil compared with pre-fire soils. Average redistribution rates were about one order of magnitude greater for burned plots, 5.96 KBq ha(-1) mm(-1) rainfall, compared with unburned plots, 0.55 KBq ha(-1) mm(-1) rainfall. The greatest surface water transport of 137Cs, 11.6 KBq ha(-1) mm(-1), occurred at the plot with the greatest amount of ground cover removal (80% bare soil) following fire. Concentration increases of 137Cs occurred during surface water erosion, resulting in enrichment of 137Cs levels in sediments by factors of 1.4 to 2.9 compared with parent soils. The elevated concentrations in runoff declined rapidly with time and cumulative precipitation occurrence and approached pre-fire levels after approximately 240 mm of rainfall. Our results provide evidence of order-of-magnitude concentration increases of a fallout radionuclide as a result of forest fire and rapid transport of radionuclides following fire that may have important implications for a wide range of geophysical, ecosystem, fire management, and risk-based issues. 相似文献
78.
/ A watershed-based approach for screening-level assessment of nonpoint source pollution from inactive and abandoned metal mines was developed and illustrated. The methodology was designed to use limited stream discharge and chemical data from synoptic surveys to derive key information required for targeting impaired waterbodies and critical source areas for detailed investigation and remediation. The approach was formulated based on the required attributes of an assessment methodology, information goals for targeting, attributes of data that are typical of basins with inactive mines, and data analysis methods that were useful for the case study. The methodology is presented as steps in a framework including evaluation of existing data/information and identification of data gaps; definition of assessment information goals for targeting and monitoring design; data collection, management, and analysis; and information reporting and use for targeting. Information generated includes the type and extent of and critical conditions for water-quality impairment, concentrations in and loadings to streams, differences between concentrations in and loadings to streams, and risks of exceeding target concentrations and loadings. Data from the Cement Creek Basin, located in the San Juan Mountains of southwestern Colorado, USA, were used to help develop and illustrate application of the methodology. The required information was derived for Cement Creek and used for preliminary targeting of locations for detailed investigation and remediation. Application of the approach to Cement Creek was successful in terms of cost-effective generation of information and use for targeting.KEY WORDS: Water quality assessment; Nonpoint source pollution; Inactive mines; Watershed 相似文献
79.
Edward A. Ward 《组织行为杂志》1995,16(1):93-100
The degree to which two measures of locus of control (LOC) and two measures of need for achievement (NACH) correlate with the motivations of persons for competitive or cooperative strategy was measured in 191 graduate students who are employed full-time as salaried employees. Results indicated significant correlations between motivation for competitive strategies and LOC, NACH, and the factors of LOC entitled self-confidence, internality, and belief in chance. The motivation to avoid the use of competitive strategies was correlated with belief in control by powerful others and chance. The motivation to use cooperative strategies failed to correlate significantly with either NACH or LOC. 相似文献