Occurrence and fate of steroid estrogens in the largest wastewater treatment plant in Beijing, China

Concern over steroid estrogens has increased rapidly in recent years due to their adverse health effects. Effluent discharge from wastewater treatment plants (WWTPs) is the main pollutant source for environmental water. To understand the pollutant level and fate of steroid estrogens in WWTPs, the occurrence of estrone (E1), 17-β-estradiol (E2), estriol (E3), and 17-β-ethinylestradiol (EE2) was investigated in the Gaobeidian WWTP in Beijing, China. Water samples from influent as well as effluent from second sedimentation tanks and advanced treatment processes were taken monthly during 2006 to 2007. In influent, steroid estrogen concentrations varied from 11.6 to 1.1?×?10(2)?ng/l, 3.7 to 1.4?×?10(2)?ng/l, no detection (nd) to 7.6×10(2)?ng/l and nd to 3.3?×?10(2)?ng/l for E1, E2, E3, and EE2, respectively. Compared with documented values, the higher steroid estrogen concentrations in the WWTP influent may be due to higher population density, higher birthrate, less dilution, and different sampling time. Results revealed that a municipal WWTP with an activated sludge system incorporating anaerobic, anoxic, and aerobic processes could eliminate natural and synthetic estrogens effectively. The mean elimination efficiencies were 83.2%, 96.4%, 98.8%, and 93.0% for E1, E2, E3, and EE2, respectively. The major removal mechanism for natural estrogens and synthetic estrogen EE2 were biodegradation and sorption on the basis of mass balance in water, suspension particles, and sludge. In the WWTP effluent, however, the highest concentrations of E1, E2, E3, and EE2 attained were 74.2, 3.9, 5.1, and 4.6?ng/l, respectively. This is concerning as residual steroid estrogens in WWTP effluent could lead to pollution of the receiving water. Advanced flocculation treatment was applied in the WWTP and transformed the residual estrogen conjugates to free species, which were reduced further by filtration with removal shifting from 32% to 57% for natural estrogen, although no EE2 was removed.     

铅冶炼区土壤重金属总量和有效态含量的函数分析

采集铅冶炼企业周边3 000 m范围内220个表层土壤样品,测定了有毒有害元素铅、镉、砷和汞的总量和有效态含量,探讨了它们之间的关系。结果表明:研究区土壤受到汞、砷、铅、镉的污染依次明显严重,土壤重金属的总量和有效态含量的变异系数均大于100%,土壤镉、铅、汞、砷的生物有效性系数平均值分别为25.9%、17.2%、0.58%、0.11%。土壤铅、镉和砷的总量与其有效态含量呈显著正相关(P0.001),而汞的总量与其有效态含量的相关性不显著(P0.05)。土壤铅和镉的总量和有效态含量可以用直线函数和幂函数表达,函数反推的有效态值和对应统计值的变异系数不大于10%。     

Quality assessment of groundwater from the south-eastern Arabian Peninsula

Assessment of groundwater quality plays a significant role in the utilization of the scarce water resources globally and especially in arid regions. The increasing abstraction together with man-made contamination and seawater intrusion have strongly affected groundwater quality in the Arabia Peninsula, exemplified by the investigation given here from the United Arab Emirates, where the groundwater is seldom reviewed and assessed. In the aim of assessing current groundwater quality, we here present a comparison of chemical data linked to aquifers types. The results reveal that most of the investigated groundwater is not suitable for drinking, household, and agricultural purposes following the WHO permissible limits. Aquifer composition and climate have vital control on the water quality, with the carbonate aquifers contain the least potable water compared to the ophiolites and Quaternary clastics. Seawater intrusion along coastal regions has deteriorated the water quality and the phenomenon may become more intensive with future warming climate and rising sea level.     

Seasonal variation of polycyclic aromatic hydrocarbons in soil and air of Dalian areas, China: an assessment of soil-air exchange

The seasonal variations of concentrations of PAHs in the soil and the air were measured in urban and rural region of Dalian, China in 2007. In soil, mean concentrations of all PAHs in summer were larger than those in winter, whereas the concentrations of heavier weight PAHs in winter were larger than those in summer. Winter/summer concentration ratios for individual PAHs (R(W/S)) increased with the increase of molecular weight of PAHs in soil, indicating that PAHs with high molecular weight were more easily deposited to soil in winter than summer. In air, mean concentrations of all PAHs in winter were larger than those in summer. In comparison with the R(W/S) in soil, all the values of R(W/S) in air were larger than one indicating that the entire individual PAH concentrations in winter were larger than those in summer. The average concentration composition for each PAH compound in soil and air samples was determined and the seasonal change of PAH profile was very small. It was suggested that PAHs in soils and air had the same or similar sources both in winter and summer. The approach to the soil-air equilibrium was assessed by calculating fugacity quotients between soil and air using the soil and air concentrations. The calculated soil-air fugacity quotients indicated that soil acted as a secondary source to the atmosphere for all lighter weight PAHs (two-three rings) and it will continue to be a sink for heavier weight PAHs (five-six rings) in the Dalian environment, both in winter and summer. Medium weight PAHs (four-five rings) were close to the soil-air equilibrium and the tendency shifted between soil and air when season or function region changed. The fugacity quotients of PAHs in summer (mean temperature 298 K) were larger than those in winter (mean temperature 273 K), indicating a higher tendency in summer than winter for PAHs to move from soil to air. The variation of ambient conditions such as temperature, rainfall, etc. can influence the movement of PAHs between soil and air. Most of the fugacity quotients of PAHs for the urban sites were larger than that for the rural site both in winter and summer. This phenomenon may be related with that the temperatures in urban sites were higher than those in the rural site because of the urban heat island effect.     

Understanding the Price Dynamics in the Jiangsu SO2 Emissions Trading Program in China: A Multiple Periods Analysis

Because emissions permits can be considered to be a pseudo-commodity, the permit price in the emissions trading markets has already attracted great interest from the economic literature. This research took the Jiangsu sulfur dioxide (SO₂) emissions trading program in China as a case study to examine the price dynamics over the next 10 years (2011–2020) based on Jiangsu’s new SO₂ emissions trading policy design. An adaptive agent-based simulation model was developed to estimate the price dynamics as well as the impact of energy price, policy design, and new environmental regulation on the permit price. The results showed that the equilibrium price of the Jiangsu SO₂ emissions trading market is approximately 4.20 CNY/kg, and the permit price will fluctuate around this price if the other conditions are not changed. If the coal price increases during 2011–2016, the permit price will decline to 2.79 CNY/kg by 2020 under China’s current coal–electricity price mechanism. In addition, the banking mechanism will smooth the price fluctuations and the average permit price will be generally higher when banking is not allowed. Finally, the stricter environmental regulation will reduce the market supply of permits and will raise the permit price. According to China’s potential new SO₂ discharge standard, the permit price will jump to 11 CNY/kg. The quantification of the permit price dynamics can help power plants to make decisions on emissions trading.     

Dissipation and residue of triforine in strawberry and soil

Two independent field trials were performed in Guangdong and Hubei, China in 2011 to investigate the dissipation and residue levels of triforine in strawberry and soil. A fast and simple method using gas chromatography with electron capture detector was developed and validated to determine triforine levels in strawberry and soil. The average recovery of triforine in strawberry ranged from 87.46 to 104.32 % with a relative standard deviation (RSD) of 0.72 to 4.54 %; that in soil ranged from 83.82 to 103.01 % with an RSD of 3.89 to 4.36 %. The limit of quantification of the proposed method was 0.01 mg/kg for both strawberry and soil. The results suggest that the triforine dissipation curves followed the first-order kinetic. The half-lives of triforine in strawberry from Guangdong and Hubei were 3.58 and 4.42 days, respectively; those in soil were 3.53 and 4.10 days, respectively. The terminal residues of triforine in strawberry ranged from 0.032 to 0.264 mg/kg at preharvest intervals of 0.5, 1, and 3 days. These values are lower than the maximum residue limit of 1 mg/kg in strawberry set by the Codex Alimentarius Commission.     

Stabilization of heavy metals in MSWI fly ash using silica fume

The objective of this work was to investigate the feasibility and effectiveness of silica fume on stabilizing heavy metals in municipal solid waste incineration (MSWI) fly ash. In addition to compressive strength measurements, hydrated pastes were characterized by X-ray diffraction (XRD), thermal-analyses (DTA/TG), and MAS NMR (²⁷Al and ²⁹Si) techniques. It was found that silica fume additions could effectively reduce the leaching of toxic heavy metals. At the addition of 20% silica fume, leaching concentrations for Cu, Pb and Zn of the hydrated paste cured for 7 days decreased from 0.32 mg/L to 0.05 mg/L, 40.99 mg/L to 4.40 mg/L, and 6.96 mg/L to 0.21 mg/L compared with the MSWI fly ash. After curing for 135 days, Cd and Pb in the leachates were not detected, while Cu and Zn concentrations decreased to 0.02 mg/L and 0.03 mg/L. The speciation of Pb and Cd by the modified version of the European Community Bureau of Reference (BCR) extractions showed that these metals converted into more stable state in hydrated pastes of MSWI fly ash in the presence of silica fume. Although exchangeable and weak-acid soluble fractions of Cu and Zn increased with hydration time, silica fume addition of 10% can satisfy the requirement of detoxification for heavy metals investigated in terms of the identification standard of hazardous waste of China.     

Characterization of a fenpropathrin-degrading strain and construction of a genetically engineered microorganism for simultaneous degradation of methyl parathion and fenpropathrin

A gram-negative fenpropathrin-degrading bacterial strain Sphingobium sp. JQL4-5 was isolated from the wastewater treatment sludge of an insecticide factory. Strain JQL4-5 showed the ability to degrade other pyrethroid insecticides, but it was not able to degrade methyl parathion. To enhance its degrading range of substrate, a methyl parathion hydrolase gene (mpd) was successfully introduced into the chromosome of strain JQL4-5 with a mini-Tn-transposon system. A genetically engineered microorganism (GEM) named JQL4-5-mpd resulted, which was capable of simultaneously degrading methyl parathion and fenpropathrin. Soil treatment results indicated that JQL4-5-mpd is a promising multifunctional bacterium in the bioremediation of multiple pesticide-contaminated environments.     

Crystallization and Mechanical Properties of Recycled Poly(ethylene terephthalate) Toughened by Styrene–Ethylene/Butylenes–Styrene Elastomer

Recycled poly(ethylene terephthalate) (R-PET) was blended with 15–30 wt% of styrene–ethylene/butylenes–styrene (SEBS) block copolymer and maleic anhydride grafted SEBS (SEBS-g-MA). Effects of nucleation and toughening of the elastomers were evaluated systematically by study of morphology, crystallization, thermal and mechanical properties of the blend. The addition of 30 wt% SEBS promoted the formation of co-continuous structure of the blend and caused the fracture mechanism to change from strain softening to strain hardening. Addition of SEBS-g-MA resulted in significant modification of phase morphology and obviously improved the impact strength. The compatibilization reaction of PET with SEBS-g-MA accelerated the crystallization of PET and increased the crystallinity. The shifts in glass transition temperature of PET towards that of SEBS-g-MA and the higher modulus for R-PET/SEBS-g-MA (70/30) blend found by DMA are also indications of better interactions under the conditions of compatibilization and interpenetrating structure.     

立式加热炉节能减排可行性研究

大庆油田原稳装置采用立式加热炉,烟气中存在大量的废热。在现有装置运行中,烟气直接排放,浪费了大量的热量。通过在实验装置中可回收废热资源及废热回收技术研究,采用热管技术回收烟气废热,用于预热空气,不仅会节能降耗,给企业创造可观的经济效益,还会减少大气污染,创造良好的社会效益。