Evaluation of a fluorometric method for measuring low concentrations of ammonia in ambient air

A fluorometric method developed for measuring low concentrations of ammonium in marine and freshwater ecosystems was adapted for the analysis of ammonia in ambient air. The modified method entails collection of samples on an acid-treated solid adsorbent followed by analysis using a fluorometer. Optimal results were obtained using a commercially available sorbent tube containing 100 mg of acid-treated silica gel for sample collection, and an analytical protocol consisting of sample desorption in DI water, addition of orthopthaldialdehyde (OPA) working reagent, and room temperature incubation. Method accuracy and precision were evaluated by comparing experimentally determined quantities of ammonia to expected levels for sample loadings ranging from 0.16 [micro sign]g to 550 [micro sign]g-accuracy was generally within +/-20%. The estimated LOQ for the method is 0.08 [micro sign]g ammonia per sample which represents a 25-375-fold improvement in sensitivity compared to current NIOSH and OSHA methods for the measurement of ammonia in ambient air. The new method should be useful for applications requiring measurement of low concentrations of ammonia using personal sampling equipment or in the characterization of short-term fluctuations of ammonia concentrations in air.     

Natural abundance of Sb and Sc in pristine groundwaters, Springwater Township, Ontario, Canada, and implications for tracing contamination from landfill leachates

Using ICP-SMS and the clean lab methods and procedures developed for determining trace element concentrations in polar snow and ice, a lower limit of detection (LOD) of 30 pg l(-1) for Sb and 5 pg l(-1) for Sc was achieved, allowing the natural abundances of Sb and Sc to be measured in pristine groundwaters. Water samples were collected from natural flows and wells between Elmvale and Wyevale in Springwater Township, Ontario, Canada. The water in this region is derived from chemical reactions between meteoric fluids and the Quaternary sediments which cover the bedrock (dolomitic limestone) to depths of more than 100 m. The chemical composition of these waters (pH 8) is primarily a reflection of reactions between the percolating fluids with calcite and dolomite. The maximum concentration of Sb was 5.0 ng l(-1), and the average of all samples collected was 2.2 +/- 1.2 ng l(-1) (n = 34). The average concentration of Sc was 8.6 +/- 4.7 ng l(-1) (n = 28). The paucity of published Sb concentration data available for comparison is probably because most of the analytical methods commonly used to date, including GFAAS, HG-AAS, HG-AFS, INAA, and ICP-QMS, have lower limits of detection which are inadequate for reliably determining the natural abundance of Sb in many uncontaminated groundwaters. Also, the measurement of extremely low concentrations of Sb requires extra care to avoid possible contamination. Given the extensive use of Sb in plastics, we show that some of the containers used to collect and store samples, and for handling and preparing samples for chemical analyses, may be important sources of contamination in the laboratory. The Sb and Sc concentrations reported here should serve as reference values for this region, against which contamination by various human impacts in future could be compared.     

Quality assurance and quality control in monitoring programs

There are three general characteristics of the data to be collected in a monitoring program that should be met in order to maximize the use and value of the data: the data quality should be known, the data type and quality should be consistent and comparable, and the data should be available and accessible. Potential problems with each of these characteristics are addressed effectively by quality assurance and quality control. One of the most important aspects of quality assurance in a monitoring program is the development of a quality assurance plan, which should identify clearly the quality of the data needed and describe in detail the planned actions to provide confidence that the program will meet its stated objectives.Quality control data, which allow for the quality and suitability of the environmental data to be evaluated and ascertained, should be collected and utilized as an integral part of the QA effort associated with a monitoring program.     

Environmental impact assessment: The work of the OECD

This report describes the work of an international group that is supported in part by the Dutch Ministry for Environment and is chaired by Frans Evers, the Ministry's Deputy Director-General for Environmental Protection.     

Genecological variation corresponding to Forest Ecosystem Classification vegetation and soil types for jack pine and black spruce from northwestern Ontario

A preliminary study was undertaken to reveal ecotypic differentiation in jack pine and black spruce corresponding to ecological land classification groups. Seed sources of jack pine (64) and black spruce (68) from northwestern Ontario were classified according to Vegetation Types (V-Types) and Soil Types (S-Types) defined by the Forest Ecosystem Classification (FEC) developed by the Ontario Ministry of Natural Resources and Forestry Canada for northwestern Ontario. Two short-term common garden field trials and a greenhouse trial were established for each species. Significant differences were present among ecological groupings of seed sources for both species. These differences were expressed according to V-Types and S-Types based on first, second, and third year heights as well as needle flushing dates for jack pine and second year growth increments for black spruce. Rank differences among the groups based on FEC V-Types and S-Types were generally consistent for each of the two species although certain groups showed rank reversals at the two field trials. Apparently, selection pressures corresponding to different FEC V-Types and S-Types have resulted in a detectable pattern of adaptive variation for both jack pine and black spruce in northwestern Ontario. However, the management implications for these two species are uncertain since additional tests are required to verify these results.     

The role of interactions in long‐term population cycles

Changes in population size and structure depend not only on the internal dynamics of populations, but also on environmental coupling, human exploitation, and interaction with other species. Some of these factors are cyclic and predictable, while others are random. In some cases the effect of interactions is to destabilise the system and produce catastrophic changes, which are manifested as discontinuities. This paper reviews several models of marine populations which generate long‐term population changes, typically much longer than the generation time of the species involved. The output of these models is realistic and agrees with existing data, but in the absence of adequate time series it is not always possible to test or validate such models in a rigorous statistical sense. The paper concludes with a discussion of the role of such models in our understanding of long‐term changes in marine populations, and the practical implications of not always being able either to validate or falsify models needed for effective decisionmaking.     

Large particles are responsible for elevated bacterial marker levels in school air upon occupation

Muramic acid (Mur) is found in bacterial peptidoglycan (PG) whereas 3-hydroxy fatty acids (3-OH FAs) are found in Gram-negative bacterial lipopolysaccharide (LPS). Thus Mur and 3-OH FAs serve as markers to assess bacterial levels in indoor air. An initial survey, in a school, demonstrated that the levels of dust, PG and LPS (pmol m(-3)) were each much higher in occupied rooms than in the same rooms when unoccupied. In each instance, the Mur content of dust was increased and the hydroxy fatty acid distribution changed similarly suggesting an alteration in the bacterial population. Here, findings are compared with results from two additional schools. Follow-up aerosol monitoring by particle size was also performed for the first time for all 3 schools. The particle size distribution was shown to be quite different in occupied versus unoccupied schoolrooms. Within individual classrooms, concentrations of airborne particles [greater-than-or-equal]0.8 [micro sign]m in diameter, and CO(2) were correlated. This suggests that the increased levels of larger particles are responsible for elevation of bacterial markers during occupation. Release of culturable and non-culturable bacteria or bacterial aggregates from children (e.g. from flaking skin) might explain this phenomenon.     

A REVIEW OF APPLICATION ISSUES OF THE METROPOLITAN WATER DISTRICT-MAIN WATER FORECASTING SYSTEM1

ABSTRACT: This paper reviews the processes that occurred during an application of the Metropolitan Water District (MWD)-MAIN water use forecasting system for the City of Salinas, California. The review includes an analysis of sources of available data, methods for estimating input data, calibration, and verification of the MWD-MAIN System, and an evaluation of the reliability of system output. We found that inexperienced users can have difficulty understanding the level of skill, knowledge, and amount of data that are required to produce reliable forecasts. Some of the issues associated with application of the MWD-MAIN System include the following:

• ? All input data needed for accurate forecasts simply are not available for many cities and towns.
• ? The data requirements are more extensive than many users anticipate.
• ? Substantial requirements for manipulation of input data produces opportunity for error that creates major time demands in troubleshooting.
• ? Calibration and verification for specific uses can be substantially more difficult than is readily apparent from the guidance manual.
• ? Independent validity checks need to be done to validate system output.
• ? If specified calibrating procedures do not produce reasonable results, reestimating slope coefficients is an option, but this requires resources and expertise that can easily exceed the limits of most users.

These are problems typical of most complex models. Reviews such as this can help users to appreciate the level of data required, and to use the MWD-MAIN System in a more effective and efficient manner.     

Book reviews

Common Property Economics: A General Theory and Land Use Applications

Glenn G. Stevenson

Cambridge, Cambridge University Press, 1992, XIV + 256pp., £35

Controversial Issues in Environmental Policy: Science vs Economics vs Politics

Kent E. Portney

London, Sage, 1992, 181 pp. £22.00 hb., £10.95 pb.

Economics of Natural Resources and the Environment

E. Kula

London, Chapman & Hall, 1992, 287 pp., £40

Policy Implications of Greenhouse Warming: Mitigation, Adaptation and the Science Base

Committee on Science, Engineering and Public Policy (US), Panel on Policy

Implications of Greenhouse Warming

Washington, DC, National Academy Press, 1992, xxiii + 918 pp., $89.95 hb.

Contemporary Rural Systems in Transition, Volume 1: Agriculture and Environment, Volume 2: Economy and Society

I. Bowler, C. Bryant & M.Nellis (Eds)

Wallingford, CAB International, 1992, 288 pp. + 336 pp., £35 + £40 (2 vols. £70) hb.

Third World Cities: Problems, Policies and Prospects

John Kasarda & Allan Parnell (Eds) London, Sage, 1993, 310 pp., £19.50 pb.

Pricing the European Environment

Stale Navrud (Ed)

Oxford, Oxford University Press/Scandinavian University Press, 1992, 288 pp., £30.00 hb.