The electrochemical reduction characteristics of chlorinated hydrocarbons were investigated by cyclic voltammetry technique. The reduction mechanism and activity of the chlorinated hydrocarbons at the copper electrode were explored. The relationship between the structure of chlorinated hydrocarbons and their reductive activity were discussed. The experimental results showed that chlorinated alkanes and a portion of chlorinated aromatic hydrocarbons could be reduced directly at the copper electrode. However, chlorinated aromatic hydrocarbons were not easy to reduce at the copper electrode. The results provided a theoretical basis for the catalyzed iron inner electrolysis method. 相似文献
With increases in the economy and standards of living, energy consumption has grown significantly in China, which has resulted in serious local air pollution and greenhouse gas emissions. Because both carbon dioxide (CO2) and air pollutant emissions mainly stem from fossil energy use, a co-control strategy is simulated and compared with single control in China, using an integrated assessment model (Global Change Assessment Model-Tsinghua University (GCAM-TU)) in this paper. We find that end-of-pipe (EOP) control measures play an important role in reducing air pollution in the near future, but in the long run, optimizing the energy system is an effective way to control both emissions. Reducing air pollutant might take a “free-ride” of decarbonizing the energy system. Compared with a single control of air pollutants, a co-control strategy is likely to reduce the requirement of EOP control measures. The result guides the Chinese government to consider a systemic and scientific plan for decarbonizing the energy system and co-controlling CO2 and air pollutant, in order to avoid duplicate investments in infrastructure and lockup effect. The solution could be extended to many other developing countries, such as India and Africa, which is helpful to realize the goals of United Nations (UN) Sustainable Development Agenda.
