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41.
The effectiveness of subcritical water extraction (SCWE) was examined for removing dioxins from contaminated soil. Most dioxins in the soil sample were reduced at 300 degrees C or more, but decreased dioxin concentrations were also observed at 150 degrees C. After 4 h of extraction, 99.4%, 94.5% and 60% of PCDDs were removed from samples at 350, 300 and 150 degrees C, respectively. It was also determined that degradation of dioxins had occurred, since the sum of dioxins in the soil plus water extracts after the experiments had considerably decreased. This study revealed that pressurizing is not essential for the removal of dioxins. Reduction was complete within 30 min at 350 degrees C; however, it took a much longer time at lower temperatures. The results of addition experiments in which OCDDs were added to different types of soil samples have shown that dechlorination is one of the major reaction pathways. After addition of OCDD to soil samples, experiments were carried out to examine in detail the degradation pathways of PCDDs. The removal rates and congener profiles varied among soil types. Although it was previously assumed that removal rates and congener profiles depended on the chemical components in soil, nonparametric statistical analysis revealed no significant relationship between the rate of reduction and elements present in the soil. It was confirmed from isomer patterns that dechlorination of the 2,3,7,8-positions in PCDDs takes place somewhat faster than for the 1,4,6,9-positions. 相似文献
42.
Nobuhisa Watanabe Shusuke Takemine Katsuya Yamamoto Yuki Haga Mitsuyasu Takata 《Journal of Material Cycles and Waste Management》2016,18(4):625-630
Perfluorooctanoic acid (PFOA), perfluorohexanoic acid (PFHxA) and perfluorooctane sulfonate (PFOS) adsorbed onto granular activated carbon (GAC) were thermally treated in N2 gas stream. The purpose was to assess the fate of perfluoroalkyl and polyfluoroalkyl substances (PFASs) during thermal regeneration of GAC, which had been used for water treatment. Mineralized F, residual PFASs including short-chained species, and volatile organic fluorine (VOF) were determined. In a temperature condition of 700 °C, VOF were 13.2, 4.8, and 5.9 % as for PFOA, PFHxA, and PFOS. However, the VOF decreased to 0.1 %, if the GAC and off-gas were kept at 1000 °C. No PFASs remained in GAC at 700–1000 °C; at the same time, short-chained PFASs were slightly detected in the aqueous trapping of off-gas at 800 and 900 °C conditions. The destruction of PFASs on GAC could be perfect if the temperature is higher than 700 °C; however, the process is competitive against volatile escape from GAC. Destruction in gaseous phase needs a temperature as high as 1000 °C. Destruction of PFASs on the surface of GAC, volatile escape from the site, and thermolysis in gas phase should be considered, as to thermal regeneration of GAC. 相似文献
43.
Congener profiles of PCDDs, PCDFs, and dioxin-like PCBs in the breast milk samples in Tokyo, Japan 总被引:1,自引:0,他引:1
Exposure to dioxins has raised much public concern recently. We determined the congeners' distribution of polychlorinated-dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and dioxin-like polychlorinated biphenyls (dl-PCBs) in the breast milk samples collected in Tokyo, Japan. Breast milk was taken from 240 mothers, 30 days after delivery in 1999 and 2000 in Tokyo, Japan. The actual concentration and TEQ concentration of PCDDs (14 congeners), PCDFs (15 congeners), and dl-PCBs (12 congeners), and each congener's contribution to the total TEQ level were calculated. Among all the samples, PCDDs accounted for 34.8%, PCDFs accounted for 23.5%, dl-PCBs accounted for 41.7%, which was also similar in the breast milk from the primiparae and secundiparae. The main contributors to the total TEQ with increasing percentages were 2,3,4,7,8-PeCDF, 1,2,3,7,8-PeCDD and 3,3',4,4',5-PCB (#126), and they accounted for more than 65% of the total TEQ. Detailed congener analysis in breast milk samples is effective to understand dioxin sources. 相似文献
44.
Formosan squirrels are considered a useful bio-indicator because their habitat exists within that of humans. Therefore, concentrations of 19 trace elements were determined in tissues of this species for assessment of environmental pollution in urban Kamakura and rural Izuohshima. Results of analyses revealed high Cu concentrations in the livers of Formosan squirrels. Moreover, concentrations of some trace elements from automobile exhausts-V, Zn, Cu and As-in the specimens from Kamakura were higher than those from Izuohshima. These results reflect the presence of pollution caused by human activities in Kamakura. 相似文献
45.
The integrated model is composed of two basic parts: one is a reaction rate model of biodegradation in combination with bioenergetics and the other is a thermal engineering model of energy flow and balance in the bioreactor. Integrating these models provides possibility to estimate microbial activity using time course of physicochemical parameters such as bed temperature, bed weight, and/or C02 concentration during decomposition. 相似文献
46.
Jian Pu Shinobu Kazama Takayuki Miura Nabila Dhyan Azraini Yoshimitsu Konta Hiroaki Ito You Ueki Ermaya Eka Cahyaningrum Tatsuo Omura Toru Watanabe 《Food and environmental virology》2016,8(4):310-312
Norovirus GII.3, GII.4, and GII.17 were detected using pyrosequencing in sewage and oysters in January and February 2015, in Japan. The strains in sewage and oyster samples were genetically identical or similar, predominant strains belonging to GII.17 Kawasaki 2014 lineage. This is the first report of GII.17 Kawasaki 2014 in oysters. 相似文献
47.
Tatsuro Nakaji Takuya Kobayashi Mihoko Kuroha Kumiko Omori Yuko Matsumoto Tetsushi Yonekura Katsuhiko Watanabe Jarkko Utriainen Takeshi Izuta 《Water, Air, & Soil Pollution: Focus》2004,4(2-3):277-287
To evaluate the effect of increasing nitrogen (N) deposition and tropospheric ozone (O3) concentrations on N-saturated forest ecosystems, we investigated the response of Japanese red pine (Pinus densiflora), an N-saturation sensitive tree species, to increasing N load under elevated O3 concentrations. One-year-old seedlings of red pine were treated with three levels of N supply (0, 50 and 100 mg N L-1 fresh soil volume) under two levels of atmospheric O3 concentration (< 5 and 60 ppb) for two growing seasons. Nitrogen treatment did not stimulate dry matter production of the seedlings. Growth inhibition was observed in the highest N treatment under low O3 and in the two higher N treatments under elevated O3. Irrespective of the O3 concentration, increasing N supply negatively affected root growth and mycorrhizal development in fine roots, resulting in a reduction in P and Mg uptake from the soil. Net photosynthetic rate was significantly reduced by both the highest N treatment under low O3 and the two higher N treatments under elevated O3, together with decreased N-availability to Rubisco. Nitrogen assimilated from NO3 - to amino acid in the needles was not affected by the treatments. However, needle protein concentration was reduced by the highest N-treatment under low O3 and by the two higher N-treatments under elevated O3. These results suggest that elevated O3 potentially disturbs the N-availability in the form of protein including Rubisco, and may advance the negative effects of excessive N-deposition on N-sensitive plant species in N-saturated forests. 相似文献
48.
A numerical simulation model of pesticide runoff through vegetative filer strips (PRVFS) was developed as a tool for investigating the effects of pesticide transport mechanisms on VFS design in dormant-sprayed orchard. The PRVFS model was developed applying existing theories such as kinematic wave theory and mixing zone theory for pesticide transport in the bare soil area. For VFS area, the model performs flow routing by simple mass accounting in sequential segments and the pesticide mass balance by considering pesticide washoff and adsorption processes on the leaf, vegetative litter, root zone and soil. Model sensitivity analysis indicated that pesticide transfer from surface soil to overland flow and pesticide washoff from the VFS were important mechanisms affecting diazinon transport. The VFS cover ratio and rainfall intensity can be important design parameters for controlling diazinon runoff using inter-row VFS in orchard. The PRVFS model was validated using micro-ecosystem simulation of diazinon transport for 0, 50 and 100% VFS cover conditions. The PRVFS model is shown to be a beneficial tool for evaluating and analyzing possible best management practices for controlling offsite runoff of dormant-sprayed diazinon in orchards during the rainy season. 相似文献
49.
Accumulation features of persistent organochlorines in resident and migratory birds from Asia 总被引:1,自引:0,他引:1
Kunisue T Watanabe M Subramanian A Sethuraman A Titenko AM Qui V Prudente M Tanabe S 《Environmental pollution (Barking, Essex : 1987)》2003,125(2):157-172
Concentrations of organochlorine contaminants including polychlorinated biphenyls (PCBs), dichlorodiphenyltrichloroethane and its metabolites (DDTs), hexachlorocyclohexane isomers (HCHs), chlordane compounds (CHLs), hexachlorobenzene (HCB) were determined in the resident and migratory birds, which were collected from India, Japan, Philippines, Russia (Lake Baikal) and Vietnam. Accumulation patterns of organochlorine concentrations in resident birds suggested that the predominant contaminants of each country were as follows: Japan--PCBs Philippines--PCBs and CHLs, India--HCHs and DDTs, Vietnam--DDTs, and Lake Baikal--PCBs and DDTs. The migratory birds from Philippines and Vietnam retained mostly the highest concentrations of DDTs among the organochlorines analyzed, indicating the presence of stopover and breeding grounds of those birds in China and Russia. On the other hand, migratory birds from India and Lake Baikal showed different patterns of organochlorine residues, reflecting that each species has inherent migratory routes and thus has exposure to different contaminants. Species which have breeding grounds around the Red Sea and Persian Gulf showed high levels of PCBs, indicating the presence of areas heavily polluted by PCBs in the Middle East. 相似文献
50.
The water flea Daphnia magna reproduces primarily by cyclic parthenogenesis. Environmental stimuli that signal a change to adverse conditions induce the organisms to switch from parthenogenesis to gamogenetic reproduction. During the gamogenetic period, they produce male daphnids and dormant resting eggs, which can survive prolonged periods of environmental adversity. However, little is known about the mechanisms associated with the switch from parthenogenesis to gamogenetic reproduction. We investigated the effects of several juvenoids on sex determination in Daphnia. Females less than 24 h old were exposed to various concentrations of the test substance and were observed for 21 days. It was found that they can trigger the appearance of male daphnids: the percentage of males in the population increases to a level greater than what occurs under ordinary environmental conditions. We found that methylfarnesoate, juvenile hormone III, methoprene, and the phenoxyphenoxy derivatives pyriproxyfen and fenoxycarb (both insecticides) reduced the production of offspring and produced sex ratios dominated by male daphnids. Pyriproxyfen and fenoxycarb showed striking effects at low concentrations. Exposure to either of these chemicals at a concentration of 330 ngl(-1) caused adult females to produce almost all male neonates. Methylfarnesoate, juvenile hormone III, and methoprene showed an effect in inducing male production at higher concentrations (3.7 x 10(3), 3.3 x 10(5), and 1.3 x 10(5) ngl(-1), respectively). Our findings suggest that juvenile hormone agonists, including some insecticides, affect the chemical signaling responsible for inducing the production of male offspring. 相似文献