Experiences in Controlling Atmospheric Pollution Encountered in Pharmaceutical Manufacturing Processes

Smog aerosol can be related to sources, atmospheric transport, and particle growth through a Lagrangian model. Sample calculations indicate that the midday Pasadena aerosol is dominated by material produced in the atmosphere, and that the afternoon drop in aerosol mass is due to the advection of cleaner air. Numerical experiments suggest that control of primary particulate emissions without corresponding control of reactive gases would not substantially improve visibility.     

Performance Characterization and Optimization of the AgNO3-Filter/FMA Fluorimetric Method for Atmospheric H2S Measurements

This sensitive, albeit precarious, method for measuring ppb-ppt (V/V) concentrations of H₂S was examined for various sources of potential error within the procedure. Filter preparation, filter storage, filter extraction, fluorimetric reagent stabilities, matrix differences between standards and samples, and possible interferences from other sulfur-containing compounds were separately studied for their effects on the analytical performance of the method. The overall method showed no Interference from SO₂, CS₂, COS, CH₃SH, CH₃SCH₃, and SO₄ ^-2. To minimize bias and obtain a reliable estimate of precision, the method should be calibrated with H₂S standards rather than liquid bisulfide standards. The measurement precision is a function of the quantity of H₂S collected as Ag₂S and/or AgSH on the impregnated filters. Because of the method’s linear dynamic range, sufficient air should be sampled to achieve filter loadings of 15 to 35 ng S/filter. A quality control method based on fluorescein mercuric acetate (FMA) is presented that ensures data quality while reducing the otherwise frequent need for fluori-metric calibration.     

Sizing and Costing of fabric Filters Part II: Costing Considerations

This is the second of a two-part article that reviews baghouse filtration theory, presents size estimating methods, and gives costing procedures for a variety of baghouse types and sizes. Part I of the article discussed theory and sizing; this part presents costing. Information is given for estimating total capital investment including separate costs for the bare baghouse (five types), bags, and, where needed, cages and Venturis. Factors are given for installation and for indirect costs. Direct and indirect annual costs are discussed. An example problem is given. The material in this article is taken primarily from the EAB Control Cost Manual.     

Incineration Techniques for Control of Volatile Organic Compound Emissions

A review of incineration techniques for control of volatile organic compound emissions is presented in two consecutive issues o/JAPCA. Part I presented an overview of the process including fundamentals and design considerations. Both thermal and catalytic incinerators were considered. Part IIpresents capital and annual operating cost estimates for both thermal and catalytic incinerator systems based on information received from a number of equipment manufacturers.     

The Role of the Computer in Air Pollution Control

The search for ways of reducing vehicular emissions has led to numerous investigations of the relationships between fuel composition and the pollutants discharged from automobiles. The most obvious fuel effects result from evaporation of gasoline components from the fuel tanks and carburetors of vehicles which lack effective mechanical devices (such as those required on all 1971 model cars) to control evaporative losses. Thus, several laboratories and cooperative study groups (Coordinating Research Council and American Petroleum Institute) have investigated the ways in which fuel properties (especially the amounts and types of C₄-C₅ hydrocarbons) influence both the amount and the potential atmospheric reactivity of evaporative emissions.^1–6 But fuel evaporation accounts for only a small portion of the total hydrocarbons emitted by automobiles, and gasoline modifications (such as volatility reductions) that reduce evaporative losses can lead to higher levels of hydrocarbons in automobile exhaust.^4–6     

Mercury Balance on a Large Pulverized Coal-Fired Furnace

This paper presents results of a survey of mercury concentrations in coal, ash, water, fly ash, and flue gas discharges from a 5.5 × 10⁶ Ib/hr steam generator serving a 775 MW (net) turbine-generator set. Representative composite or grab samples were obtained for inlet coal and outlet ash and water. Stack samples were obtained for fly ash and mercury vapor emissions while the unit was operated at 660 MW (net) (85% of full load). Samples were analyzed by anodic stripping voltammetry, plasma emission spectroscopy, and neutron activation analysis to determine mercury concentration entering the furnace in the coal and leaving the furnace in the flue gas, fly ash, bottom and hopper ash, and water. Method inter-comparisons are discussed. A material balance for mercury has been calculated from fuel, ash, and stack gas flow rates. About 90% of the mercury in the coal is released and appears as vapor discharged in the stack gas while 10% remains in the residual ash. For a 700 MW (net) unit, about 5 lb/day of mercury vapor is released to the atmosphere.     

Rural and Urban Ozone Relationships In New York State

High ozone concentrations, often in excess of the national ambient air quality standard for photochemical oxidants, have been measured simultaneously in urban and rural areas of New York State. Average daily rural ozone concentrations were found to correlate well with daily maximum urban ozone concentrations suggesting a common source. Estimations of the quantity of ozone advectively transported into New York State are more than an order of magnitude greater than estimations of the potential photochemical generation of ozone from hydrocarbon emissions within New York State. It is suggested thai the high rural ozone levels are not primarily due to the transport of ozone and ozone precursors from olher urban areas, but are rather due to natural phenomena such as photochemical generation from naturally occurring precursors or transport of ozone from the stratosphere to the troposphere. The effectiveness of a hydrocarbon control strategy for New York State to meet the ambient air quality standard for photochemical oxidants when background levels themselves may be above the standard is questioned.