2种反应器中好氧颗粒污泥培养的比较研究

以絮状活性污泥为接种污泥,采用人工配制的模拟生活污水,分别在气提式序批反应器(SBAR)和序批式活性污泥反应器(SBR)中成功地培养出了成熟的好氧颗粒污泥.SBAR和SBR中的好氧颗粒污泥都具有稳定的基本形态结构,其微生物主要由杆菌和球菌组成,对COD的去除率可达到93%左右.对NH+4-N的去除率可达到98%以上.SBAR中好氧颗粒污泥的粒径主要分布、污泥体积指数(SVI)、比耗氧速率(SOUR)、TN去除率和TP去除率分别为0.45～2.00 mm、19.97 mL/g、47.68 g/(kg·h)、82%和65%;而SBR中好氧颗粒污泥的粒径主要分布、SVI、SOUR、TN去除率和TP去除率分别为0.18～1.00 mm、29.12 mL/g、43.21 g/(kg·h)、58%和50%.相对而言,SBAR更有利于好氧颗粒污泥的培养和运行.     

负载TiO2浮石对污水处理厂二沉池出水的矿化与灭菌研究

城市污水处理厂第二沉淀池出水的污染物浓度较低,经过矿化及灭菌等深度处理后可以回用,从而减轻对淡水资源的需求。本实验采用溶胶-凝胶法制备了负载TiO2的浮石光催化剂,对城市污水处理厂第二沉淀池出水进行了矿化及灭菌处理研究。采用低压汞灯对处理水样照射2h,有机物降解率可以达到50％,灭菌效率达到100％。处理后的水可以作为农作物灌溉、城市绿化和娱乐用水。负载在浮石表面的TiO2薄膜经过10次的光催化循环实验后,没有明显破损,可以再次循环使用。TiO2浮石具有质轻、机械性能好和价格低等优点,该方法处理废水的适用浓度低,可以广泛应用于微污染水和城市污水处理厂出水的深度处理。     

Carbon isotope analysis for source identification of atmospheric formaldehyde and acetaldehyde in Dinghushan Biosphere Reserve in South China

Formaldehyde and acetaldehyde are two most abundant carbonyls in ambient air. Biogenic emission has been proposed as a significant source other than anthropogenic emissions and atmospheric secondary formation. Here at a forest site in South China, the carbon isotopic compositions of formaldehyde and acetaldehyde emitted from leaves of three tree species (Litsea rotundifolia, Canarium album and Castanea henryi) were measured in comparison with the bulk carbon isotopic compositions of tree leaves. δ¹³C data of the emitted aldehydes (from ?31‰ to ?46‰) were quite different for tree species, which were all more depleted in ¹³C than the tree-leaf bulk δ¹³C values (from ?27‰ to ?32‰). Formaldehyde in ambient air at the forest site had δ¹³C values different from those of leaf-emitted formaldehyde, indicating other sources for ambient formaldehyde apart from direct emission from leaves, most probably the photooxidation of biogenic hydrocarbon like isoprene and monoterpene. The δ¹³C differences of acetaldehyde between ambient data and those of tree leaves emission were less than 1‰, implying direct biogenic emission as the dominant source.     

An important pathway for ozonolysis of alpha-pinene and beta-pinene in aqueous phase and its atmospheric implications

The aqueous ozonolysis of α-pinene and β-pinene was conducted under simulated tropospheric conditions at different pHs and temperatures. Three kinds of products, peroxides, carbonyl compounds, and organic acids, were well characterized, and the detection of these products provides effective evidence for understanding the atmospheric aqueous reaction pathway. We have two interesting findings: (1) the unexpected formation of methacrolein (MACR), with a yield of ～40%, in the α-pinene–O₃ aqueous reaction indicates a potentially new SOA formation pathway, because MACR is one of the important precursors of SOA; and (2) the surprisingly high yields of H₂O₂, ～60% for the α-pinene–O₃ reaction and ～100% for the β-pinene–O₃ reaction, indicates that H₂O₂ can be a significant contributor to the origin and transformation of oxidants in the atmosphere, especially in the humid regions. Moreover, we have determined the rate constant for aqueous reaction between MACR and H₂O₂ in pH 2 to 7 and obtained its upper limit as 0.13 M L^?1 s^?1. A mechanism concerning the formation of the species mentioned above is proposed, and it differs from that in the gas-phase reaction. We suggest that water plays a key role in the mechanism, by participating in the reactions as a direct reactant and by removing the excess energy of intermediates formed in the reactions.     

Concentrations of volatile organic compounds,carbon monoxide,carbon dioxide and particulate matter in buses on highways in Taiwan

Although airborne pollutants in urban buses have been studied in many cities globally, long-distance buses running mainly on highways have not been addressed in this regard. This study investigates the levels of volatile organic compounds (VOCs), carbon monoxide (CO), carbon dioxide (CO₂) and particulate matter (PM) in the long-distance buses in Taiwan. Analytical results indicate that pollutants levels in long-distance buses are generally lower than those in urban buses. This finding is attributable to the driving speed and patterns of long-distance buses, as well as the meteorological and geographical features of the highway surroundings. The levels of benzene, toluene, ethylbenzene and xylene (BTEX) found in bus cabins exceed the proposed indoor VOC guidelines for aromatic compounds, and are likely attributable to the interior trim in the cabins. The overall average CO level is 2.3 ppm, with higher average level on local streets (2.9 ppm) than on highways (2.2 ppm). The average CO₂ level is 1493 ppm, which is higher than the guideline for non-industrial occupied settings. The average PM level in this study is lower than those in urban buses and IAQ guidelines set by Taiwan EPA. However, the average PM₁₀ and PM_2.5 is higher than the level set by WHO. Besides the probable causes mentioned above, fewer passenger movements and less particle re-suspension from bus floor might also cause the lower PM levels. Measurements of particle size distribution reveal that more than 75% of particles are in submicron and smaller sizes. These particles may come from the infiltration from the outdoor air. This study concludes that air exchange rates in long-distance buses should be increased in order to reduce CO₂ levels. Future research on long-distance buses should focus on the emission of VOCs from brand new buses, and the sources of submicron particles in bus cabins.     

An Interval-Parameter Waste-Load-Allocation Model for River Water Quality Management Under Uncertainty

A simulation-based interval quadratic waste load allocation (IQWLA) model was developed for supporting river water quality management. A multi-segment simulation model was developed to generate water-quality transformation matrices and vectors under steady-state river flow conditions. The established matrices and vectors were then used to establish the water-quality constraints that were included in a water quality management model. Uncertainties associated with water quality parameters, cost functions, and environmental guidelines were described as intervals. The cost functions of wastewater treatment units were expressed in quadratic forms. A water-quality planning problem in the Changsha section of Xiangjiang River in China was used as a study case to demonstrate applicability of the proposed method. The study results demonstrated that IQWLA model could effectively communicate the interval-format uncertainties into optimization process, and generate inexact solutions that contain a spectrum of potential wastewater treatment options. Decision alternatives can be generated by adjusting different combinations of the decision variables within their solution intervals. The results are valuable for supporting local decision makers in generating cost-effective water quality management strategies.     

Methodology of industry scale analysis under the constraint of regional resource capacity using HSY algorithm

This paper develops a methodology of proper scale analysis for regional industry development, which can be used in industry planning with the consideration of regional resource capacities. In the face of different data sources and even data scarcity, alternative methods based on linear programming and quadratic programming algorithms for calculating the resource intensity factors are designed. Based on the empirical study of industrialization, initial scenarios of industry development were set. Using HSY algorithm, sensitive industries that may cause exceeding regional resource capacity can be identified, and the risk of exceeding can be predicted and expressed in probability. Furthermore, a proper scale range can be designed for these sensitive industries according to resource capacity. Taking the case of Dalian city in China, this paper estimated the regional urban development plan, various resources capacities were studied, and land resources were estimated to be the most critical resource for the city. The land resource depletion intensities of different industries are calculated by quadratic programming algorithm. Under the constraint of 427.56 km² available industrial land resources, the electronic and power industries have the most significant impact on total land use, if the scale of power industry exceeds 1.27 billion USD, the probability of land resource capacity breakthrough will be 50%.     

Agricultural Structure in Western China by Comparing with before and after CFFG Based on Shift-share Method

Based on shift-share method, this article employs re- gional share, structural shift and competitive shift to analyze the structural benefit and competitive position of agricultural structure in western China by comparing with agriculture, foresting, stockbreeding and fishing before and after Conversion of Farmland to Forest and Grassland （CFFG）. Then authors draw following conclusion： while CFFG program has been put in practice, the agricultural structure in western China has some typical characteristics, such as growth faster, structural predominance obvious and more competitive. But the contributiveness from the competition is not too much yet, and the structural benefit of forest estate and stockbreeding are restrained.     

CuCoOx/TiO2催化氧化NO性能研究

采用浸渍法制备了CuCoOx/TiO₂催化剂,考察了焙烧温度、反应温度、氧含量、NO浓度和空间速度对催化剂催化氧化NO性能的影响,并考察了催化剂的抗硫抗水性能。XRD、TPR和BET分析表明,350℃焙烧的催化剂具有CuCo₂O₄尖晶石结构,比表面积大,对NO的氧化效果好。在空速为5 000 h^-1,NO进口浓度500 mg/m³,含氧量10%的条件下,反应温度300℃时NO转化率可达79.5%,250℃时NO转化率接近50%。该催化剂具有良好的单独抗SO₂、抗H₂O毒化性能,H₂O和SO₂同时存在时很快失活。该催化剂可用于不同时含H₂O和SO₂的含NO气体催化氧化后再吸收处理。     

几种试剂对硝酸根光催化脱色甲基橙的影响

以NO^-₃为光催化剂,在紫外灯照射下,对甲基橙溶液进行光催化脱色。结果表明,叔丁醇、甲醇和乙醇对催化脱色反应有抑制作用; KBr和Na₂SO₄对脱色反应均有促进作用;而且KBr的加入量存在最佳值; Na₂SO₄的促进作用随Na₂SO₄的量的增加逐渐增强。Na₂CO₃的存在对甲基橙的脱色反应没有影响。K₂S₃O₈和NO^-₃之间存在较强的协同作用;KIO₃和NO^-₃之间存在相加作用;KBrO₃和NO^-₃之间存在拮抗作用。