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61.
Md. Musfiqur Rahman Tae Woong Na A. M. Abd El-Aty Jong-Hyouk Park M. N. U. Al Mahmud Angel Yang Ki Hun Park Jae-Han Shim 《Environmental monitoring and assessment》2013,185(11):9461-9469
The pre-harvest residue limit (PHRL) of abamectin (abamectin B1a and B1b) in Perilla frutescens leaves grown under greenhouse conditions were investigated using high-performance liquid chromatography with a fluorescence detector. Samples were extracted with acetonitrile. The extract was purified through a solid phase extraction procedure. Then the purified extract was derivatized with trifluoroacetic anhydride and N-methylimidazole to form a strong stable fluorescent derivative of abamectin. Finally, derivatized abamectins were conveyed to the detector via an Atlantis C18 column, with water and methanol as a mobile phase. Calibration curves were linear over the calibration ranges with coefficients of determinants r 2?≥?0.999. The limits of detection and quantification were 0.0033 and 0.01 mg kg?1 for abamectin B1a and B1b, respectively. Recovery was assessed in a control matrix at two different fortification concentrations, with three replicates for each concentration. Good recoveries were obtained for the target analytes and ranged from 82.11 to 93.03 %, with relative standard deviations of less than 8 %. The rate of disappearance of total abamectin on perilla leaves for recommended and double the recommended doses was described as first-order kinetics with a half-life of 0.7 days. Using the PHRL curve, we could predict the residue level of total abamectin to be 0.92 mg kg?1 at 7 days before harvest or 0.26 mg kg?1 at 4 days before harvest, which would be below the provisional MRL designed by the Korea Food and Drug Administration. 相似文献
62.
In environmental risk assessments (ERA), biomarkers have been widely used as an early warning signal of environmental contamination. However, biomarker responses have limitation due to its low relevance to adverse outcomes (e.g., fluctuations in community structure, decreases in population size, and other similar ecobiologically relevant indicators of community structure and function). To mitigate these limitations, the concept of adverse outcome pathways (AOPs) was developed. An AOP is an analytical, sequentially progressive pathway that links a molecular initiating event (MIE) to an adverse outcome. Recently, AOPs have been recognized as a potential informational tool by which the implications of molecular biomarkers in ERA can be better understood. To demonstrate the utility of AOPs in biomarker-based ERA, here we discuss a series of three different biological repercussions caused by exposure to benzo(a)pyrene (BaP), silver nanoparticles (AgNPs), and selenium (Se). Using mainly aquatic invertebrates and selected vertebrates as model species, we focus on the development of the AOP concept. Aquatic organisms are suitable bioindicator species whose entire lifespans can be observed over a short period; moreover, these species can be studied on the molecular and population levels. Also, interspecific differences between aquatic organisms are important to consider in an AOP framework, since these differences are an integral part of the natural environment. The development of an environmental pollutant-mediated AOP may enable a better understanding of the effects of environmental pollutants in different scenarios in the diverse community of an ecosystem. 相似文献
63.
64.
Mi-Young Lee Hye-Sung Won Ji Eun Park Jae-Yoon Shim Pil-Ryang Lee Ahm Kim Jung Bok Lee 《黑龙江环境通报》2016,36(5):424-431
65.
66.
Fertilization success and sexual behavior in male medaka, Oryzias latipes, exposed to tributyltin 总被引:5,自引:0,他引:5
Nakayama K Oshima Y Yamaguchi T Tsuruda Y Kang IJ Kobayashi M Imada N Honjo T 《Chemosphere》2004,55(10):1331-1337
We evaluated the effects of tributyltin (TBT), polychlorinated biphenyls (PCBs), and a mixture of TBT and PCBs on reproduction, gonadal histology, and sexual behavior in Japanese medaka (Oryzias latipes). We administered TBT (1 microg g(-1) body weight [b.w.] daily), PCBs (1 microg g(-1) b.w. daily), or both to medaka for 3 weeks. We assessed reproductive success during week 3 and the sexual behavior of male medaka after the exposure period. Fertilization success was significantly decreased in groups that received TBT. The profiles of fertility developed a bimodal distribution in the TBT and TBT+PCBs groups, and the numbers of males that performed "following" and "dancing" were significantly decreased in the TBT+PCBs group. The frequency of "dancing" also decreased after treatment with TBT, whereas fish that received PCBs only showed no difference in sexual behavior. Testes that had oocytes showed normal spermatogenesis, even though two of the five males treated with TBT+PCBs had some indication of testis-ova, which did not occur in any other group. Our results indicate that TBT, but not PCBs, affects sexual behavior and reproduction in medaka. 相似文献
67.
Tae Won Kim Kotaro Sakamoto Yasuhisa Henmi Jae C. Choe 《Behavioral ecology and sociobiology》2008,62(7):1139-1147
For males, courting and foraging are often behavioral alternatives, which take time and consume energy. When males have a
possibility of mating with receptive females, there may be a behavioral trade-off between courtship and feeding; the outcome
of which may be affected by male physiological condition and food availability. Although many mathematical models and empirical
studies suggest that the expression of male courtship signals are condition-dependent, decisions about courtship and mating
strategies in relation to food availability have not attracted much attention. In this study, we tested whether daily changes
in food availability affect males’ decisions about whether to court. We conducted experiments with the fiddler crab Uca lactea by providing males with additional food every other day. In food-supplemented enclosures, males did not increase courtship
activity on the days when food was supplemented. However, they built more courtship structures (semidomes) and waved more
on the days when they were not given additional food. Male size had a strong influence on the number of days the males courted.
We also tested whether the frequency of surface mating, as an alternative reproductive tactic, decreased when food was supplemented.
Contrary to our expectation, the number of males that exhibited the surface-mating tactic increased when food was supplemented
whereas the number of mate-searching females did not change. Our findings in this field study suggest that reproductive decisions
by male fiddler crabs are affected by fluctuating food availability and present body condition, and the alternative mating
tactic of this species may be more frequently used by males under good condition. 相似文献
68.
Human health risk assessment of explosives and heavy metals at a military gunnery range 总被引:1,自引:0,他引:1
In this research, a risk assessment was undertaken in order to develop the remediation and management strategy of a contaminated
gunnery site, where a nearby flood controlling reservoir is under construction. Six chemicals, including explosives and heavy
metals, posing potential risk to environmental and human health, were targeted in this study. A site-specific conceptual site
model was constructed, based on effective, reasonable exposure pathways, to avoid any overestimation of the risk. Also, conservative
default values were adapted to prevent underestimation of the risk when site-specific values were not available. The risks
posed by the six contaminants were calculated using the API’s Decision Support System for Exposure and Risk Assessment, with
several assumptions. In the crater-formed-area (Ac), the non-carcinogenic risks (i.e., HI values) of tri-nitro-toluene (TNT)
and Cd were slightly larger than 1, but for RDX (Royal Demolition Explosives) was over 50. The total non-carcinogenic risk
of the whole gunnery range was calculated to be 62.5, which was a significantly high value. The carcinogenicity of Cd was
estimated to be about 10−3, while that for Pb was about 5 × 10−4, which greatly exceeded the generally acceptable carcinogenic risk level of 10−4–10−6. It was concluded from the risk assessment that there is an immediate need for remediation of both carcinogens and non-carcinogens
before construction of the reservoir. However, for a more accurate risk assessment, further specific estimations of the changes
in environmental conditions due to the construction of the reservoir will be required; and more over, the effects of the pollutants
to the ecosystem will also need to be evaluated. 相似文献
69.
Myong Hwan Sohn Kyung Won Seo Yong Seok Choi Sang Joon Lee Young Sil Kang Yang Soon Kang 《Marine Biology》2011,158(3):561-570
The marine dinoflagellate Cochlodinium polykrikoides is a harmful and highly motile algal species. To distinguish between the motility characteristics of solitary and chain-forming
cells, the swimming trajectories and speeds of solitary cells and 2- to 8-cell chains of C. polykrikoides were measured using a digital holographic particle tracking velocimetry (PTV) technique. C. polykrikoides cells exhibited helical swimming trajectories similar to other dinoflagellate species. The swimming speed increased as the
number of cells in the chain increased, from an average of 391 μm s−1 (solitary cells) to 856 μm s−1 (8-cell chain). The helix radius R and pitch P also increased as the number of cells in the chain increased. R increased from 9.24 μm (solitary cell) to 20.3 μm (8-cell chain) and P increased from 107 μm (solitary cell) to 164 μm (8-cell chain). The free thrust-generating motion of the transverse flagella
and large drag reduction in the chain-forming cells seemed to increase the swimming speed compared to solitary cells. The
measured swimming speeds agreed with those from field observations. The superior motility of chain-forming C. polykrikoides cells may be an important factor for its bloom, in addition to the factors reported previously. 相似文献
70.
Lee LA Lee EG Lee T Kim SW Slaven JE Harper M 《Journal of environmental monitoring : JEM》2011,13(3):527-535
Recent laboratory research indicates physiologic sampling of gas and vapor may provide more representative estimates of personal exposures than traditional methods. Modifications to the physiologic sampling pump (PSP) used in that research are described which extend its usefulness to size-selective sampling of particulates. PSPs used in previous research varied motor speed to keep sampling proportional to the subject's inhalation. This caused airflow and particle velocities through the collection device to continually change making those pumps unsuitable for sampling particulates. The modified implementation of the PSP pulls a constant airflow into and through a cyclone, then uses valves to either direct the airflow through, or divert the airflow around, the sampling filter. By using physiologic inputs to regulate the fraction of each second that air flows through the sampling filter, samples may be collected in proportion to inhalation rate. To evaluate the performance of a functional prototype 5 different sizes of monodisperse aerosols of ammonium fluorescein were generated by a vibrating orifice aerosol generator and introduced into a calm air chamber. To simulate different inhalation rates the valves of the PSP were energized using 9 different duty cycles. Efficiency curves are presented and compared to a standard respirable convention by bias mapping. The performance of the modified cyclone used in the PSP sampling head compared favorably with a commercially available cyclone of the same model, operating at a constant airflow (± 10% over almost all the size distributions of concern). The new method makes physiologic sampling of the respirable fraction of particulates feasible. 相似文献