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111.
采用西安市第四污水处理厂A2/O系统中的絮体污泥为接种污泥,在连续流传统活性污泥系统中进行了好氧颗粒污泥的培养研究。当系统温度为25~27℃、沉淀时间为2 h、溶解氧为4.2 mg/L、搅拌速度为240 r/min时,系统可培养出粒径为0.5~1.5 mm的颗粒污泥,扫描电镜结果显示,颗粒污泥主要由球状菌和杆状菌组成,此外还存在少量的丝状菌。实验结果表明,相对于反应器的形式和沉淀时间,水力剪切力和接种污泥中的丝状菌对好氧颗粒污泥形成的影响更大,胞外多糖的产生对好氧颗粒污泥的形成也起着至关重要的作用。 相似文献
112.
为研究含硫油品储油罐中硫铁化物的自燃倾向性,采用STA8000同步热分析仪对10,15,20℃/min等不同升温速率和15,20,25 mL/min等不同空气流量下的硫铁化物进行试验,并通过获得的TG-DSC曲线研究试样的自燃特性;在此基础上,根据Coat模型,利用不同反应机理函数对热重数据进行分析。结果表明:该试验条件下,硫铁化物的氧化进程符合三级反应动力学机制;得出了硫铁化物在不同升温速率和空气流量下的表观活化能;在560~746℃温度区间内,随着升温速率的增加,空气流量的加大,活化能数值明显减小,自燃倾向性增大。研究结果可为预防和控制因硫铁化物自燃引发的火灾、爆炸事故提供理论参考。 相似文献
113.
Methyl-triclosan (MTCS), a transformation product and metabolite of triclosan, has been widely spread in environment through the daily use of triclosan which is a commonly used anti-bacterial and anti-fungal substance in consumer products. Once entering human body, MTCS could affect the conformation of human serum albumin (HSA) by forming MTCS–HSA complex and alter function of protein and endocrine in human body. To evaluate the potential toxicity of MTCS, the binding mechanism of HSA with MTCS was investigated by UV–vis absorption, circular dichroism and Fourier transform infrared spectroscopy. Binding constants, thermodynamic parameters, the binding forces and the specific binding site were studied in detail. Binding constant at room tempreture (T = 298 K) is 6.32 × 103 L mol−1; ΔH0, ΔS0 and ΔG0 were 22.48 kJ mol−1, 148.16 J mol−1 K−1 and −21.68 kJ mol−1, respectively. The results showed that the interactions between MTCS and HSA are mainly hydrophobic forces. The effects of MTCS on HSA conformation were also discussed. The binding distance (r = 1.2 nm) for MTCS–HSA system was calculated by the efficiency of fluorescence resonance energy transfer. The visualized binding details were also exhibited by molecular modeling method and the results could agree well with that from the experimental study. 相似文献
114.
Fe/C微电解-Fenton氧化-混凝沉淀-生化法处理染料母液废水 总被引:4,自引:2,他引:4
采用Fe/C微电解-Fenton氧化-混凝沉淀-生物接触氧化法处理强酸性染料生产母液废水。结果表明,组合工艺对该强酸性母液废水具有理想的处理效果。在铁炭处理单元,当铁炭比为2.5∶1,曝气量为90 L/h,HRT=80 min时,单级色度和COD去除率分别为77.2%和48.7%,BOD5/COD升高至0.30;Fenton氧化处理单元,当30%H2O2投加量为3 mL/L,pH=3.5,HRT=80 min时,单级色度和COD去除率分别为83.6%和77.4%,BOD5/COD升高至0.48。再经过混凝沉淀和生物接触氧化处理后,废水的色度和COD总去除率可分别高于99.8%和99.2%。 相似文献
115.
Yan Mi Zhou Xuanyou Zhang Sicheng Liao Wenjuan Zhu Gaojun Wang Jingyi Kanchanatip Ekkachai Khan Muhammad Sajid 《Journal of Material Cycles and Waste Management》2021,23(3):1141-1151
Journal of Material Cycles and Waste Management - RDF made of municipal solid waste was pyrolyzed under simulated pyrolytic gas (PG) atmosphere and N2 atmosphere. Besides pyrolysis temperature, the... 相似文献
116.
细颗粒物(PM2.5)和臭氧(O3)是影响我国环境空气质量持续改善的两个关键污染物,具有一定的同根同源性,具备协同控制的基础条件。通过对现阶段我国实施O3和PM2.5协同控制的政策管理、科学机理、技术措施和能力建设等方面的系统分析,建议从国家层面科学划定O3联防联控区域,优化区域联防联控机制;摸清O3关键前体物VOCs和NOx的排放基数,建立VOCs分物种清单;量化协同方案,有序开展污染物、区域、行业多角度协同控制;开展O3和PM2.5协同机理研究,强化科学研究的支撑作用;开展VOCs综合治理,提高监管执法能力建设。以期实现O3和PM2.5短期削峰,长期达标。 相似文献
117.
通过研究嗜水气单胞菌RB5-M1菌株对活性黑5的脱色过程,探讨了菌株脱色不同初始浓度的活性黑5的动力学模型,并从机械强度、包埋量和渗漏量3个方面,对菌株的固定化条件进行了优化。结果表明,当初始染料浓度为50、100、150、200、250和300 mg/L时,菌株脱色活性黑5的动力学过程均更为符合Monod零级反应模型。当冷却温度为30℃、PVA与海藻酸钠浓度比为10∶1、氯化钙浓度为2%、明胶浓度0.2%时,可以获得机械强度较好、包埋量较多的固定化颗粒。当氯化钙浓度2%、明胶浓度0.3%、PVA与海藻酸钠浓度9∶2、冷却温度20℃,可获得渗漏量较少的固定化颗粒。 相似文献
118.
Jing Zhang Yaobin Zhang Wei Liu Xie Quan Shuo Chen Huimin Zhao Yihe Jin Wenjuan Zhang 《Chemosphere》2013,90(11):2662-2666
The anoxic–oxic (A/O) process has been extensively applied for simultaneous removal of organic contaminants and nitrogen in wastewater treatment. However, very little is known about its ability to remove toxic materials. Municipal wastewater contains various kinds of pollutants, some of which have recalcitrant genotoxicity and may cause potential threat to environment, and even can lead to extinction of many species. In this study, we have selected three municipal wastewater treatment plants (WWTPs) employing anoxic–oxic (A/O) process to evaluate their ability to remove acute toxicity and genotoxicity of wastewater. Mortality rate of zebrafish (Danio rerio) was used to evaluate acute toxicity, while micronucleus (MN) and comet assays were used to detect genotoxicity. Results showed that in this process the acute toxicity was completely removed as the treatment proceeded along with decrease in chemical oxygen demand (COD) (<50 mg L?1) in the effluent. However, in these treatment processes the genotoxicity was not significantly reduced, but an increase in genotoxicity was observed. Both MN and comet assays showed similar results. The eliminated effluent may pose genotoxic threaten although its COD level has met the Chinese Sewage Discharge Standard. This study suggests that further treatment of the wastewater is required after the A/O process to remove the genotoxicity and minimize the ecotoxicological risk. 相似文献
119.
120.