Greening academia: use and disposal of mobile phones among university students

Mobile phones have relatively short lifecycles and are rapidly seen as obsolete by many users within little over a year. However, the reusability of these devices as well as their material composition means that in terms of mass and volume, mobile phones represent the most valuable electronic products that are currently found in large numbers in waste streams. End-of-life mobile phones are a high value (from a reuse and resource perspective), high volume (quantity), low cost (residual monetary value) and transient (short lifecycle) electronic product. There are very large numbers of higher education (mainly university) students in the world - there are >2.4 million in the UK alone, 19 million in Europe and 18.2 million in the USA - and they often replace their mobile phones several times before graduation. Thus, because of the potentially significant environmental and economic impacts, a large scale survey of students at 5 UK universities was conducted to assess the behaviour of students with regard to their use and disposal of mobile phones. Additionally, a small scale trial mobile phone takeback service at one of the universities was carried out. The findings indicate that many students replace their phones at least once a year; replacing broken phones, getting upgrades from network operators, remaining “fashionable” and a desire to have a handset with a longer battery life are the main reasons for such rapid replacement. Almost 60% of replaced phones are not sent to reuse or recycling operations but are stockpiled by students mainly as spare/backup phones. Approximately 61% of students own an extra mobile phone with male students replacing their phones more often than females. In particular, the results highlight the potentially huge stockpile of mobile phones - and consequently valuable supplies of rare metals - being held by the public; we estimate that there are 3.7 million phones stockpiled by students in UK higher education alone (29.3 and 28.1 million stockpiled, respectively, for Europe and USA). Although many students are aware of UK mobile phone takeback services, only a moderate number have previously used the services. Students’ recycling of other waste materials such as paper and glass did not have a significant impact on their disposal actions for their unwanted mobile phones, although students who often recycled these waste materials were also the most willing to participate in mobile phone takeback services. Monetary incentives such as cash payments and vouchers have the greatest influence over students’ willingness to utilise takeback services, followed by convenience and ease of use of the services. The paper discusses these findings as well as the outcome of the trial mobile phone takeback. It is suggested that universities should partner with established takeback operators to conduct event-based mobile phone takeback services primarily targeting students. Lessons from mobile phone takeback applicable to takeback services for end-of-life gadgets similar to mobile phones are also discussed.     

Uptake of acetone,acetaldehyde and ethanol in cold sulfuric acid solutions containing organic material: Carbon accretion mechanisms

The solubilities of acetone, ethanol and acetaldehyde in cold ternary solutions composed of 38.4–75.0 wt% sulfuric acid in water with additional dissolved organic material have been measured over the temperature range 214.4–238.5 K using a Knudsen cell reactor. The solubility of acetaldehyde in H₂SO₄/H₂O is enhanced by an order of magnitude by the presence of ethanol or acetone. The reactive uptake of acetaldehyde is enhanced by the presence of formaldehyde in acid solution. No significant formation of acetals from ethanol with carbonyl partners was observed. The solubility of acetone is unaffected by the presence of ethanol in solution and vice versa. Only polymerization of small aldehydes offers a potentially significant route to the accretion of organic material into acidic particles in the upper troposphere. The acid-catalyzed polymerization of aldehydes, RC(H)O + R′C(H)O, proceeds through the hydrated forms of the aldehydes, is optimized at acidities around 40 wt% H₂SO₄, and can potentially accumulate significant amounts (>20%) of organic material by mass in upper tropospheric particles.     

Hydroxyl radical (OH) yields from the ozonolysis of both double bonds for five monoterpenes

A new method has been applied to determine OH-radical yields from the ozonolysis of both double bonds from five selected, atmospherically relevant monoterpenes, namely terpinolene, α-phellandrene, limonene, α-terpinene and γ-terpinene. While OH-yields for the faster reacting double bond agreed with previous literature values, the yields from the second double bond were determined for the first time and are as follows: limonene 7–10%, terpinolene 39–48%, α-phellandrene 8–11% and α-terpinene 12–14%. Only for γ-terpinene the rate coefficient for the reaction of ozone with the two double bonds was too similar in order to distinguish the OH-yield with this method. In all cases the yield from the second double bond was significantly lower than the first. The reasons for this difference are discussed in terms of the Criegee-intermediate reactions, in particular the number of abstractable H-atoms and the number of possible hydroperoxide products.     

An Event-Based Approach for Examining the Effects of Wildland Fire Decisions on Communities

Public concern over the consequences of forest fire to wildland interface communities has led to increased resources devoted to fire suppression, fuel treatment, and management of fire events. The social consequences of the decisions involved in these and other fire-related actions are largely unknown, except in an anecdotal sense, but do occur at a variety of temporal and social organizational scales. These consequences are not limited to the fire event itself. Preparation for the possibility of a fire, actions that suppression agencies take during a fire, and postfire decisions all have consequences, if unknown currently. This article presents an "event-based" approach that can be useful for constructing and systematic discussion about the consequences of wildland fire to human communities. For each of the three major periods within this approach, agencies, communities, and individuals make decisions and take actions that have consequences. The article presents an integrated, temporally based process for examining these consequences, which is similar to others developed in the natural hazards and disaster management literature.     

Delineating protected wildlife corridors with multi‐objective programming

Protected wildlife corridors can help counteract habitat fragmentation and link isolated reserve “islands” into connected reserve systems. The need for wildlife corridors will grow as expanding human populations place increasing pressure on remaining undeveloped land. A two‐objective zero–one programming model is formulated for the problem of selecting land for a system of wildlife corridors that must connect a known set of existing reserves or critical habitat areas. This problem is modeled as a network Steiner tree problem, under the objectives of minimizing corridor land costs and minimizing the amount of unsuitable land within the corridor system. Linear programming is used to find exact solutions with little or no branching and bounding, and the multi‐objective weighting method is used to generate non‐inferior alternatives. Two hypothetical examples demonstrate the model and solution procedure. Results can help inform planning and decision making for protected area land acquisition and habitat restoration.     

Pyrolysis of latex gloves in the presence of Y-zeolite

In this study we have investigated the possibility of processing waste rubber gloves using pyrolysis. Y-zeolite catalyst was employed to upgrade the pyrolysis products to give higher yields of valuable aromatic compounds such as toluene and xylenes. The composition of the pyrolysis products was determined using gas chromatography with linked mass spectrometry (GC-MS), gas chromatograph equipped with a flame ionization detector (GC-FID), gas chromatograph fitted with dual thermal conductivity detectors (GC-TCD), and Fourier Transform Infra-Red Spectrometry (FT-IR). It was found that when rubber gloves were pyrolysed in the absence of a catalyst, the pyrolysis oil consisted mainly of limonene and oligomers of polyisoprene. When Y-zeolite was added to the reaction system, the yields of toluene, xylene, methylbenzenes, ethylbenzenes, and naphthalenes increased dramatically. The Y-zeolite also catalysed the decomposition of limonene, which was absent from the catalytic pyrolysis products. The presence of the Y-zeolite catalyst also increased the yield of hydrocarbon gases. The tests were carried out at both 380 degrees C and 480 degrees C and it was found that the higher reaction temperature led to increased yields of all the major compounds, both in the presence and absence of the Y-zeolite catalyst.     

What difference might sewage treatment performance make to endocrine disruption in rivers?

An assessment of the steroid estrogen removing performance of 23 different sewage treatment plants (STPs) was performed. The assessment relied on a model to estimate influent concentrations, and completed questionnaires on the STP treatment details from the relevant water companies. This information was compared with observed effluent 17beta-estradiol (E2) and estrone (E1) concentrations. The 10 biological filter plants (BFP) in the study performed poorly with only 30% (SD 31) removal on average for E1. This reduced E1 removal performance of the BFPs compared to all the other STP types in the survey was statistically significant (p<0.001). Scenarios of all the STPs as activated sludge types, and one as all BFP types were modelled using the GREAT-ER model set up for the Aire/Calder catchment in the UK. This difference was shown to have an important effect on predicted river E1 concentrations and consequent risk classifications.     

Influence of temperature on PCDD/PCDF desorption from waste incineration flyash under nitrogen

A municipal solid waste incinerator flyash was heated to between 200 and 400 degrees C under nitrogen in a bench-scale, static bed reactor for 4 days soak time. The influence of temperature on the levels of PCDD and PCDF remaining in and desorbed from the ash were investigated using GC-MS/MS. PCDD and especially PCDF formation was seen on the flyash between 225 and 300 degrees C. Large increases in the I-TEQ of the treated ash relative to the increase in its overall PCDD/PCDF content indicated that the formation of 2378-substituted congeners was favoured over that of other substitution patterns. In the absence of a source of gaseous oxygen, formation was mainly attributed to de novo reactions involving solid phase oxygen. Dechlorination of the PCDD/PCDF in flyash became increasingly important above 275 degrees C. Maximum desorption was seen at 325 degrees C, with the equivalent of 35 wt% of the PCDD/F in the original flyash being recovered from the exhaust traps at this temperature. The desorbed species were mainly M(1)CDD/CDDF-T(3)CDD/CDDF resulting from dechlorination of higher chlorinated PCDD/PCDF, with consequently low I-TEQ values.