Surface and subsurface geologic risk factors to ground water affecting brownfield redevelopment potential

A model is created for assessing the redevelopment potential of brownfields. The model is derived from a space and time conceptual framework that identifies and measures the surface and subsurface risk factors present at brownfield sites. The model then combines these factors with a contamination extent multiplier at each site to create an index of redevelopment potential. Results from the application of the model within an urbanized watershed demonstrate clear differences between the redevelopment potential present within five different near-surface geologic units, with those units containing clay being less vulnerable to subsurface contamination. With and without the extent multiplier, the total risk present at the brownfield sites within all the geologic units is also strongly correlated to the actual costs of remediation. Thus, computing the total surface and subsurface risk within a watershed can help guide the remediation efforts at broad geographic scales, and prioritize the locations for redevelopment.     

Hydrogen infrastructure build-up for automotive applications

Some lessons for the introduction of hydrogen fueled vehicles can be learned from experience gained by the introduction of natural gas fueled vehicles, either in Europe or in Argentina. While the European efforts have failed, at least until today, Argentina has achieved a remarkable market share of about 20% natural gas vehicles since the early 80ies. Beyond a short review on the constituents of a hydrogen refueling infrastructure, the Compressed Natural Gas (CNG)-example is analyzed to formulate some ‘must be’s’ for the successful introduction of hydrogen refueling infrastructure: Clear concerted signals have to be sent by all important players, the politicians as well as the involved industry from car producers to fuel suppliers. Bi-fueled hybrid vehicles are not seen as a proper tool, as they are forcing neither the user to look for hydrogen nor the supplier to provide hydrogen. After general considerations, various strategies and policies of different countries and manufacturers are reviewed. For instance, the electric hybrid cars as already today introduced by some Japanese manufacturers offer the chance of settling a maintenance infrastructure for electric drive systems already today which can be easily extended to cover full fuel cell drive systems, once they are available.     

Photodynamic action of some sensitizers by photooxidation of luminol

We report the development of a novel simple experimental method which allows the comparison of new photosensitizers based on their production of reactive oxygen species. A high-performance liquid chromatography (HPLC) assay permits the monitoring of several substances (sensitizer, reactant and oxidized end product) simultaneously on a single chromatogram. Photoreactions were monitored throughout their course by the HPLC assay surveying the sensitizers' efficiency of singlet oxygen production by the oxidative decomposition of luminol. Several photosensitizers were tested: Rose Bengal, Methylene Blue, Protoporphyrin IX, Photosan III, Photofrin, Hypericin and Pseudohypericin. Additionally, photoreactions were monitored by a standard pO₂ detection system. The measurements of the two detection methods were strongly correlated. Rose Bengal proved to be the most efficient photosensitizer, clearly decreasing the luminol concentration and causing a corresponding increase in aminophthalic acid. Our experiments show that when factors necessary for photochemical reactions are absent or are blocked (antioxidants), no reaction can be detected.