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171.
The very significant impact of European legislation (Directive 91/414/EEC) on the authorization of plant protection products is reviewed herein, which has resulted in withdrawal of 704 active substances (AS) out of 889 assessed so far. The list of currently approved 276 AS includes 194 AS “existing” in the market before 1993 and 82 “new” AS introduced during the last 15 years. Results of toxicity characterization of the approved AS are also summarized, utilizing several well-known databases. Although significant data gaps exist for a rather large part of the approved AS, it is found that 84 AS are positive for at least one health effect (after chronic and/or acute exposure) including carcinogenicity, reproductive and neuro-developmental disorders, as well as endocrine disruption. The toxicity characterization results of this study are compared to those of recent assessments by other organizations (KemI, the Swedish Chemicals Agency, and the Pesticide Safety Directorate of the UK), where interpretation and use is made of AS “cut-off” criteria foreseen in new EU legislation. These studies report a comparatively smaller AS number with positive toxicity characterization. The possibility of some additional AS withdrawal in the near future, combined with the rather small rate of new AS introduction (approx. 5 per year) suggest that the list of approved AS over the next 10–15 years may not change very drastically. Consideration of the above trends is necessary and instructive in evaluating results of existing health impact assessment (HIA) studies, as well as in planning new ones. Due to the very drastic change in the number and type of marketed AS, that took place within the past 8–9 years, it is suggested that new HIA studies (based on epidemiological data after year 2000) should focus on a rather short time frame and, therefore, on appropriate cohort groups, e.g. young children. For the same reason, results of epidemiological studies of the past (involving banned AS) should be carefully interpreted and used with caution.  相似文献   
172.
The study focuses on evaluating factors that farmers consider relevant in adopting cassava production in five semi-arid zone of West African countries. The study is based on primary data randomly collected as part of collaborative study of cassava in semiarid zones of Africa (COSCASSA) village level survey from five West African countries namely: Nigeria, Ghana, Chad, Niger and Burkina Faso. This study models effects of farm, farmer and technology specific factors on the decision of semi arid farmers to adopt cassava into their farming system. By way of threshold decision models—Probit and Logit models, the estimation of each country and the pooled data adoption models reveal different adoption models for the countries considered. For each country, different variables appeared as major adoption shifters. Comparatively, the adoption models for Nigeria and whole region appear to have the highest significance variables, being seven in number. This is followed by Chad (6), Ghana (4), and Burkina Faso and Niger with three each. For the variables considered, distance to nearby urban market appears a major adoption shifter in all the country, except for Niger. This is closely followed by contact with extension, variety, pest/disease resistance and livestock feeds, which appear significant in four of the countries. Membership of cooperative societies appears as the least adoption predictor, which is only significant in Chad republic. The study therefore recognizes the importance of varietial characteristics and farmers’ characteristics in acceptance of cassava as a major root tuber crop in the semi arid region of West Africa. Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue.  相似文献   
173.
This paper considers the evolution of attempts to control and manage air pollution, principally but not exclusively focussing upon the challenge of managing air pollution in urban environments. The development and implementation of a range of air pollution control measures are considered. Initially the measures implemented primarily addressed point sources, a small number of fuel types and a limited number of pollutants. The adequacy of such a source-control approach is assessed within the context of a changing and challenging air pollution climate. An assessment of air quality management in the United Kingdom over a 50-year timeframe exemplifies the range of issues and challenges in contemporary air quality management. The need for new approaches is explored and the development and implementation of an effects-based, risk management system for air quality regulation is evaluated.  相似文献   
174.
The US EPA has exempted t-butyl acetate from VOC regulations, which increases the likelihood that it may replace other solvents in some settings. This investigation probes its chemosensory properties. In Study 1, subjects (n = 29) sought to detect the odor of t-butyl acetate and of n-butyl acetate in forced-choice testing of stable concentrations, analytically confirmed. Subjects sniffed from cones with a high enough volumetric flow to insure against dilution by nonodorized air. A subject made hundreds of judgments, enough for a psychometric function for each material. The points of 50% detection above chance (“threshold”) occurred at 8 and 2 ppb for t-butyl acetate and n-butyl acetate, respectively. In study 2, subjects (n = 26) sought to detect vapor with the eye via chemesthesis (sensory irritation) in 10-s exposures. Detection at 50% occurred at 177 and 113 ppm for t-butyl acetate and n-butyl acetate, respectively, more than 10,000 times above that for odor detection. The protocols produced results of uncommon precision compared to those in often-misleading archival databases. The nose exhibits much higher sensitivity than the databases indicate. The collections rarely exhibit accuracy better than ±1000%. Collection of accurate data for a VOC can ironically bring on stricter regulation for just it, a situation that calls for a strategy to improve the database by collection of new data, importation of better data, and development of quantitative structure–activity modeling.  相似文献   
175.
Strategies for beneficial use of biosolids in New Zealand and elsewhere are currently focused primarily on land application. The long-term success of these and other strategies is dependent not only on technical factors, but also on their environmental, economic, social and cultural sustainability. This paper briefly reviews the situation with respect to biosolids management in New Zealand, where land application is not yet widespread; the rise in public opposition to land application in the United States; and the biosolids industry's approach to public engagement. We argue that, at least until recently, the industry has misinterpreted the nature and meaning of public opposition and thus substituted public relations for public engagement. We argue that genuine public engagement is necessary and that its purpose cannot be to gain public acceptance for an already-decided-upon strategy. It therefore calls for humility among biosolids managers, including a willingness to open up the framing of 'the problem', to acknowledge areas of uncertainty, and to recognise the role of values in 'technical' decision-making. We then present and analyse an example of the use of the scenario workshop process for public participation in biosolids management policy in Christchurch, New Zealand, and conclude that scenario workshops and related methods represent an opportunity to enhance sustainable waste management when certain conditions are met.  相似文献   
176.
Despite biological invasions being a worldwide phenomenon causing significant ecological, economic, and human welfare impacts, there is limited understanding regarding how environmental managers perceive the problem and subsequently manage alien species. Spanish environmental managers were surveyed using questionnaires to (1) analyze the extent to which they perceive plant invasions as a problem; (2) identify the status, occurrence, and impacts of noxious alien plant species; (3) assess current effort and expenditure targeting alien plant management; and, finally, (4) identify the criteria they use to set priorities for management. In comparison to other environmental concerns, plant invasions are perceived as only moderately problematic and mechanical control is the most valued and frequently used strategy to cope with plant invasions in Spain. Based on 70 questionnaires received, 193 species are considered noxious, 109 of which have been the subject of management activities. More than 90% of species are found in at least one protected area. According to respondents, the most frequently managed species are the most widespread across administrative regions and the ones perceived as causing the highest impacts. The perception of impact seems to be independent of their invasion status, since only half of the species identified as noxious are believed to be invasive in Spain, while 43% of species thought to only be casual aliens are causing a high impact. Records of management costs are poor and the few data indicate that the total actual expenditure amounted to 50,492,437 € in the last decade. The majority of respondents stated that management measures are insufficient to control alien plants due to limited economic resources, lack of public awareness and support, and an absence of coordination among different public administrations. Managers also expressed their concern about the fact that much scientific research is concerned with the ecology of alien plants rather than with specific cost-efficient strategies to manage alien species.  相似文献   
177.
The Mining and Chemical Industrial Combine, Zheleznogorsk (MCIC, previously known as Krasnoyarsk-26) on the River Yenisey has contaminated the surrounding environment with anthropogenic radionuclides as a result of discharges of radioactive wastes. The purpose of this study was to investigate the vertical distribution of anthropogenic contamination (137Cs and plutonium) within floodplain areas at different distances from the discharge point. Sites were chosen that display different characteristics with respect to periodic inundation with river water. Cs-137 activity concentrations were in the range 23–3770 Bq/kg (dry weight, d.w.); Pu-239,240 activity concentrations were in the range <0.01–14.2 Bq/kg (d.w.). Numerous sample cores exhibited sub-surface maxima which may be related to the historical discharges from the MCIC. Possible evidence indicating the deposition of earlier discharges at MCIC in deeper core layers was observed in the 238Pu:239,240Pu activity ratio data: a Pu signal discernible from global fallout could be observed in numerous samples. Cs-137 and Pu-239,240 activity concentrations were correlated with the silt fraction (% by mass <63 μm) though no significant correlation was observed between (grain-size) normalised 137Cs activity concentrations and distance downstream from the MCIC.  相似文献   
178.
Specific ecogenetic features of solods in the forest-steppe zone has been studied, and the role of biotic and abiotic factors of soil formation has been estimated. Differentiation of soil horizons with respect to the physical clay fraction accounts for specific features of their moistening, which is reflected in the ratio of strongly and weakly crystallized forms of iron. Periodic changes in redox conditions results in iron segregation, and a high content of fulvic acids accounts for its eluvial migration. These processes are controlled by soil geochemical barriers.  相似文献   
179.
The composition of pied flycatcher (Ficedula hypoleuca Pall.) nestling diet was studied in the zone of strong pollution with emissions from the Middle Ural Copper Smelter (Revda, Sverdlovsk oblast) and in the background area from 2005 to 2007. The results show that diversity of the diet decreases and prevalence in it of one insect taxon (Lepidoptera) increases near the source of emissions. The proportion of uncharacteristic food objects (orthopterans, herpetobiont invertebrates) and variation in the size of invertebrates brought by parents to their nestlings increase, which is explained by degradation of forest habitats in the polluted area. Pied flycatchers provide nestlings with sufficient quantities of food, but its quality in the polluted zone is lower than in the background area.  相似文献   
180.
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