Schwermetalle in Federn

Results from the literature concerning feathers as a matrix for heavy metal accumulation were presented. Especially problems like the differentiation between endo and exogenous contributions, cleaning procedures or the right choice of feather parts were described. The question of the use of feathers for monitoring air, food or bird contamination is also discussed, as well as the advantages or disadvantages of this matrix in comparison to other methods.     

Clean development mechanism: an incentive for waste management projects?

The Clean Development Mechanism (CDM) was introduced by the Kyoto Protocol to provide a financial incentive to establish project activities in developing countries for reducing greenhouse gas emissions while also fostering sustainable development. This article shows that waste management project activities play an important role in achieving the aims of the CDM. It describes how these activities have to prove additionality, how the emission reductions must be calculated and monitored in order to be eligible and in order to lead to Certified Emission Reductions (CERs). The article further provides an analysis about the various challenges that are involved in applying the CDM scheme to waste management project activities, which require a new specific set of technical skills and regulatory standards.     

Effects of pore volume-transmissivity correlation on transport phenomena

The relevant velocity that describes transport phenomena in a porous medium is the pore velocity. For this reason, one needs not only to describe the variability of transmissivity, which fully determines the Darcy velocity field for given source terms and boundary conditions, but also any variability of the pore volume. We demonstrate that hydraulically equivalent media with exactly the same transmissivity field can produce dramatic differences in the displacement of a solute if they have different pore volume distributions. In particular, we demonstrate that correlation between pore volume and transmissivity leads to a much smoother and more homogeneous solute distribution. This was observed in a laboratory experiment performed in artificial fractures made of two plexiglass plates into which a space-dependent aperture distribution was milled. Using visualization by a light transmission technique, we observe that the solute behaviour is much smoother and more regular after the fractures are filled with glass powder, which plays the role of a homogeneous fault gouge material. This is due to a perfect correlation between pore volume and transmissivity that causes pore velocity to be not directly dependent on the transmissivity, but only indirectly through the hydraulic gradient, which is a much smoother function due to the diffusive behaviour of the flow equation acting as a filter. This smoothing property of the pore volume-transmissivity correlation is also supported by numerical simulations of tracer tests in a dipole flow field. Three different conceptual models are used: an empty fracture, a rough-walled fracture filled with a homogeneous material and a parallel-plate fracture with a heterogeneous fault gouge. All three models are hydraulically equivalent, yet they have a different pore volume distribution. Even if piezometric heads and specific flow rates are exactly the same at any point of the domain, the transport process differs dramatically. These differences make it important to discriminate in situ among different conceptual models in order to simulate correctly the transport phenomena. For this reason, we study the solute breakthrough and recovery curves at the extraction wells. Our numerical case studies show that discrimination on the basis of such data might be impossible except under very favourable conditions, i.e. the integral scale of the transmissivity field has to be known and small compared to the dipole size. If the latter conditions are satisfied, discrimination between the rough-walled fracture filled with a homogeneous material and the other two models becomes possible, whereas the parallel-plate fracture with a heterogeneous fault gouge and the empty fracture still show identifiability problems. The latter may be solved by inspection of aperture and pressure testing.     

The erect ‘penis’ is a flag of submission in a female-dominated society: greetings in Serengeti spotted hyenas

In East Africa, spotted hyenas live in large clans in a highly structured society dominated by females. A clan is a fission-fusion society where members are often solitary or in small groups. Spotted hyenas have a ritualized greeting during which two individuals stand parallel and face in opposite directions. Both individuals usually lift their hind leg and sniff or lick the anogenital region of the other. The unique aspect of greetings between individuals is the prominent role of the erect penis in animals of both sex. Female spotted hyenas have fused outer labiae and a pseudo-penis formed by the clitoris which closely resembles the male penis and can be erected. During greetings subordinates signalled submission with gestures which were not necessarily reciprocated by the dominant participant. Asymmetries were most pronounced in greetings between adult females where the probability of asymmetries increased with the divergence in rank between partners. Greetings between adult females and males were uncommon and restricted to males above median rank, principally the alpha male. Models of primate affiliative behavior assume that benefits derived from social relationships with different individuals are not equal and that individuals are selected to maximize the benefits they receive from social relationships with others. The observed distribution of greetings between partners of different rank matched the predictions of these models. An examination of non-adaptive hypotheses on the evolution of the pseudo-penis demonstrated that the conventional scenario linking (initial) virilization of female genitalia with selection for female dominance does not explain either the initial virilization, nor the evolution of the pseudo-penis to its current form and use. We sketch a new scenario that links (1) initial virilization to the occurrence of neonatal siblicide amongst members of a twin litter, and (2) costs of maintenance, pseudo-penile control over copulation and male submission. Our analysis confirms previous adaptive hypotheses on the function of the pseudo-penis in greetings and suggests new hypotheses to account for hitherto unexplained features. Correspondence to: M.L. East     

Photometrische Bestimmung der Zytotoxizität von Chemikalien

Two test methods are presented to assess the cytotoxicity of chemicals. On one hand the protozoonTetrahymena pyriformis and on the other the bacteriumPseudomonas aeruginosa is cultured in defined media containing the test chemicals. Test parameter is the quantity of living cells surviving exposure. The conversion of the tetrazolium salt MTT into formazan is equivalent to cell viability. A mixture of detergent and isopropanol is used to dissolve the blue formazan which is not soluble in water, prior to photometric measurement. For cetyltrimethylammonium bromide, benzyldimethyldodecylammonium chloride, dodecylbenzenesulfonic acid sodium salt, potassium dichromate, 4-toluenesulfonic acid sodium salt, and 4-nitrophenol the EC50-values (mol/l) in theTetrahymena pyriformis- (Pseudomonas aeruginosa) test system were: 10^?5,81 (10^?5,08); 10^?4,68) (10^?3,80; 10^?4,50 (10^?4,14); 10^?3,97 (10^?5,11); 10^?2,71 (10^?2,50) and 10^?4,00 (10^?3,64). — With the assays described here it is possible to measure a large number of samples by quick and simple means.     

The European Water Framework Directive: Water Quality Classification and Implications to Engineering Planning

The European Water framework directive (WFD) is probably the most important environmental management directive that has been enacted over the last decade in the European Union. The directive aims at achieving an overall good ecological status in all European water bodies. In this article, we discuss the implementation steps of the WFD and their implications for environmental engineering practice while focusing on rivers as the main receiving waters. Arising challenges for engineers and scientists are seen in the quantitative assessment of water quality, where standardized systems are needed to estimate the biological status. This is equally of concern in engineering planning, where the prediction of ecological impacts is required. Studies dealing with both classification and prediction of the ecological water quality are reviewed. Further, the combined emission–water quality approach is discussed. Common understanding of this combined approach is to apply the most stringent of either water quality or emission standard to a certain case. In contrast, for example, the Austrian water act enables the application of only the water quality based approach - at least on a temporary basis.     

Leaching Induced Changes in Substrate and Solution Chemistry of Mine Soil Microcosms

Leaching of soluble salts formed as the result of pyrite oxidation and primary mineral weathering is a major process in mine soil development. A microcosm experiment was designed to study leaching rates from mine soil columns under controlled laboratory conditions. Objectives of this experiment were to investigate the effect of leaching and the effect of fly ash amelioration on mid- to long-term chemical soil properties, and to test whether the results are qualitatively comparable to long-term field studies along a site chronosequence. The leaching experiment was conducted over a period of 850 days representing a kind of time-lapse picture due to high water fluxes. Leaching resulted in more favourable mid- to long-term properties of mine site topsoils, especially a reduced risk for acidity and salt stress. Ash amelioration decreases leaching rates by increasing pH and Al and Fe precipitation. It could be shown that the results of the column leaching studies are qualitatively in good agreement with field observations at least for long-term considerations. By enhancing the leaching process mid- to long-term chemical soil properties can be estimated.