Development of some natural matrix standards — Progress report

Substantial progress has been made in the production of environmental level, natural matrix, radioactivity standards of soil of low organic and low carbonate content, and of human lung and human liver. This is in response to the deliberations of the 1977 ICRM meeting at which the need for such standards was voiced and the criteria suggested. The soil samples have been reduced to optimum particle size and are ready for blending and standardization. A ten year supply of this standard should be ready in a year or less. Reducing the dried lung and liver to less than 74 μm has proven formidable because of the natural fat and oil content. Using cyrogenic milling techniques more than three quarters of the total mass of each has been reduced to the desired particle size; the balance will either be reduced or removed and we can then proceed to the final standardization.     

Comparing Vapor Intrusion Mitigation System Performance for VOCs and Radon

This article summarizes a long‐term study of vapor intrusion mitigation system performance in a historic, unoccupied residential duplex with an extensive set of temporal variability observations. The experimental design included multiple cycles of subslab depressurization (SSD) system operation and shut‐off during a seven‐month period, followed by a year‐long period of continuous operation. Results showed that the system provided rapid pressure field extension and radon control as much as 100 days of operation before optimum volatile organic compound (VOC) mitigation was achieved. Greater variability in VOC concentrations than in radon concentrations was observed during the initial mitigation system cycling. Subslab VOC concentrations at numerous locations increased during this initial period of SSD operation, and indoor air VOC concentrations were more variable than radon. However, indoor air concentrations were considerably less variable (and lower) during the first year of continuous mitigation system operation. ©2015 Wiley Periodicals, Inc.     

A new economic instrument for financing accelerated landfill aftercare

The key aspects of landfill operation that remain unresolved are the extended timescale and uncertain funding of the post-closure period. This paper reviews the topic and proposes an economic instrument to resolve the unsustainable nature of the current situation. Unsustainability arises from the sluggish degradation of organic material and also the slow flushing of potential pollutants that is exacerbated by low-permeability capping. A landfill tax or aftercare provision rebate is proposed as an economic instrument to encourage operators to actively advance the stabilization of landfilled waste. The rebate could be accommodated within existing regulatory and tax regimes and would be paid for: (i) every tonne of nitrogen (or other agreed leachate marker) whose removal is advanced via the accelerated production and extraction of leachate; (ii) every tonne of non-commercially viable carbon removed via landfill gas collection and treatment. The rebates would be set at a level that would make it financially attractive to operators and would encourage measures such as leachate recirculation, in situ aeration, and enhanced flushing. Illustrative calculations suggest that a maximum rebate of up to ～€50/tonne MSW would provide an adequate incentive.     

Co-pyrolysis of swine manure with agricultural plastic waste: Laboratory-scale study

Manure-derived biochar is the solid product resulting from pyrolysis of animal manures. It has considerable potential both to improve soil quality with high levels of nutrients and to reduce contaminants in water and soil. However, the combustible gas produced from manure pyrolysis generally does not provide enough energy to sustain the pyrolysis process. Supplementing this process may be achieved with spent agricultural plastic films; these feedstocks have large amounts of available energy. Plastic films are often used in soil fumigation. They are usually disposed in landfills, which is wasteful, expensive, and environmentally unsustainable. The objective of this work was to investigate both the energetics of co-pyrolyzing swine solids with spent plastic mulch films (SPM) and the characteristics of its gas, liquid, and solid byproducts. The heating value of the product gas from co-pyrolysis was found to be much higher than that of natural gas; furthermore, the gas had no detectable toxic fumigants. Energetically, sustaining pyrolysis of the swine solids through the energy of the product gas could be achieved by co-pyrolyzing dewatered swine solids (25% m/m) with just 10% SPM. If more than 10% SPM is used, the co-pyrolysis would generate surplus energy which could be used for power generation. Biochars produced from co-pyrolyzing SPM and swine solid were similar to swine solid alone based on the surface area and the ¹H NMR spectra. The results of this study demonstrated the potential of using pyrolysis technology to manage two prominent agricultural waste streams (SPM and swine solids) while producing value-added biochar and a power source that could be used for local farm operations.     

Investigating the effect of compression on solute transport through degrading municipal solid waste

The effect of applied compression on the nature of liquid flow and hence the movement of contaminants within municipal solid waste was examined by means of thirteen tracer tests conducted on five separate waste samples. The conservative nature of bromide, lithium and deuterium tracers was evaluated and linked to the presence of degradation in the sample. Lithium and deuterium tracers were non-conservative in the presence of degradation, whereas the bromide remained effectively conservative under all conditions. Solute diffusion times into and out of less mobile blocks of waste were compared for each test under the assumption of dominantly dual-porosity flow. Despite the fact that hydraulic conductivity changed strongly with applied stress, the block diffusion times were found to be much less sensitive to compression. A simple conceptual model, whereby flow is dominated by sub-parallel low permeability obstructions which define predominantly horizontally aligned less mobile zones, is able to explain this result. Compression tends to narrow the gap between the obstructions, but not significantly alter the horizontal length scale. Irrespective of knowledge of the true flow pattern, these results show that simple models of solute flushing from landfill which do not include depth dependent changes in solute transport parameters are justified.